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On the magnitude of dissipation in open quantum systems

Patrick M. Hayden, Jonathan Sorce

Published Aug 18, 2021• 1 citation
OpenAlex

Abstract

If an open quantum system is initially uncorrelated from its environment, then its dynamics can be written in terms of a Lindblad-form master equation. The master equation is divided into a unitary piece, represented by an effective Hamiltonian, and a dissipative piece, represented by a hermiticity-preserving superoperator; however, the division of open system dynamics into unitary and dissipative pieces is non-unique. For finite-dimensional quantum systems, we resolve this non-uniqueness by specifying a norm on the space of dissipative superoperators and defining the canonical Hamiltonian to be the one whose dissipator is minimal. We show that the canonical Hamiltonian thus defined is equivalent to the Hamiltonian initially defined by Lindblad, and that it is uniqueley specified by requiring the dissipator's jump operators to be traceless. For a system weakly coupled to its environment, we give a recursive formula for computing the canonical effective Hamiltonian to arbitrary orders in perturbation theory, which we can think of as a perturbative scheme for renormalizing the system's bare Hamiltonian.

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•Sep 24, 2021•1 citation
If an open quantum system is initially uncorrelated from its environment, then its dynamics can be written in terms of a Lindblad-form master equation. The master equation is divided into a unitary piece, represented by an effective Hamiltonian, and a dissipative piece, represented by a hermiticity-preserving superoperator; however, the division of open system dynamics into unitary and dissipative pieces is non-unique. For finite-dimensional quantum systems, we resolve this non-uniqueness by specifying a norm on the space of dissipative superoperators and defining the canonical Hamiltonian to be the one whose dissipator is minimal. We show that the canonical Hamiltonian thus defined is equivalent to the Hamiltonian initially defined by Lindblad, and that it is uniqueley specified by requiring the dissipator's jump operators to be traceless. For a system weakly coupled to its environment, we give a recursive formula for computing the canonical effective Hamiltonian to arbitrary orders in perturbation theory, which we can think of as a perturbative scheme for renormalizing the system's bare Hamiltonian.
Abstract If an open quantum system is initially uncorrelated from its environment, then its dynamics can be written in terms of a Lindblad-form master equation. The master equation is divided into a unitary piece, represented by an effective Hamiltonian, and a dissipative piece, represented by a hermiticity-preserving superoperator; however, the division of open system dynamics into unitary and dissipative pieces is non-unique. For finite-dimensional quantum systems, we resolve this non-uniqueness by specifying a norm on the space of dissipative superoperators and defining the canonical Hamiltonian to be the one whose dissipator is minimal. We show that the canonical Hamiltonian thus defined is equivalent to the Hamiltonian initially defined by Lindblad, and that it is uniquely specified by requiring the dissipator’s jump operators to be traceless, extending a uniqueness result known previously in the special case of Markovian master equations. For a system weakly coupled to its environment, we give a recursive formula for computing the canonical effective Hamiltonian to arbitrary orders in perturbation theory, which we can think of as a perturbative scheme for renormalizing the system’s bare Hamiltonian.
We develop a recursive perturbative expansion for the time-convolutionless generator of an open quantum system in a generalized Lindblad form. This formulation provides a systematic approach to derive the generator at arbitrary order while preserving a Lindblad-like structure, without imposing assumptions on the system or environment beyond an initially uncorrelated state. The generator is written, at all orders, in a canonical form, which also corresponds to the minimal dissipation condition, which uniquely specifies the decomposition of the generator into Hamiltonian and dissipative contributions. To validate the method and show its effectiveness in addressing non-Markovian dynamics and strong-coupling effects, we compute the generator explicitly up to fourth order.
Open quantum systems, which interact with their environments, exhibit non-unitary dynamics that are fundamentally different from the unitary evolution of closed systems. The conventional Jordan canonical form, a powerful tool for analyzing linear operators, falls short in providing a complete and physically intuitive decomposition for the superoperators governing the dynamics of open quantum systems, such as the Lindblad superoperator. This limitation arises from the non-Hermitian and often non-diagonalizable nature of these superoperators, whose spectral properties encode critical information about dissipation, decoherence, and relaxation to steady states. This paper introduces and rigorously develops a novel canonical form specifically tailored for the Lindblad superoperator describing Markovian open quantum systems. We propose a decomposition that systematically separates coherent, dissipative, and coupling components, offering a more profound insight into the underlying physical processes. Our methodology leverages advancements in the theory of non-Hermitian operators and Lie algebraic structures of Lindblad operators to construct this form. We demonstrate that this new canonical representation not only clarifies the spectral properties, including the identification of steady states and decay rates, but also provides a systematic framework for analyzing complex open quantum system dynamics. The proposed canonical form promises to significantly advance the analytical capabilities in quantum information, quantum control, and quantum thermodynamics by offering a clearer, more interpretable representation of non-unitary evolution.
We investigate the algebraic structure underlying the Lindblad equation for finite-dimensional open quantum systems. By introducing a suitable operator representation of the Liouville superoperator, we show that the dynamics can be formulated in terms of a closed algebra of Hermitian operators that is independent of the particular physical model. This formulation reveals that dissipative dynamics requires a substantially richer algebraic structure than purely unitary evolution, thereby providing a clear characterization of the additional complexity introduced by the Lindbladian. The resulting framework naturally leads to parametrizations of the dynamical map and to differential equations governing its evolution. We further derive recursion relations that enable the efficient construction of the algebra for systems of increasing dimension. Because the algebraic basis is universal, while all model-dependent information enters through a single set of coefficients, the proposed approach significantly reduces the computational cost of constructing the Liouville superoperator compared with direct methods. To facilitate the implementation of the method, we provide a Mathematica notebook containing a one-qubit example that can be systematically extended to an arbitrary number of qubits. The proposed framework therefore provides both a general mathematical description of finite-dimensional Lindblad dynamics and a practical foundation for efficient analytical and numerical implementations.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open-system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat, and entropy production, formulate the first and second laws of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.