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The Analytic Connection Between the Elements of the Scattering Matrix and the Discrete Stationary States in the Heisenberg S-Matrix Theory

K. Wildermuth

Published Jan 1, 1949• 0 citations
OpenAlex

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A tetradic scattering matrix formalism is proposed as a comprehensive framework for describing scattering and relaxation processes of both stationary and non-stationary systems. In the latter case (realized by the scattering of the molecular-maser beam) ordinary dyadic T-matrix formalism involving on-the-energy-shell scattering amplitudes is inadequate, the introduction of off-the-shell elements being required. Expressions are given relating the tetradic T-matrix elements to various scattering and attenuation rates (or cross sections). The relation to the tetradic level-shift operator in relaxation (linear response) theory is discussed. Photon absorption is presented as the successive occurrence of a scattering and a relaxation process, from the point of view of this formalism.
Transport in open quantum systems can be explored through various theoretical frameworks, including the quantum master equation, scattering matrix, and Heisenberg equation of motion. The choice of framework depends on factors such as the presence of interactions, the coupling strength between the system and environment, and whether the focus is on steady-state or transient regimes. Existing literature mainly treats these frameworks independently. Our work establishes connections between them by clarifying the role and status of these approaches using two paradigmatic models for single and multipartite quantum systems in a two-terminal setup under voltage and temperature biases. We derive analytical solutions in both steady-state and transient regimes for the populations, currents, and current correlation functions. Exact results from the Heisenberg equation are shown to align with scattering matrix and master equation approaches within their respective validity regimes. Crucially, we establish a protocol for the weak-coupling limit, bridging the applicability of master equations at weak-coupling with Heisenberg or scattering matrix approaches at arbitrary coupling strength. Published by the American Physical Society 2024