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Bulletin of the American Physical Society

Measuring the hyperfine structure within rubidium 5P 3/2 excited-state using Saturated Absorption Spectroscopy

P. M. Rupasinghe, Trieu Le, Elina van Kempen

Published Jun 1, 2021• 0 citations
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In this paper, we describe two complementary nonlinear spectroscopy methods which both allow one to achieve Doppler-free spectra of atomic gases. First, saturated absorption spectroscopy is used to investigate the structure of the 5S 1/2 → 5P 3/2 transition in rubidium. Using a slightly modified experimental setup, Doppler-free two-photon absorption spectroscopy is then performed on the 5S 1/2 → 5D 5/2 transition in rubidium, leading to accurate measurements of the hyperfine structure of the 5D 5/2 energy level. In addition, electric dipole selection rules of the two-photon transition are investigated, first by modifying the polarization of the excitation laser, and then by measuring two-photon absorption spectra when a magnetic field is applied close to the rubidium vapour. All experiments are performed with the same grating-feedback laser diode, providing an opportunity to compare different high-resolution spectroscopy methods using a single experimental setup. Such experiments may acquaint students with quantum mechanics selection rules, atomic spectra and Zeeman effect.
Abstract The Saturated Absorption Spectroscopy (SAS) was performed to measure the hyperfine constants of rubidium 5P1/2 excited state using an external-cavity diode laser (ECDL) operating at 795 nm. We report our measurements for the magnetic dipole coupling constants 120.79(29) and 407.75(57) for 85 Rb and 87 Rb respectively. Our measurement of the 85 Rb hyperfine constant shows a good agreement with previous results and our measurement of the 87 Rb hyperfine constant resolves the discrepancy of results that exists in the literature.