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Russian Journal of Physical Chemistry B

Spin Chain Ferrimagnetism with Competing Exchange Interactions

V. Ya. Krivnov, Д. В. Дмитриев

Published Jan 1, 2021• 5 citations
Publisher

Abstract

Abstract A quantum spin model of a delta chain with exchange interactions of ferro- (F) and antiferromagnetic (AF) types is studied. The model properties significantly depend on the frustration parameter α (the ratio of the constants of AF and F interactions). When α < 1/2, the ground state is ferromagnetic, and at α = 1/2, a quantum phase transition occurs to another phase. Based on the numerical calculations and analysis of the model at large values of α it is concluded that the ground state at α > 1/2 is magnetically ordered and the total spin of the ground state is half the maximum possible spin. Comparison of the properties of the ground state of the classical and quantum models shows that the considered model is an example of a system in which quantum effects are responsible for the appearance of order from disorder.

DOI
10.1134/s199079312101022x

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Abstract A quantum spin model of a delta chain with exchange interactions of ferro- (F) and antiferromagnetic (AF) types is studied. The model properties significantly depend on the frustration parameter α (the ratio of the constants of AF and F interactions). When α < 1/2, the ground state is ferromagnetic, and at α = 1/2, a quantum phase transition occurs to another phase. Based on the numerical calculations and analysis of the model at large values of α it is concluded that the ground state at α > 1/2 is magnetically ordered and the total spin of the ground state is half the maximum possible spin. Comparison of the properties of the ground state of the classical and quantum models shows that the considered model is an example of a system in which quantum effects are responsible for the appearance of order from disorder.
Background. Low-dimensional quantum magnets based on geometrically frustrated lattices are of considerable interest last time. As a typical example of such systems is the delta-chain which is a linear chain of triangles with spins on vertices. The delta-chain with AF exchange interactions is well studied and has a number of unusual properties. However, the same model with competing ferro (F)-and antiferromagnetic (AF) interactions is less studied. The purpose of this work is the study of the anisotropic F-AF delta-chain on the critical line separating different ground state phases, the calculation of the ground state degeneracy, residual entropy etc. Materials and methods. The study of this model is both analytically and numerically. It is proposed a method of construction of exact ground state wave functions and accounting of the number of ground ststes states in each spin sector. The analytical results are confirmed by numerical calculations of finite chains. Results. It is shown that the ground state manifold of the F-AF delta-chain on the critical line consists of localized magnons. Together with isolated magnons there are bound magnon complexes which give dominated contribution in ground state manifold in the thermodynamic limit. Conclusions. Spin systems with macroscopically degenerated ground state and with residual entropy demonstrate significant magnetocaloric effect. Taking into account great progress in a synthesis of frustrated magnets, it can be expected that real compounds of the FAF delta-chain type with parameters close to critical ones will be obtained and these compounds will be used for the construction of effective magnetocooling devices.
Abstract We study the delta-chain with spin-1 on basal sites and spin- 1 2 on apical sites. The Heisenberg interaction between neighbor basal spins is antiferromagnetic (AF) and the interaction between basal and apical spins is ferromagnetic (F). We show that the magnetization curve of this model is the same as that of the spin- 1 2 kagome-like chain with competing Heisenberg interactions. The ground state phase diagram of the latter as a function of the ratio between the AF and F interaction, α, consists of the ferromagnetic, ferrimagnetic and singlet phases. We study the magnetic properties in each ground state phase and analyze the magnetization curves. We show that there are magnetization plateaus and jumps in definite regions of value α. We compare the magnetic properties of considered models with those of the spin- 1 2 delta chain.
Abstract A quantum spin model of a delta-chain with ferro- and antiferromagnetic exchange interactions has been analyzed. Special attention has been paid to the analysis of magnetic properties at the critical point that separates the ferro- and ferrimagnetic phases of the ground state. The ground state is macroscopically degenerate in this case, and the entropy at zero temperature is finite. The gap in the excitation spectrum is exponentially small, and the spectrum itself has a multiscale structure that determined the low-temperature thermodynamics. The results obtained are used to analyze the magnetic properties of recently synthesized molecules with a record-breaking spin value of the ground state.
Using density-matrix renormalization group (DMRG) method, we studied the effect of magnetic frustrations due to next-nearest- neighbor bonds in a system of quasi-one-dimensional Heisenberg antiferromagnetic chain but with ferrimagnetic properties. In this paper, the ground state energy per unit cell, spin correlation function and spin gap are calculated. As a result of the frustrations, the quantum disordered phase with the spin gap appears at the spin order-disorder phase transition point αC≈0.412 to α＝1. And in the region of magnetic-order phase, the increasing magnetic frustrations reduce the magnetic order.
Abstract We propose a novel two-dimensional (2D) frustrated quantum spin-1/2 anisotropic Heisenberg model with alternating ferromagnetic and antiferromagnetic magnetic chains along one direction and antiferromagnetic interactions along the other. The (mean-field) ground state is ferrimagnetic in certain range of the interaction space. Spin-wave theory analysis of the reduction of ordered moments at inequivalent spin sites and the instability of the spin waves suggest a quantum phase transition which has the characteristics of both the frustrated 2D antiferromagnetic S = 1/2 ( J 1 , J 2 ) model and 1D S 1 = 1, S 2 = 1/2 quantum ferrimagnetic model.
Frustrated spin-12model consisting of a linear chain of triangles with ferro (F)- and antiferromagnetic interactions connected by ferromagnetic interactions (triangles chain) is studied. The ground state phase diagram depending on the interaction ratios consists of ferromagnetic, two ferrimagnetic and singlet phases. The magnetic properties in these phases are analyzed both analytically and numerically. We show that in some regions of the singlet phase the magnetization curves have magnetization plateau and magnetization jumps. We study the thermodynamics and its relation to the specific structure of the excitation spectrum of the triangle chain.