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Science

Shielding ultracold molecules

Yury Suleymanov

Published Aug 12, 2021• 0 citations
Publisher

Abstract

Ultracold Molecules Ultracold molecules hold promise for a wide range of exciting applications. However, such applications are currently hampered by the limited number of ultracold molecular ensembles that can be created and by their short lifetimes. Anderegg et al. used a microwave dressing field to tune the collisional properties of calcium monofluoride molecules trapped in optical tweezers. This approach allowed a sixfold suppression of inelastic trap-loss collisions. This scheme paves the way for the creation of a variety of long-lived ultracold molecular ensembles. Science , abg9502, this issue p. [779][1] [1]: /lookup/doi/10.1126/science.abg9502

DOI
10.1126/science.373.6556.754-h

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Ultracold Molecules
Ultracold molecules hold promise for a wide range of exciting applications. However, such applications are currently hampered by the limited number of ultracold molecular ensembles that can be created and by their short lifetimes. Anderegg et al. used a microwave dressing field to tune the collisional properties of calcium monofluoride molecules trapped in optical tweezers. This approach allowed a sixfold suppression of inelastic trap-loss collisions. This scheme paves the way for the creation of a variety of long-lived ultracold molecular ensembles.
Science , abg9502, this issue p. 779
Harnessing the potential wide-ranging quantum science applications of molecules will require control of their interactions. Here, we used microwave radiation to directly engineer and tune the interaction potentials between ultracold calcium monofluoride (CaF) molecules. By merging two optical tweezers, each containing a single molecule, we probed collisions in three dimensions. The correct combination of microwave frequency and power created an effective repulsive shield, which suppressed the inelastic loss rate by a factor of six, in agreement with theoretical calculations. The demonstrated microwave shielding shows a general route to the creation of long-lived, dense samples of ultracold polar molecules and evaporative cooling.
Cold Molecules Arrays of optical tweezers have been used to trap atoms, but trapping and laser-cooling molecules in this setting is tricky. Such an approach would, however, be generalizable to many molecular species. Anderegg et al. created an optical tweezer array of calcium monofluoride molecules, which were laser cooled to their ground state (see the Perspective by Kotochigova). By distinguishing between single and multiple molecules in the tweezers, the researchers were able to observe molecular collisions. Boasting exquisite control over individual molecules, the optical tweezer array platform holds much promise for extending the applications of ultracold molecules. Science , this issue p. [1156][1]; see also p. [1079][2] [1]: /lookup/doi/10.1126/science.aax1265 [2]: /lookup/doi/10.1126/science.aay3989
Tweezing cold molecules Arrays of optical tweezers have been used to trap atoms, but trapping and laser-cooling molecules in this setting is tricky. Such an approach would, however, be generalizable to many molecular species. Anderegg et al. created an optical tweezer array of calcium monofluoride molecules, which were laser cooled to their ground state (see the Perspective by Kotochigova). By distinguishing between single and multiple molecules in the tweezers, the researchers were able to observe molecular collisions. Boasting exquisite control over individual molecules, the optical tweezer array platform holds much promise for extending the applications of ultracold molecules. Science , this issue p. 1156 ; see also p. 1079
We propose a method to suppress collisional loss in strongly dipolar, rotationally excited ultracold molecules using a combination of static (dc) and microwave (ac) electric fields. By tuning two excited pair molecular rotational states into a Förster resonance with a dc field, simultaneously driving excited rotational transitions with an ac field removes all long-range bound states, allowing near complete suppression of all two- and three-body collisional loss channels. While permitting tunable dipolar and anti-dipolar interactions, this bound-state-free ac/dc scheme is not subject to photon-changing collisions that are the primary source of two-body loss in shielding with two microwave fields, used to achieve the first molecular Bose-Einstein condensate [Bigagli et al., Nature 631, 289 (2024)]. Using NaCs as a representative example for strongly dipolar molecules, close-coupling calculations are performed to show that bound-state-free shielding can achieve ratios of elastic-to-loss rates ≳106\gtrsim 10^{6}≳106 at 100 nK, with currently accessible ac and dc field generation technologies. This work opens new opportunities for realizing large, long-lived samples of strongly interacting degenerate molecular gases with tunable long-range interactions.
Ultracold Chemistry Because reactive collisions limit the lifetime of ultracold molecular ensembles, controlling chemical reactivity at ultralow temperatures has been a long-standing goal. Using large electric fields that trigger resonant dipolar interactions between potassium-rubidium molecules trapped in a quasi–two-dimensional geometry, Matsuda et al. report suppression of the reactive loss rate in the vicinity of the dipolar-mediated resonances by up to an order of magnitude below the background value. The proposed shielding mechanism is general and is expected to be effective in three-dimensional geometry. It could also be used for creating long-lived quantum molecular gases of other polar molecules under strong electric fields. Science , this issue p. [1324][1] [1]: /lookup/doi/10.1126/science.abe7370
Ultracold dipolar molecules hold great promise for the creation of exotic quantum states of matter, but the realization of long-lived molecular bulk samples with strong dipole-dipole interactions has remained challenging. In this work, we realized a collisionally stable gas of ultracold ground state molecules with a lifetime of several seconds. Utilizing double-microwave dressing, we achieved an extreme suppression of inelastic two- and three-body losses by factors of more than 10,000 and 1000, respectively. We found that losses remained suppressed across a wide range of dipole-dipole interactions, allowing the continuous tuning of the dipolar length from −21,000 to 12,000 a 0 , where a 0 is the Bohr radius. Combined with the recent realization of Bose-Einstein condensation of dipolar molecules, our findings open the door to the exploration of strongly dipolar quantum liquids.