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Quantum mechanics (QM): Path integrals in phase space

Jean Zinn‐Justin

Published Apr 15, 2021• 0 citations
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Abstract

Abstract In Chapter 2, a path integral representation of the quantum operator e-β H in the case of Hamiltonians H of the separable form p2/2m + V(q) has been constructed. Here, the construction is extended to Hamiltonians that are more general functions of phase space variables. This results in integrals over paths in phase space involving the action expressed in terms of the classical Hamiltonian H(p,q). However, it is shown that, in the general case, the path integral is not completely defined, and this reflects the problem that the classical Hamiltonian does not specify completely the quantum Hamiltonian, due to the problem of ordering quantum operators in products. When the Hamiltonian is a quadratic function of the momentum variables, the integral over momenta is Gaussian and can be performed. In the separable example, the path integral of Chapter 2 is recovered. In the case of the charged particle in a magnetic field a more general form is found, which is ambiguous, since a problem of operator ordering arises, and the ambiguity must be fixed. Hamiltonians that are general quadratic functions provide other important examples, which are analysed thoroughly. Such Hamiltonians appear in the quantization of the motion on Riemannian manifolds. There, the problem of ambiguities is even more severe. The problem is illustrated by the analysis of the quantization of the free motion on the sphere SN−1.

DOI
10.1093/oso/9780198834625.003.0003

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Abstract Functional integrals are basic tools to study first quantum mechanics (QM), and quantum field theory (QFT). The path integral formulation of QM is well suited to the study of systems with an arbitrary number of degrees of freedom. It makes a smooth transition between nonrelativistic QM and QFT possible. The Euclidean functional integral also emphasizes the deep connection between QFT and the statistical physics of systems with short-range interactions near a continuous phase transition. The path integral representation of the matrix elements of the quantum statistical operator e-β H for Hamiltonians of the simple separable form p2/2m +V(q) is derived. To the path integral corresponds a functional measure and expectation values called correlation functions, which are generalized moments, and related to quantum observables, after an analytic continuation in time. The path integral corresponding to the Euclidean action of a harmonic oscillator, to which is added a time-dependent external force, is calculated explicitly. The result is used to generate Gaussian correlation functions and also to reduce the evaluation of path integrals to perturbation theory. The path integral also provides a convenient tool to derive semi-classical approximations.
Abstract The functional integral representation of the density matrix at thermal equilibrium in non-relativistic quantum mechanics (QM) with many degrees of freedom, in the grand canonical formulation is introduced. In QM, Hamiltonians H(p,q) can be also expressed in terms of creation and annihilation operators, a method adapted to the study of perturbed harmonic oscillators. In the holomorphic formalism, quantum operators act by multiplication and differentiation on a vector space of analytic functions. Alternatively, they can also be represented by kernels, functions of complex variables that correspond in the classical limit to a complex parametrization of phase space. The formalism is adapted to the description of many-body boson systems. To this formalism corresponds a path integral representation of the density matrix at thermal equilibrium, where paths belong to complex spaces, instead of the more usual position–momentum phase space. A parallel formalism can be set up to describe systems with many fermion degrees of freedom, with Grassmann variables replacing complex variables. Both formalisms can be generalized to quantum gases of Bose and Fermi particles in the grand canonical formulation. Field integral representations of the corresponding quantum partition functions are derived.
Operator calculusThe operator calculus developed by Feynman [Fey51] makes it possible to represent functions of (noncommuting) operators as path integrals, with the integrand being the path-ordered exponential of operators, the order of which is controlled by a parameter that varies along the trajectory.This procedure is termed Feynman disentangling.It is also applicable to functions of matrices (say, γ-matrices which are associated with a spinor particle).When applied to the evolution operator, this procedure results in the standard path-integral representation of quantum mechanics.In this chapter we first demonstrate the general technique using the simplest example, a free propagator in Euclidean space, and then consider the path-integral representation of quantum mechanics, as well as propagators in an external electromagnetic field. Free propagatorLet us first consider the simplest propagator of a free scalar field which is given in the operator formalism by the vacuum expectation value of thewith ϕ being the field-operator.The T -product (1.1) obeys the equationwhere d = 4 is the dimension of space-time, however the formulas are applicable at any value of d.In the operator formalism, Eq. (1.2) is a * The ordered products of operators were introduced by Dyson [Dys49].This paper and other classical papers on quantum electrodynamics are collected in the book edited by Schwinger [Sch58].
Consistent dynamics which couples classical and quantum degrees of freedom exists. This dynamics is linear in the hybrid state, completely positive and trace preserving. Starting from completely positive classical-quantum master equations, we derive a general path integral representation for such dynamics in terms of a classical-quantum action, which includes the necessary and sufficient conditions for complete positivity and trace preservation. The path integral we study is a generalization of the Feynman path integral for quantum systems, and the stochastic path integral used to study classical stochastic processes, allowing for interaction between the classical and quantum systems. When the classical-quantum Hamiltonian is at most quadratic in the momenta we are able to derive a configuration space path integral, providing a map between master equations and covariant classical-quantum path integrals.
Coherent quantum physics is quantum physics in terms of a coherent space and an appropriate coherent product. The kinematical structure and the meaning of the quantities are given by the symmetries (invertible coherent maps) of the coherent space. If Z is a coherent manifold, a canonical symplectic form is often canonically determined by the coherent product through the coherent action principle discussed in Section 6.1. In a quantum mechanical context, Z is indeed a classical phase space or an extended phase space-typically a symplectic manifold, a Poisson manifold, or a circle or line bundle over such a manifold that incorporates the classical action variable (encoding the Berry phase under quantization). For example, the Aharonov-Bohm effect [3] needs the bundle formulation. A coherent space and its quantum space provide a classical and a quantum view of the same physical system, discussed in Section 6.2. Section 6.3 shows that symmetries of coherent spaces can be quantized, that is, promoted to linear operators on the quantum space. This leads to quantum dynamics, which in special (completely integrable) situations can be solved in closed form in terms of classical motions on the underlying coherent space, if the latter has a compatible manifold structure. Close relations to concepts from geometric quantization and Kähler manifolds are pointed out in Section 6.4. In order that the quantum space of a coherent space Z can describe physics, one needs not only a distinguished class of coherent states but a more general concept of state. In Sections 6.5-6.6, we give a general abstract setting for states in Lie ∗-algebras, emphasize the essential mathematical features and the close analogy between classical and quantum physics. We illustrate these generalities with a number of examples in Section 6.7. The coherent action principle is put to use in Section 6.8 for numerical quantum physics and an application to quantum chaos. Spectral issues can, in favorable cases, be handled in terms of dynamical Lie algebras, discussed in Section 6.9.