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Izvestiya vysshikh uchebnykh zavedenii Fizika

Laser photoionization spectroscopy of Rydberg and autoionization states of rare-earth element atoms

N. B. Eshkabilov, A. S. Kurbaniyazov, Sh. R. Haidarov

Published Oct 1, 2021• 2 citations
Publisher
DOI
10.17223/00213411/64/10/79

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We investigated for the first time the high-lying Rydberg levels in the rare radioactive element francium (Fr). The investigations were conducted by the highly sensitive laser resonance atomic photoionization technique with Fr atoms produced at a rate of about ${10}^{3}$ atoms/s in a hot cavity. We measured the wave numbers of the 7${p}^{2}$${P}_{3/2}$\ensuremath{\rightarrow}${\mathrm{nd}}^{2}$D (n=22--33) and 7${p}^{2}$${P}_{3/2}$\ensuremath{\rightarrow}${\mathrm{ns}}^{2}$S (n=23, 25--27,29--31) transitions and found the binding energy of the 7${p}^{2}$${P}_{3/2}$ state to be T=-18 924.8(3) ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$, which made it possible to establish accurately the ionization potential of Fr.

Physical Review Letters•Sep 21, 1987•53 citations
We investigated for the first time the high-lying Rydberg levels in the rare radioactive element francium (Fr). The investigations were conducted by the highly sensitive laser resonance atomic photoionization technique with Fr atoms produced at a rate of about 103{10}^{3}103 atoms/s in a hot cavity. We measured the wave numbers of the 7p2{p}^{2}p2P3/2{P}_{3/2}P3/2​\ensuremath{\rightarrow}nd2{\mathrm{nd}}^{2}nd2D (n=22--33) and 7p2{p}^{2}p2P3/2{P}_{3/2}P3/2​\ensuremath{\rightarrow}ns2{\mathrm{ns}}^{2}ns2S (n=23, 25--27,29--31) transitions and found the binding energy of the 7p2{p}^{2}p2P3/2{P}_{3/2}P3/2​ state to be T=-18 924.8(3) ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$, which made it possible to establish accurately the ionization potential of Fr.