Quantum Mechanics of Many-Particle Systems

Luca Salasnich

Stephen W. McKnight, Christos Zahopoulos

The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.

Marco Bilardello

The classical limit of quantum mechanics is investigated, by focusing on the study of the center of mass of a many-body system where each particle is described by quantum mechanics. We study how, in the limit when the number of particles diverges and under quite general assumptions, the center of mass of the system is not anymore described by quantum mechanics but by classical mechanics: the center of mass of the system becomes with a well-defined position and momentum, the state of the center of mass is fully determined by its position and by its momentum, and its dynamics is given by the classical law of dynamics. In order to get this result, three assumptions on the many-body system are necessary: the total mass of the system must be much larger than the mass of each particle composing the system; at most a finite number of particles has non-zero correlation in position with an infinite number of particles; finally, when the number of particles composing the system diverge, the variance in position of each particle converges to a finite value. These assumptions are commonly realized for a macroscopic solid and liquid systems. The results obtained in this paper show how the classical limit of quantum mechanics can be naturally achieved without the need to modify quantum mechanics, without the need to have an external environment and without the need of changing the interpretations of quantum mechanics.

Pang Xiao‐feng

We debate first the properties of quantum mechanics and its difficulties and the reasons resulting in these diffuculties and its direction of development. The fundamental principles of nonlinear quantum mechanics are proposed and established based on these shortcomings of quantum mechanics and real motions and interactions of microscopic particles and backgound field in physical systems. Subsequently, the motion laws and wave-corpuscle duality of microscopic particles described by nonlinear Schr?dinger equation are studied completely in detail using these elementary principles and theories. Concretely speaking, we investigate the wave-particle duality of the solution of the nonlinear Schr?dinger equation, the mechanism and rules of particle collision and the uncertainty relation of particle’s momentum and position, and so on. We obtained that the microscopic particles obey the classical rules of collision of motion and satisfy the minimum uncertainty relation of position and momentum, etc. From these studies we see clearly that the moved rules and features of microscopic particle in nonlinear quantum mechanics is different from those in linear quantum mechanics. Therefore, nolinear quantum mechanics is a necessary result of development of quantum mechanics and represents correctly the properties of microscopic particles in nonlinear systems, which can solve difficulties and problems disputed for about a century by scientists in linear quantum mechanics field.