Quantum optical sensing is a maturing field that offers the capability to achieve extraor- dinary sensitivity. Atomic magnetometers, for example, now have the capability to detect brain signals and to precisely measure Earth’s gravity field. In optical atomic magnetome- ters, the electronic spins of the atoms in vapor form are aligned in the same direction by “pumping” the ensemble using laser light at a select frequency. Any magnetic field alters the spin states, which changes the optical properties of the vapor, such as the transmission of the laser light, providing a way to measure magnetic fields. After reviewing the theory of atomic structure and atom-light interactions relevant to the research presented here, I describe in the first part of this thesis a vector magnetometry method using microwave-assisted optical pumping, in which a microwave field resonant to the ground state hyperfine splitting of 87Rb pumps an ensemble of warm rubidium vapor, in addition to a strong optical pump beam, and a weaker optical probe beam. I present theoretical details as well as preliminary data demonstrating magnetic field measurements of a DC magnetic field. The measurements were taken when the DC field was aligned at various angles relative to the microwave magnetic field alignment. I compare theoretical and experimental differences in the measurements. With new methods for quantum devices comes the need for portability. In the second part of this thesis, we demonstrate the fabrication of millimeter-sized rubidium vapor cells using silicon micro-machining techniques. This method is relatively inexpensive compared to glass-blowing methods and allows rapid, large-scale production. I describe our process flow and demonstrate the presence of rubidium atoms inside our vapor cells. To conclude, suggestions for improvement are discussed.
Quantum optical sensing is a maturing field that offers the capability to achieve extraor- dinary sensitivity. Atomic magnetometers, for example, now have the capability to detect brain signals and to precisely measure Earth’s gravity field. In optical atomic magnetome- ters, the electronic spins of the atoms in vapor form are aligned in the same direction by “pumping” the ensemble using laser light at a select frequency. Any magnetic field alters the spin states, which changes the optical properties of the vapor, such as the transmission of the laser light, providing a way to measure magnetic fields. After reviewing the theory of atomic structure and atom-light interactions relevant to the research presented here, I describe in the first part of this thesis a vector magnetometry method using microwave-assisted optical pumping, in which a microwave field resonant to the ground state hyperfine splitting of 87Rb pumps an ensemble of warm rubidium vapor, in addition to a strong optical pump beam, and a weaker optical probe beam. I present theoretical details as well as preliminary data demonstrating magnetic field measurements of a DC magnetic field. The measurements were taken when the DC field was aligned at various angles relative to the microwave magnetic field alignment. I compare theoretical and experimental differences in the measurements. With new methods for quantum devices comes the need for portability. In the second part of this thesis, we demonstrate the fabrication of millimeter-sized rubidium vapor cells using silicon micro-machining techniques. This method is relatively inexpensive compared to glass-blowing methods and allows rapid, large-scale production. I describe our process flow and demonstrate the presence of rubidium atoms inside our vapor cells. To conclude, suggestions for improvement are discussed.
Spin polarized atomic magnetometers involve the preparation of atomic spins and their detection for monitoring magnetic fields. Due to the fact that magnetic fields are ubiquitous in our world, spin polarized atomic magnetometers are used in a wide range of applications from the detection of magnetic fields generated by the human heart and brain to the detection of nuclear magnetic resonance. In this thesis we developed microfabricated spin polarized atomic magnetometers. These sensors are based on optical pumping and spin-exchange collisions between alkali atoms and noble gases contained in microfabricated millimeter-scale vapor cells. In the first part of the thesis, we improved different features of current microfabricated optical magnetometers. Specifically, we improved the bandwidth of these devices, without degrading their magnetic field sensitivity, by broadening their magnetic resonance through spin-exchange collisions between alkali atoms. We also implemented all-optical excitation techniques to avoid problems, such as the magnetic perturbation of the environment, induced by the radio-frequency fields used in some of these sensors. In the second part of the thesis we demonstrated a microfluidic chip for the optical production and detection of hyperpolarized Xe gas through spin-exchange collisions with optically pumped Rb atoms. These devices are critical for the widespread use of spin polarized atomic magnetometers in applications requiring simple, compact, low-cost, and portable instrumentation.
We report an all-optical atomic vector magnetometer using dual Bell-Bloom optical pumping beams in a Rb vapor cell. This vector magnetometer consists of two orthogonal optical pumping beams, with amplitude modulations at 85Rb and 87Rb Larmor frequencies, respectively. We simultaneously detect atomic signals excited by these two pumping beams using a single probe beam in the third direction, and extract the field orientation information using the phase delays between the modulated atomic signals and the driving beams. By adding a Herriott cavity inside the vapor cell, we improve the magnetometer sensitivity. We study the performance of this vector magnetometer in a magnetic field ranging from 100 mG to 500 mG, and demonstrate a field angle sensitivity better than 10 $\ensuremath{\mu}\mathrm{rad}/{\mathrm{Hz}}^{1/2}$ above 10 Hz.
Research of hot atomic vapor systems has a long history. Recently, much-improved technologies, such as lasers, microwaves and digital/analog control systems, have led to exciting progress in this reviving field. Due to its cryogenic-free and vacuum-free deployment potential, room-temperature and quantum-enabled sensing devices using gaseous atoms have become a popular research topic, and engineering such devices has received considerable attention. Proof-of-principle experiments have been performed demonstrating new ideas such as quantum-enhanced motion sensors, next-generation magnetometers, Rydberg enabled microwave sensors, etc. This thesis focuses on my work related to electromagnetic-field sensing using Rydberg atoms in vapor cells, where Rydberg atoms are excited and detected by electromagnetically induced transparency (EIT) spectroscopy. I first investigate the detection of strong magnetic fields (sim 1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of pm0.12%. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a Lambda-type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.
The Svenja and Regal research groups are collaboratively advancing the development of scalar and vector magnetometers, including integrated vector-scalar systems. This thesis focuses on designing a compact optically pumped vector magnetometer (COPVM) that measures the orientation of the magnetic field through Rabi frequencymeasurements driven by a microwave field, serving as an electromagnetic vector reference, across multiple atomic transitions. We transformed a large optical table setup for the vector magnetometer, designed by Cindy's group, into a 20 cm by 10 cm rectangular optical breadboard, designing and fabricating essential components like optical mounts, a microwave cavity, a thermal oven, Kapton heaters, and photodiode electronics to meet the dimensional constraints of COPVMs. To improve temperature uniformity in the vapor cell, we propose a novel cylindrical oven design supported by thermal simulations and in-situ experimental measurements of the vapor cell's heating temperature. We also designed a low-magnetic polyimide heater to mitigate magnetic field interference caused by conventional electrical heating elements. Additionally, we developed a compact cubic dielectric cavity (15 x 15 x 15 mm) with feeding loop antennas as a microwave source to drive various hyperfine 87Rb transitions (σ± and π). This project analyzes miniaturization challenges for the compact physics package (CPP) and its impact on size, weight, and power (SWaP), aiming to maintain optimal functionality. Components like optics mounts and microwave cavities are fabricated from nonmetallic materials using advanced techniques such as selective laser sintering (SLS) and CNC machining, which reduce magnetic interference and enhance structural alignment. This approach also allows for customization and rapid adjustments, supporting flexible prototyping and optimization. This thesis provides a roadmap for designing a compact optically pumped vector magnetometer, addressing key challenges and laying the foundation for future advancements in miniaturized atomic sensors.
Introduction Shortly after the inception of atomic magnetometry, alkali-vapor magnetometers were being used to measure the Earth's magnetic field to unprecedented precision. During the same era, Bell and Bloom first demonstrated all-optical atomic magnetometry through synchronous optical pumping [1] (see Chapters 1 and 6). In this approach, optical-pumping light is frequency- or amplitude-modulated at harmonics of the Larmor frequency ω L to generate a precessing spin polarization within an alkali vapor at finite magnetic field [2, 3]. Although this technique received considerable attention from the atomic physics community for its applicability to optical pumping experiments, Earth's-field alkali-vapor atomic magnetometers continued to rely on radiofrequency (RF) field excitation for several decades (see Chapter 4). Upon the advent of diode lasers addressing alkali and metastable helium transitions, synchronously pumped magnetometers experienced a revival beginning in the late 1980s. In recent years, such magnetometers have found applications in nuclear magnetic resonance detection [4] (see also Chapter 14), quantum control experiments [5], and chip-scale devices intended for spacecraft use [6] (see also Chapters 7 and 15). All-optical magnetometers possess several advantages over devices that employ RF coils. RF-driven magnetometers can suffer from cross-talk if two sensors are placed in close proximity, since the AC magnetic field driving resonance in one vapor cell can adversely affect the other. All-optical magnetometers are free from such interference. When operated in self-oscillating mode [7], RF-driven magnetometers require an added ±90° electronic phase shift in the feedback loop to counter the intrinsic phase shift between the RF field and the probe-beam modulation.
We report a rubidium atomic magnetometer based on pump-probe nonlinear magneto-optical rotation. The rubidium vapor cell is placed in a five-layer magnetic shield with inner coils that can generate uniform magnetic fields along the direction of pump beam, and the cell is also placed in the center of a Helmholtz coil that can generate an oscillating magnetic field perpendicular to the direction of pump beam. The atoms are optically pumped by circularly polarized pump beam along a constant magnetic field in a period of time, then the pump beam is turned off and a /2 pulse of oscillating magnetic field for 87Rb atoms is applied. After the above process, the individual atomic magnetic moments become phase coherent, resulting in a transverse magnetization vector precessing at the Larmor frequency in the magnetic field. The linearly polarized probing beam is perpendicular to the direction of magnetic field, and can be seen as a superposition of the left and right circularly polarized light. Because of the different absorptions and dispersions of the left and right circularly polarized light by rubidium atoms, the polarization direction of probing beam rotates when probing beam passes through rubidium vapor cell. The rotation of the polarization is subsequently converted into an electric signal through a polarizing beam splitter. Finally, the decay signal related to the transverse magnetization vector is measured. The Larmor frequency proportional to magnetic field is obtained by the Fourier transform of the decay signal. The value of magnetic field is calculated from the formula:B=(2/) f, where and f are the gyromagnetic ratio and Larmor frequency, respectively. In order to measure the magnetic field in a wide range, the tracking lock mode is proposed and tested. The atomic magnetometer can track the magnetic field jump of 1000 nT or 10000 nT, indicating that the atomic magnetometer has strong locking ability and can be easily locked after start-up. The main performances in different magnetic fields are tested. The results show that the measurement range of the atomic magnetometer is from 100 nT to 100000 nT, the extreme sensitivity is 0.2 pT/Hz1/2, and the magnetic field resolution is 0.1 pT. The transverse relaxation times of the transverse magnetization vector in different magnetic fields are obtained, and the relaxation time decreases with the increase of the magnetic field. When the measurement range is from 5000 nT to 100000 nT, the magnetic field sampling rate of the atomic magnetometer can be adjusted in a range from 1 Hz to 1000 Hz. The atomic magnetometer in high sampling rate can measure weak alternating magnetic field at low frequency. This paper provides an important reference for developing the atomic magnetometer with large measurement range, high sensitivity and high sampling rate.