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Elsevier eBooks

Formulation of quantum statistics

Raj K. Pathria, Paul D. Beale

Published Feb 21, 2021• 2 citations
Publisher
DOI
10.1016/b978-0-08-102692-2.00014-4

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A formulation of quantum statistical mechanics is discussed in which the Feynman path centroid density in Feynman path integration is recast as the central statistical distribution used to average equilibrium and dynamical quantities. In this formulation, the path integral centroid density occupies the same role as the Boltzmann density in classical statistical mechanics. Therefore, the statistical ensemble of imaginary time path centroid configurations provides the distribution which is used to average the appropriately formulated effective operators and imaginary time correlation functions. An accurate renormalized diagrammatic perturbation theory for the centroid density and centroid-constrained imaginary time propagator will also be described with particular emphasis given to the mathematical advantages arising from the centroid-based formulation. The present paper is concerned with the calculation of equilibrium properties from the centroid perspective, while the companion paper describes a centroid-based formalism for calculating dynamical time correlation functions.
The classical and quantum Statistical Mechanics is straightforwardly formulated in the configuration space (x, v), and an example of a system is given to make the comparison with the formulation of the Statistical Mechanics in the phase space (x, p). It is shown that the advantage of using configuration space for system with their interaction force depends explicitly on the velocity of the bodies. In addition, for these types of systems it is shown that their partition function can be well defined in the configuration space but it is not defined in the phase space, or they can bring about different results, bringing the possibility of experimental verification of the formulation of Statistical Mechanics in the configuration space.