Dynamics play an important role in physics. From classical mechanics, astrophysics, hydrodynamics to quantum physics, the dynamics of physical systems have crucial impact on our understanding of nature. For simple configurations such as in the two-body problem the dynamics can be calculated analytically. However, things get more complicated once the number of contributors in a system increases such as in few- or many-body systems. One way to study such an ensemble is to use a model system where decisive parameters can be controlled. In this thesis I make use of an ultracold cloud of fermionic Lithium-6 atoms close to zero temperature to study dynamics of few- and many-body systems. Two experimental studies to this topic are presented. In the first study, I produced a gas of di-atomic molecules (dimers), consisting of two Lithium-6 atoms in different states, to study the reaction kinetics of the four-body process of a dimer-dimer collision. At temperatures close to absolute zero the internal and external degrees of freedom of the dimers can be well controlled. This allowed us to investigate the kinetics of a single-channel reaction. To resolve the dynamics of the process we heated a gas of molecules and tracked the state of the system as a function of time. We determined the reaction-rate constant of the process for various thermal energies which allowed us to verify the Arrhenius law for molecule-molecule reactions in the ultracold regime. Additionally, we provided first insight into the dependence of this four-body process on the particle interaction. In the second experimental work, I focused on the thermodynamical properties of the ultracold gas. Cooling the gas of Lithium-6 atoms close to zero temperature the gas undergoes a phase transition and superfluidity is established. To study the dynamics in such a gas, we used a local perturbation to produce sound waves. Depending on the excitation scheme we either excited first sound, i.e. a pressure wave, known from classical mechanics, or second sound, i.e. an entropy wave. In the study we focused on second sound and determined the second sound speed as a function of the particle interaction. We found agreement of our results with both - a numerical and an analytical description of the interaction strength dependence of the second sound speed. Besides the experimental work, a theoretical proposal for a novel imaging technique for a 2D ultracold gas in an optical lattice is presented. The scheme is based on a holographic approach and enables the detection of individual particles with only a few hundred scattered photons per atom.
Dynamics play an important role in physics. From classical mechanics, astrophysics, hydrodynamics to quantum physics, the dynamics of physical systems have crucial impact on our understanding of nature. For simple configurations such as in the two-body problem the dynamics can be calculated analytically. However, things get more complicated once the number of contributors in a system increases such as in few- or many-body systems. One way to study such an ensemble is to use a model system where decisive parameters can be controlled. In this thesis I make use of an ultracold cloud of fermionic Lithium-6 atoms close to zero temperature to study dynamics of few- and many-body systems. Two experimental studies to this topic are presented. In the first study, I produced a gas of di-atomic molecules (dimers), consisting of two Lithium-6 atoms in different states, to study the reaction kinetics of the four-body process of a dimer-dimer collision. At temperatures close to absolute zero the internal and external degrees of freedom of the dimers can be well controlled. This allowed us to investigate the kinetics of a single-channel reaction. To resolve the dynamics of the process we heated a gas of molecules and tracked the state of the system as a function of time. We determined the reaction-rate constant of the process for various thermal energies which allowed us to verify the Arrhenius law for molecule-molecule reactions in the ultracold regime. Additionally, we provided first insight into the dependence of this four-body process on the particle interaction. In the second experimental work, I focused on the thermodynamical properties of the ultracold gas. Cooling the gas of Lithium-6 atoms close to zero temperature the gas undergoes a phase transition and superfluidity is established. To study the dynamics in such a gas, we used a local perturbation to produce sound waves. Depending on the excitation scheme we either excited first sound, i.e. a pressure wave, known from classical mechanics, or second sound, i.e. an entropy wave. In the study we focused on second sound and determined the second sound speed as a function of the particle interaction. We found agreement of our results with both - a numerical and an analytical description of the interaction strength dependence of the second sound speed. Besides the experimental work, a theoretical proposal for a novel imaging technique for a 2D ultracold gas in an optical lattice is presented. The scheme is based on a holographic approach and enables the detection of individual particles with only a few hundred scattered photons per atom.
In this Thesis we will theoretically address some issues concerning the Physics of ultracold Fermi gases, all of them with experimental relevance. The field of ultracold gases, and more recently of ultracold Fermi gases, is gathering a lot of experimental and theoretical interest for two main reasons: the great control on the relevant parameters of the problem and the relative simplicity of the minimal theory which is able to correctly describe the system. Building upon this solid background, ultracold gases provided an ideal laboratory for testing more refined theories and also for addressing fundamental issues of quantum mechanics as well as for simulating more complex physical systems such as those encountered in condensed matter. Even if the effective hamiltonian of ultracold gases can be simple, due to the diluteness of the system and the low temperature, which imply low energy physics, the solution of the quantum mechanic equations governing the state of these systems is not always simple. For the static properties usually mean-field solutions exist or perturbative expansions can be produced in some regimes. However Quantum Monte Carlo (QMC) techniques provide more accurate results especially in the strongly interacting regimes. For confined systems it is possible to use QMC only for a few particles, so that, for large number of particles, a fruitful combined use of Density Functional Theory (DFT) and QMC is necessary. The study of the dynamics of ultracold gases has received little attention with QMC techniques, due to the intrinsic computational difficulty of the many-body problem, so that general hydrodynamic equations are often used for studying the propagation of smoothly varying perturbations. In this Thesis we use QMC techniques for studying the problem of ferromagnetism in repulsive or effectively repulsive ultracold gases without a lattice and the problem of the Bardeen-Cooper-Schrieffer to Bose-Einstein-Condensation (BCS-BEC) crossover in two dimensions. We use DFT in the Local Density Approximation (LDA) for calculating the density profiles of ultracold Fermi gases in harmonic magneto-optical traps, starting from QMC equations of state. We study the propagation of first and second sound in ultracold Fermi gases in cylindrical geometry, using the hydrodynamic equations of superfluids.
We study ultracold gases of alkali-metal atoms in the quantum degenerate regime. The interatomic interactions in these type of systems can be tuned using resonances induced by magnetic or electric fields. The tunability of the interactions, together with the possibility of confining the atoms with several kinds of external potentials, allows for a completely novel approach to study basic problems in many-body physics, and moreover, allows to enter regimes which have never been accessible in condensed matter or nuclear physics. For example, this has led to the experimental demonstration of an intimate relation between two types of superfluidity: the crossover from Bose-Einstein condensation of tightly bound molecules to the superfluid behavior related to weakly bound BCS-like pairs. Another experimental landmark was reached when the existence of universal Efimov three-body bound states was proven in experiments with ultracold bosonic cesium atoms. In this thesis, we study several aspects of these strongly interacting and ultracold atomic gases. We develop an analytical model that encapsulates all of the relevant scattering physics in atomic systems where open-channel shape resonances and closedchannel Feshbach resonances give rise to complicated and non-trivial scattering properties. This model provides lots of physical insight and is shown to describe important quantities, such as the molecular energies and scattering phase shifts, with a high level of accuracy. The model is compared to full numerical coupled-channel calculations in two atomic systems: rubidium and lithium. We study the BCS-BEC crossover using a many-body description of the ultracold gas that includes the non-trivial energy dependence of the scattering model. We show that it gives rise to superfluid behavior associated with the formation of BCS-like pairs while the low-energy interactions are repulsive in character. The energy dependence of the interactions is crucial, as it gives rise to attractive interactions at the Fermi energy, necessary for the formation of Cooper pairs. We demonstrate new ways of controlling the interatomic interactions using a combination of magnetic and electric fields. This leads to experimental control of, for instance, the three-body parameter in the context of Efimov physics and of non-universal behavior in the BCS-BEC crossover in fermionic gases. Using a four-body method based on first principles, we solve the molecule-molecule scattering problem to calculate several important properties of bosonic and fermionic Summary 145 molecules that consist of light and heavy atoms. These type of molecules are of current experimental interest, and we predict several exciting relations between three- and four-body observables in these type of systems.
The field of ultra-cold atomic physics allows probing of two-component quantum liquids with a hydrodynamic normal fluid accompanied by superfluid Bose-Einstein condensates (BEC’s), where the experimental results can be compared to theoretical predictions of the behavior of a weakly interacting two fluid system. Hydrodynamicity in quantum systems like BEC's can have influence on multiple aspects of the collective behavior of the system, such as on the oscillation frequency of quadrupole modes, multiple sound modes in the condensate, but also on high-order excitations which resemble standing sound waves. The hydrodynamicity and excitations of the ultra-cold atomic cloud are the main motivation for the experiments presented in this thesis. In the Utrecht experiment large BEC's up to a few hundred million atoms are produced, which are deeply in the hydrodynamic collisional regime. The macroscopic behavior of the cloud of atoms is dominated by inter-atomic collisions since the mean free path of the individual particles is much smaller than the size of the atomic sample and local equilibrium is established. The influence of the hydrodynamicity on the collective excitations can be investigated by measuring the quadrupole frequency of ultra-cold atomic clouds above the transition temperature Tc, where Bose-Einstein condensation occurs. This quadrupole frequency is determined by measuring the collective shape oscillations of the atomic cloud, where the oscillation frequency is influenced by inter-atomic collisions during the shape oscillations due to the hydrodynamicity of the atomic cloud. The hydrodynamic equations predict the existence of two sound modes in ultra-cold atomic gases below Tc. The speeds of sound are dependent on both the temperature and the chemical potential of the atomic cloud. For low enough temperatures or large enough chemical potential these two speeds of sound become comparable and reaching this regime experimentally allows measuring the speed of sound beyond this avoided crossing. An alternate method of measuring the speed of sound of ultra-cold atomic clouds is exploiting the analogy between a standing sound wave-pattern and high order excitations in BEC's, also referred to as Faraday waves. By exciting the wave-pattern with a frequency and measuring the wavenumber k of the wave-pattern, the speed of sound c can be extracted from the linear dispersion relation. In the process of exciting the standing wave-pattern, remarkable dynamics is discovered in the BECs. As a result of the excitation a large array of other modes are excited next to the wave-pattern. These modes are for example the dipole mode, the axial and radial quadrupole modes, and the scissor mode. This gives rise to complex dynamics in this hydrodynamic quantum mechanical system and although the ultra-cold sample is only excited with a very short pulsed excitation, these modes and the wave-pattern show a large degree of reproducibility during several seconds of time evolution.
Second sound is an entropy wave which propagates in the superfluid component of a quantum liquid. Because it is an entropy wave, it probes the thermodynamic properties of the quantum liquid which are determined, e.g., by the interaction strength between the particles of the quantum liquid and their temperature. Here, we study second sound propagation for a large range of interaction strengths within the crossover between a Bose-Einstein condensate (BEC) and the Bardeen-Cooper-Schrieffer (BCS) superfluid. In particular, we investigate the strongly-interacting regime where currently theoretical predictions only exist in terms of an interpolation between the BEC, BCS and unitary regimes. Working with a quantum gas of ultracold fermionic 6Li atoms with tunable interactions, we show that the second sound speed varies only slightly in the crossover regime. We gain deeper insights into sound propagation and excitation of second sound by varying the excitation procedure which ranges from a sudden force pulse to a gentle heating pulse at the cloud center. These measurements are accompanied by classical-field simulations which help with the interpretation of the experimental data. Furthermore, we determine the spatial extension of the superfluid phase and estimate the superfluid density. In the future, this may be used to construct the so far unknown equation of state throughout the crossover.
This thesis covers two fields of research carried out in the context of ultracold Fermi gases: Non-equilibrium physics in the BEC-BCS crossover and the use of machine learning methods in physics. \n\t \nThe BEC-BCS crossover is of particular interest for the investigation of low-temperature superconductivity and related many-body phenomena. We realise the BEC-BCS crossover experimentally by cooling a mixture of two hyperfine states of fermionic lithium atoms far below degeneracy. To tune the interaction between the constituents, we make use of a broad magnetic Feshbach resonance between the states. We achieve temperatures far in the degenerate regime that can be tuned by a trap release heating procedure. Being able to tune temperature and interaction allows us to access the whole BEC-BCS crossover regime and investigate related phenomena. \n\t \nOne key quantity across the crossover is the critical temperature of the thermal to superfluid phase transition that signals condensation of pairs. The critical temperature can be calculated in the limits of weak interactions, however, for strong interactions theoretical treatment is difficult. In this thesis, we use neural networks to explore the critical temperature in the whole crossover regime with unprecedented accuracy. We show that a supervisedly trained neural network can not only detect the critical temperature, but also distinguish between Cooper pairs and Feshbach molecules, which was not possible before. Moreover, we show that an unsupervisedly trained autoencoder network is able to determine the critical temperature without any external input other than time-of-flight pictures. \n\t \nAnother important quantity in the crossover regime is the superfluid gap parameter. We measure the gap by exciting the Higgs mode through radio-frequency modulation of the atom population. In the BCS limit, the frequency of the Higgs mode is given by twice the gap frequency. By observing the frequency dependent response of the system we can therefore measure the gap parameter. Towards strong interactions, the observed feature broadens, signalling an instability of the mode due to the gradual violation of the required particle-hole symmetry. \n\t \nExploring the non-equilibrium behaviour of a Fermi gas in the BEC-BCS crossover might hold the key to understand the formation dynamics of pairs and how to induce superconductivity in a system that does not exhibit superconductivity in its equilibrium state. In this work, we present two ways to expose the system to a sudden change of interaction, resulting in a non-equilibrium response. Firstly, we use a fast radio-frequency transfer of one of the hyperfine states into a different, third state. We observe dynamics on several timescales in the momentum distribution and condensate fraction. Secondly, we develop a new coil system that is able to change the magnetic field at the atom position by tens of Gauss within a few microseconds. We detail the construction, testing and alignment process and present investigations into the long-time response of the system. \n\t \nMachine learning procedures can not only be used for data analysis, but also to improve upon the control over experimental systems. In this work we present a novel approach to improve the detection and correction of experimental errors exponentially. We use two machine learning approaches, principal component analysis and small, fully connected neural networks to create an empirical model of the experimental setup. Using this model allows us to reduce the required amount of data for compensation of noise sources exponentially. We demonstrate both approaches in the context of micromotion compensation on a single trapped ytterbium ion in a radio-frequency Paul trap.
Ultracold atomic gases provide an ideal system with which to study fundamental many-body physics.Exhibiting universal interactions in clean and controllable environments, long-used simple models as well as more exotic models can now be realized.The interplay between theory and experiment is therefore very active, and, in this thesis, I will detail several works, both exact analytic results and numerical calculations, which have impacts on current experiments.I begin with an introduction to the field including a brief discussion of experiments, the microscopic model of two species of interacting fermions, the BCS-BEC crossover and an overview of the various phases of atomic Fermi gases.I then describe the various results of my theoretical investigations, which are divided into five chapters.First, I describe radio frequency (RF) spectroscopy experiments and how they probe the single-particle spectral function.This leads to my results on an exact feature of the spectral lineshape, a universal large-momentum structure which exists for all states of interacting Fermi systems and has been verified in recent angle-resolved RF experiments.Second, I focus on gases which have a normal Fermi liquid ground state and show that their lineshape exhibits a characteristic jump discontinuity.I illustrate this Fermi surface singularity and the previously mentioned universal large momentum tail with explicit calculations.Third, I turn to the low energy structure of the single-particle spectral function in the superfluid state.I argue that sharp low energy quasiparticle excitations exist across the BCS-BEC crossover using a general argument that includes the interaction of fermions with the low-energy collective mode.This is illustrated with an explicit calculation within an approximation scheme.Fourth, I address the trap-induced inhomogeneity and use a Bogoliubov-deGennes analysis to test if a simple local density approximation (LDA) can provide an adequate description of a spin imbalanced Fermi system.Finally, I discuss dynamics of atomic gases motivated by a recent experiment in which two spin-polarized clouds are allowed to collide with each other.Despite the underlying attractive interactions, the clouds are seen to bounce off of each other.Using a hydrodynamic description, I argue that the short and intermediate time dynamics reflects a metastable state in which the effective interaction is repulsive.It is my hope that the work presented in this thesis can be used to gain key insights which inspire future endeavors.6.2 Time dependence of the center-of-mass positions zσ of the two spin clouds at unitarity for an initial separation z↑ (t = 0) = R z , z↓ (t = 0) = -R z using the upper branch energy functional and damping γ = 1.Red (upper) and blue (lower) curves denote the different spin species. . . . . . . . . . . . . . . .71 6.3 The upper branch energy functional obtained from lowest order constraint variational method.(a), energy as a function of the polarization P for various values of k F a s as indicated in the figure.(b), energy as a function of the interaction parameter k F a s for various values of polarization P as indicated in the figure.(c), phase diagram of the interacting two-component Fermi gases.The two vertical red dashed lines indicates the separation between three phases.For 1/(k F a s ) > 1.124, the system is in the Fermi liquid (FL) phase.For 1.124 > 1/(k F a s ) > 0.91, the system is in the partially polarized phase (PP) and for 1/(k F a s ) < 0.91, the system is fully polarized. . . . . .74 6.4 (Color online) Time dependence of the center-of-mass positions zσ of the two spin clouds for k F (0)a s = 2. . . . . . . . . . . . . . . . . . . . . . . . . . .75 6.5 (Color online) Time dependence of the center-of-mass positions zσ of the two spin clouds for k F (0)a s = 0.5. . . . . . . . . . . . . . . . . . . . . . . . . .