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Quantum adiabatic cycles and their breakdown

Nicolò Defenu

Published Jan 1, 2021• 8 citations
Publisher

Abstract

The assumption that quasi-static transformations do not quantitatively alter the equilibrium expectation of observables is at the heart of thermodynamics and, in the quantum realm, its validity may be confirmed by the application of adiabatic perturbation theory. Yet, this scenario does not straightforwardly apply to Bosonic systems whose excitation energy is slowly driven through the zero. Here, we prove that the universal slow dynamics of such systems is always non-adiabatic and the quantum corrections to the equilibrium observables become rate independent for any dynamical protocol in the slow drive limit. These findings overturn the common expectation for quasi-static processes as they demonstrate that a system as simple and general as the quantum harmonic oscillator, does not allow for a slow-drive limit, but it always displays sudden quench dynamics.

DOI
10.3929/ethz-b-000493950

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The assumption that quasi-static transformations do not quantitatively alter the equilibrium expectation of observables is at the heart of thermodynamics and, in the quantum realm, its validity may be confirmed by the application of adiabatic perturbation theory. Yet, this scenario does not straightforwardly apply to Bosonic systems whose excitation energy is slowly driven through the zero. Here, we prove that the universal slow dynamics of such systems is always non-adiabatic and the quantum corrections to the equilibrium observables become rate independent for any dynamical protocol in the slow drive limit. These findings overturn the common expectation for quasi-static processes as they demonstrate that a system as simple and general as the quantum harmonic oscillator, does not allow for a slow-drive limit, but it always displays sudden quench dynamics.
Abstract The assumption that quasi-static transformations do not quantitatively alter the equilibrium expectation of observables is at the heart of thermodynamics and, in the quantum realm, its validity may be confirmed by the application of adiabatic perturbation theory. Yet, this scenario does not straightforwardly apply to Bosonic systems whose excitation energy is slowly driven through the zero. Here, we prove that the universal slow dynamics of such systems is always non-adiabatic and the quantum corrections to the equilibrium observables become rate independent for any dynamical protocol in the slow drive limit. These findings overturn the common expectation for quasi-static processes as they demonstrate that a system as simple and general as the quantum harmonic oscillator, does not allow for a slow-drive limit, but it always displays sudden quench dynamics.
We show a finite-time Otto-like quantum thermodynamic cycle that preserves the adiabatic population structure of a time-dependent harmonic oscillator in the non-quasi-static regime. In the conventional energy representation, finite-rate driving induces non-adiabatic population redistribution and leaves residual excitations after the Hamiltonian has returned to its initial value. We show that this difficulty can be avoided by formulating the dynamics in the Lewis-Riesenfeld invariant representation, without modifying the physical Hamiltonian through auxiliary counterdiabatic driving. For a parametric Mathieu protocol, quantum inertia produces a mismatch between the spatial width of the working mode and its transient dressed energy scale. We propose an experimental implementation of this scheme in a trapped-ion Paul trap using stimulated Raman interactions, with independent control of the laser detuning and beam intersection angle. This provides a finite-time implementation in which the invariant population structure is preserved while the physical trap frequency evolves non-quasi-statically. Our results establish a clear distinction between adiabatic operation and quasi-static driving, providing a route toward finite-time quantum thermal cycles that retain the adiabatic energy structure without requiring the quasi-static limit.
We study the temporal behavior of topological quantum fluids with strong long-range couplings under slow external perturbations, whose rate δδδ approaches the quasi-static limit δ→0δ\to 0δ→0. As expected, due to strong long-range interactions, the system lies in the mean-field universality and the density of defects for drives across the quantum critical point is adiabatic nexc∝δ2n_{\rm exc}\propto δ^{2}nexc​∝δ2. However, if the drive is instead terminated precisely at the edge of the topological non-trivial phase, the number of generated excitations becomes extensive nexc∝O(1)n_{\rm exc}\propto O(1)nexc​∝O(1). This result fundamentally breaks the established universal behavior observed in local topological quantum fluids and demonstrates a novel mechanism for the breakdown of adiabaticity in fermionic systems with strong long-range interactions.
The quantum harmonic oscillator with time-dependent frequency is a paradigmatic model of driven quantum dynamics and one of the few nontrivial systems that admits an exact analytical solution. In this review paper, we present a unified treatment of the time-dependent oscillator based on the Lewis-Riesenfeld invariant method, Bogoliubov transformations and the Ermakov-Pinney equation. We show how these approaches naturally connect to squeezing for the description of excitations production, and to the breakdown of adiabaticity under generic frequency protocols. Exact results for sudden quenches and smooth ramps are discussed in detail. By explicitly bridging invariant methods and squeezing formalism, this review is meant to provide a comprehensive framework for understanding nonequilibrium dynamics in quadratic potentials, with applications ranging from thermodynamics and condensed matter to quantum control theory.
We develop a perturbation theory to estimate the finite time corrections around a quasi static trajectory, in which a quantum system is able to equilibrate at each instant with its environment. The results are then applied to non equilibrium thermodynamics, in which context we are able to provide a connection between the irreversible contributions and the microscopic details of the dynamical map generating the evolution. Turning the attention to finite time Carnot engines, we found a universal connection between the spectral density esponent of the hot/cold thermal baths and the efficiency at maximum power, giving also a new interpretation to already known results such as the Curzon-Ahborn and the Schmiedl-Seifert efficiencies.
Abstract In this work, we give a quantitative answer to the question: how sudden or how adiabatic is a frequency change in a quantum harmonic oscillator (HO)? We do that by studying the time evolution of a HO which is initially in its fundamental state and whose time-dependent frequency is controlled by a parameter (denoted by ϵ ) that can continuously tune from a totally slow process to a completely abrupt one. We extend a solution based on algebraic methods introduced recently in the literature that is very suited for numerical implementations, from the basis that diagonalizes the initial Hamiltonian to the one that diagonalizes the instantaneous Hamiltonian. Our results are in agreement with the adiabatic theorem and the comparison of the descriptions using the different bases together with the proper interpretation of this theorem allows us to clarify a common inaccuracy present in the literature. More importantly, we obtain a simple expression that relates squeezing to the transition rate and the initial and final frequencies, from which we calculate the adiabatic limit of the transition. Analysis of these results reveals a significant difference in squeezing production between enhancing or diminishing the frequency of a HO in a non-sudden way.