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Physics of Particles and Nuclei Letters

Does a Single Electron Have Wave Properties?

Vadim A. Bednyakov

Published Jul 1, 2021• 2 citations
Publisher

Abstract

Abstract An attempt is made to substantiate the absence of wave properties for a single electron. What is commonly called the corpuscular-wave duality or the wave properties of matter, which appear in the form of a diffraction pattern on the target of certain kind, is a result of the obligatory involvement of a large number of electrons in the diffraction process. In the context of quantum mechanics, a form of the diffraction pattern can be predicted using the rule of adding probability amplitudes, which, in the simplest case, are solutions to the Schrödinger equation for free particles. Therefore, the answer to the question posed in the title sounds something like this: a single electron has no wave properties; however, they become apparent whenever there are many electrons and a suitable target.

DOI
10.1134/s1547477121040038

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East African Scholars Journal of Engineering and Computer Sciences•May 15, 2022•1 citation
Abstract An attempt is made to substantiate the absence of wave properties for a single electron. What is commonly called the corpuscular-wave duality or the wave properties of matter, which appear in the form of a diffraction pattern on the target of certain kind, is a result of the obligatory involvement of a large number of electrons in the diffraction process. In the context of quantum mechanics, a form of the diffraction pattern can be predicted using the rule of adding probability amplitudes, which, in the simplest case, are solutions to the Schrödinger equation for free particles. Therefore, the answer to the question posed in the title sounds something like this: a single electron has no wave properties; however, they become apparent whenever there are many electrons and a suitable target.
This chapter discusses the conceptual foundations of quantum mechanics in the context of matter. Classical physics identified matter with particles and radiation with "waves." Although this description accounted for a large number of very important facts, it became apparent around the turn of the century that other phenomena, such as blackbody radiation and photoelectric effect, are satisfactorily explained only if radiation is described in terms of particles. Sometime later the hypothesis that, conversely, matter has wave properties was proposed by Louis de Broglie and was confirmed by the Davisson-Germer experiment of electron diffraction. In this experiment and similar ones, an electron beam was passed through a regular lattice (crystal), and subsequently showed the well-known diffraction patterns that are characteristic of waves. These results confirmed the theoretical predictions that a monoenergetic electron beam should be described by a plane wave and that the wave vector k of the wave should be related to the momentum p of an individual electron.
Arguments about particles or waves gave way to a recognized need for both particles and waves in the description of radiation. The confusion over particle versus wave properties was resolved by Louis de Broglie. He postulated that since light has a dual wave–particle nature, matter also has this nature. The idea was to perform a diffraction experiment with electrons. An interference pattern was demonstrated not only with electrons, but also with many kinds of material particles like protons and neutrons. However, any attempt to observe an interference pattern with neutral atoms was found difficult by the fact that atoms carried no charge as electrons do and could not penetrate through condensate matter like neutrons. The de Broglie wavelength of an electron in the smallest orbit turns out to be exactly equal to the circumference of the orbit predicted by Bohr. The interpretation of the interference phenomenon becomes more subtle when the light beams are replaced by individual photons or particles.
The author has worked with high-resolution transmission electron microscope for many years, which provides the most direct evidence of wave-particle duality. This relates to Crookes and J. J. Thomson's cathode rays tubes to determine that electron beams are of particle nature. This also relates to Röntgen's discovery that when an electron beam in the cathode rays tube strikes the glass wall, it produces X-rays with extremely high penetrating power. This behavior is consistent with Maxwell-Lorentz’s electrodynamics that electromagnetic waves must be produced whenever electricity carriers alter their velocity. The wave-particle duality proposed by de Broglie refers to accelerated electron beam, rather than single electron. De Broglie emphasized that the crystallographic diffraction pattern produced by his electron beam was completely consistent with the crystallographic diffraction pattern of von Laue by X-rays, therefore, he proposed that electrons possess wave-particle duality. This is actually the selected area electron diffraction pattern in transmission microscope. It is X-rays, not the waves of the electrons themselves to produce diffraction pattern. He extended this to the wave-particle duality of all matter and light. Schrödinger directly introduced de Broglie's electron beam behavior into electron wave in atoms. It was just at this stage that illogical reasoning occurred, making the quantum theory increasingly difficult to understand.
This chapter examines the wave properties of matter. Early attempts to extend the quantum ideas to the theory of matter had some limited success, but did not progress very far. Another radical idea was required before a satisfactory theory could be developed. As light has both wave and particle properties, perhaps the same is true of 'ordinary' particles such as electrons. This bold suggestion was made by Louis de Broglie in 1923, and within a few years it had been confirmed experimentally. De Broglie's wave hypothesis formed the basis for Schrödinger's equation, which was found capable of predicting the allowed energy levels in atoms and molecules, and must be regarded as one of the most important mathematical equations of modern science. Before discussing these ideas, the chapter begins by considering the classical mechanics of particles, reviewing some simple concepts that form an essential background to the quantum theory of matter.
The simplest but deepest questions of the philosophy of quantum mechanics are these: Are quantum systems waves, or are they particles? Are they both or are they neither? When light bounces an electron out of the surface of an alkali metal it behaves like a particle. Light carries momentum but also a punch. Just as there is no such thing as half a punch, so there is no such thing as half a quantum of light. On the other hand, the shadow formed on a screen by an object has soft edges, edges which get softer as the object is moved away from the screen. Light exhibits the phenomena of diffraction and interference and so is wavelike. This dual behaviour of light, and indeed of matter itself, is called wave-particle duality. The wave nature of a quantum system is reflected in wave mechanics which assigns a wave-function to the system. But the dual nature of light was noticed before Schrodinger developed the wave-mechanical formalism in 1926. In fact, it goes back at least as far as Einsteins explanation of the photoelectric effect in 1905. Wave-particle duality is not something that arises within the quantum mechanical formalism. It is something which is expressed within it, and is something which is best discussed in terms of the paradoxes that quantum experiments force upon physics. In fact, the simplest and most immediately disturbing of the quantummechanical paradoxes arise out of wave-particle duality. We take the two-slit experiment and the delayed-choice experiment as examples.
The long history of the dispute among physicists as to whether matter is composed of particles or waves is reviewed. A turning point came at the dawn of the 20th century in the form of the de Broglie momentum-wavelength and Bohr/Planck energy frequency relations. It was on this basis that Schrödinger developed a quantum mechanical differential equation whose solution came to be known as a wave function. The Born Interpretation of these functions holds that their absolute square constitutes a probability distribution which has been used successfully to make predictions of the properties of the system under discussion. It is pointed out that the phenomenon of light refraction played a key role in the development of both Newton’s corpuscular theory of light and the competing theory of Huygens which looks upon light as consisting exclusively of waves. It is shown that Newton’s failure to predict the decrease in the speed of light as it passes from air into water was not because of his belief in the particle composition of light, but rather because he not did anticipate that the mass of a photon changes upon entering a medium of higher index of refraction n. By assuming that the energy E of light is equal pc/n, where p is the momentum of the photons and c is the speed of light in free space, it is shown that the experimental dependence of the speed the light on its wavelength as it passes through a transparent medium is derived successfully through the use of Hamilton’s Canonical Equations and Newton’s Second Law of Kinetics. It is suggested that the relationship between particles and waves can be understood by noting that the localized properties of matter exhibit themselves in experiments such as the photoelectric effect where attention can be concentrated on the behavior of a single particle. The corresponding wave properties occur when large numbers of particles are observed under exactly similar circumstances, as for example in electron diffraction. ...........