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Springer eBooks

Environmental and Primary Quantum State Diffusion

Ian Colin Percival

Published Jan 1, 1995• 0 citations
Publisher
DOI
10.1007/978-1-4899-1391-3_25

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Abstract Primary quantum state diffusion (PSD) theory is an alternative quantum theory from which classical dynamics, quantum dynamics and localization dynamics are derived. It is based on four principles, that a system is represented by an operator, its state by a normalized state vector, the state vector satisfies a Langevin-Itô state diffusion equation, and the resultant density operator for an ensemble must satisfy an equation of elementary Lindblad form. There are three conditions. The ז0 first determines the operator, to within an undetermined universal time constant ז0. The second and third conditions put opposing bounds on ז0. Dissipation of coherence is distinguished from destruction of coherence. The state diffusion destroys coherence and produces the localization or reduction that makes classical dynamics possible. PSD theory is a development of the environmental quantum state diffusion theory of Gisin and Percival and particularly resembles earlier proposals by Gisin and by Milburn. It is also related to the spontaneous localization theories of Ghirardi, Rimini and Weber, of Diósi and of Pearle. The non-relativistic PSD theory is of value only for systems which occupy small regions of space. Special relativity is needed for more extended systems even when they contain only slowly moving massive particles. Experiments on coherence lifetimes and matter interferometry are proposed which either measure ז0 or put bounds on it, and which might distinguish between PSD and ordinary quantum mechanics.

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Abstract Primary quantum state diffusion (PSD) theory is an alternative quantum theory from which classical dynamics, quantum dynamics and localization dynamics are derived. It is based on four principles, that a system is represented by an operator, its state by a normalized state vector, the state vector satisfies a Langevin-Itô state diffusion equation, and the resultant density operator for an ensemble must satisfy an equation of elementary Lindblad form. There are three conditions. The ז0 first determines the operator, to within an undetermined universal time constant ז0. The second and third conditions put opposing bounds on ז0. Dissipation of coherence is distinguished from destruction of coherence. The state diffusion destroys coherence and produces the localization or reduction that makes classical dynamics possible. PSD theory is a development of the environmental quantum state diffusion theory of Gisin and Percival and particularly resembles earlier proposals by Gisin and by Milburn. It is also related to the spontaneous localization theories of Ghirardi, Rimini and Weber, of Diósi and of Pearle. The non-relativistic PSD theory is of value only for systems which occupy small regions of space. Special relativity is needed for more extended systems even when they contain only slowly moving massive particles. Experiments on coherence lifetimes and matter interferometry are proposed which either measure ז0 or put bounds on it, and which might distinguish between PSD and ordinary quantum mechanics.
We theoretically investigate the statistical properties of photon emission of a driven two-level single-molecule system undergoing spectral diffusion induced by nonequilibrium environmental fluctuations. Within the framework of the generating function method and the stochastic Liouville equation, we analyze the influence of the nonequilibrium characteristics of environmental fluctuations respectively governed by nonstationary Ornstein-Uhlenbeck noise and random telegraph noise on the photon counting statistics of the driven single-molecule system. In the slow modulation limit of spectral diffusion, the intensity and statistical fluctuations of photon emission depend on the environmental nonequilibrium characteristics at short time scales, whereas they become independent of the nonequilibrium characteristics of environmental fluctuations in the steady state. In the fast modulation limit of spectral diffusion, neither the line shape nor the Mandel's parameter depends on the environmental nonequilibrium characteristics owing to the rapid relaxation of environmental fluctuations. These findings not only shed light on the role of nonequilibrium environmental fluctuations in shaping the photon emission properties of single-molecule systems but also provide a basis for distinguishing between equilibrium and nonequilibrium characteristics of environmental fluctuations in experimental measurements.