This chapter introduces the basic physics of Bose--Einstein condensation. We first start with why there is a difference between distinguishable and indistinguishable particles in terms of the number of states that are available in a composite system. Then Bose and Einstein's argument of why one expects a high probability of occupation of the ground state is discussed. This is derived then more rigorously for the grand canonical ensemble, showing that at some critical temperature there should be a macroscopic occupation of the ground state. Next, the low-lying energy spectrum of an interacting Bose--Einstein condensate is derived, leading to the Bogoliubov dispersion. The significance of the Bogoliubov dispersion as the origin of superfluidity is then discussed, in terms of superfluditysuperfluidity. Laudau'sLandau's criterion for superfluidity is derived, by general principles of Galilean transformations of Schrodinger's equation.
This chapter introduces the basic physics of Bose--Einstein condensation. We first start with why there is a difference between distinguishable and indistinguishable particles in terms of the number of states that are available in a composite system. Then Bose and Einstein's argument of why one expects a high probability of occupation of the ground state is discussed. This is derived then more rigorously for the grand canonical ensemble, showing that at some critical temperature there should be a macroscopic occupation of the ground state. Next, the low-lying energy spectrum of an interacting Bose--Einstein condensate is derived, leading to the Bogoliubov dispersion. The significance of the Bogoliubov dispersion as the origin of superfluidity is then discussed, in terms of superfluditysuperfluidity. Laudau'sLandau's criterion for superfluidity is derived, by general principles of Galilean transformations of Schrodinger's equation.
1. Define Bose-Einstein condensation in an interacting boson system in term of macroscopic occupation. 2. Introduce the Gross-Pitaevskii equation and its applicable conditions. 3. Derive the hydrodynamic equations and various physical consequences of the hydrodynamics with or without harmonic trap. 4. Introduce sound wave and emphasize the difference between the wave behavior and the diffusive behavior. 5. Introduce the criterion for superfluidity and determine the superfluid critical velocity. 6. Introduce two-fluid hydrodynamics. 7. Introduce the Bogoliubov theory. 8. Introduce various concepts related to quasi-particle, including ground state as vacuum of quasi-particles, the zero-point energy of quasi-particle, quasi-particle lifetime and vacuum fluctuation. 9. Introduce healing length as the characteristic length scale for low-energy physics of an interacting Bose condensate. 10. Summarize the difference between an interacting and non-interacting Bose condensate. 11. Introduce the Bragg spectroscopy. 12. Show that the Bogoliubov theory fails in one-dimension due to the infrared divergence. 13. Discuss the basic idea of the Bethe-ansatz solution and the Tonks-Girardeau limit. 14. Introduce scale invariant quantum gases. 15. Introduce the Josephson effect and the self-trapping as two different transport phenomena driven by phase coherence. 16. Discuss the conjugate relation between the relative phase fluctuation and the relative particle number fluctuation, and show strong enough phase fluctuation renders the system into a Fock state. 17. Discuss an example of quantum measurement that can project two independent condensates to a coherent superposition state. 18. Discuss interference effects in density and density-density correlations. 19. Discuss the relation between the instability of the Sch\"odinger Cat state and the stability of symmetry breaking.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.
Abstract This chapter describes the mechanism of Bose–Einstein condensation in the simplest ideal Bose gas case. An explicit expression for the critical temperature is derived in the analytically soluble case of a gas confined in a box. Various thermodynamic quantities are calculated above and below the critical temperature. Emphasis is given to the isothermal compressibility which diverges below the critical temperature. The behaviour of the off-diagonal one-body density matrix is discussed. Results for the fluctuations of the single-particle occupation numbers are derived in both the canonical and grand canonical ensembles.
Bose-Einstein condensation, superfluidity, and superconductivity are quantum mechanics made visible. They mark the boundary between the classical and the quantum worlds, and they show the macroscopic role of quantum mechanics in condensed matter. This book presents these phenomena in terms of particles, their positions, and their momenta, giving a concrete visualisation and description that is not possible with traditional wave functions. A single approach that bridges the classical-quantum divide provides new insight into the role of particle interactions in condensation, the nature of collisions in superfluid flow, and the physical form of Cooper pairs in high-temperature superconductors. High-temperature superconductivity is explored with quantum statistical mechanics, which links it to Bose-Einstein condensation. Identifying a new mechanism for Cooper pairing, this explains the differences between the low- and high-temperature superconducting regimes and the role of the molecular structure of the conductor. The new perspective offered by this book on Bose-Einstein condensation, superfluidity, and high-temperature superconductivity gives particle-based explanations as well as mathematical and computational methods for these macroscopic quantum phenomena so that readers understand the role of particle interactions and structure in the physics of these phenomena. This book will appeal to undergraduate and graduate students, lecturers, academics, and scientific researchers in the fields of Bose-Einstein condensation and condensates, superfluidity, and superconductivity. It will also be of interest to those working with thermodynamics, statistical mechanics, statistical physics, quantum mechanics, molecular dynamics, materials science, condensed matter physics, and theoretical chemistry. Key Features: · Explores Bose-Einstein condensation with new evidence for multiple condensed states and novel Monte Carlo simulations for interacting bosons · Establishes the thermodynamic nature of condensed bosons from an analysis of fountain pressure measurements, including that they carry energy and entropy, and the thermodynamic principle of superfluid flow · Derives equations of motion for condensed bosons, and performs molecular dynamics simulations of the viscosity with molecular trajectories that give rise to superfluidity · Identifies the mechanism for electron pairing in high-temperature superconductivity
Abstract This chapter presents a general discussion of the phenomenon of superfluidity, starting from the famous Landau criterion for the critical velocity. The Landau expression for the normal (non-superfluid) component of the gas, expressed in terms of the elementary excitations of the system, is derived. The relationship between Bose–Einstein condensation and the phenomenon of superfluidity is outlined, with special focus on the role played by the phase of the order parameter, whose gradient fixes the velocity of the superfluid. The chapter derives the hydrodynamic equations of superfluids at both zero and finite temperatures and discuss the solutions for first and second sound. The formalism of quantum hydrodynamics is presented, with an application to the Beliaev decay of phonons and to the calculation of the fluctuations of the phase. It also discusses the consequences for superfluidity on the rotational properties and the spatial structure of vortex lines.