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Advanced Materials

Room‐Temperature Quantum Memories Based on Molecular Electron Spin Ensembles

Samuel Lenz, Dennis König, David Hunger, Joris van Slageren

Published Jun 9, 2021• 21 citations
Publisher

Abstract

Whilst quantum computing has recently taken great leaps ahead, the development of quantum memories has decidedly lagged behind. Quantum memories are essential devices in the quantum technology palette and are needed for intermediate storage of quantum bit states and as quantum repeaters in long-distance quantum communication. Current quantum memories operate at cryogenic, mostly sub-Kelvin temperatures and require extensive and costly peripheral hardware. It is demonstrated that ensembles of weakly coupled molecular spins show long coherence times and can be used to store microwave pulses of arbitrary phase. These studies exploit strong coupling of the spin ensemble to special 3D microwave resonators. Most importantly, these systems operate at room temperature.

DOI
10.1002/adma.202101673

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Whilst quantum computing has recently taken great leaps ahead, the development of quantum memories has decidedly lagged behind. Quantum memories are essential devices in the quantum technology palette and are needed for intermediate storage of quantum bit states and as quantum repeaters in long-distance quantum communication. Current quantum memories operate at cryogenic, mostly sub-Kelvin temperatures and require extensive and costly peripheral hardware. It is demonstrated that ensembles of weakly coupled molecular spins show long coherence times and can be used to store microwave pulses of arbitrary phase. These studies exploit strong coupling of the spin ensemble to special 3D microwave resonators. Most importantly, these systems operate at room temperature.
Quantum memories will be an essential part of many quantum information protocols, including distributed quantum computing, quantum sensing, and the synchronization of repeater nodes. Most efforts toward developing such a quantum memory have been focused on matter-based storage systems, which convert the energy and information from an optical state to an atomic state of matter to be retrieved later. These matter memories, while capable of achieving great storage times, have several limitations; namely, they are inherently narrow bandwidth, they typically do not operate at key telecommunications wavelengths, and often require costly overhead in the form of cryogenics. In this work, we have developed a quantum memory that operates in free space at room temperature, allowing us to avoid all the previously mentioned limitations, and achieve a record-high time-bandwidth product.
Strong coupling between a microwave photon and electron spins, which could enable a long-lived quantum memory element for superconducting qubits, is possible using a large ensemble of spins. This represents an inefficient use of resources unless multiple photons, or qubits, can be orthogonally stored and retrieved. Here we employ holographic techniques to realize a coherent memory using a pulsed magnetic field gradient and demonstrate the storage and retrieval of up to 100 weak 10 GHz coherent excitations in collective states of an electron spin ensemble. We further show that such collective excitations in the electron spin can then be stored in nuclear spin states, which offer coherence times in excess of seconds.
Abstract Hybrid architectures combining complementary quantum systems will be largely used in quantum technologies and the integration of different components is one of the key issues. Thanks to their long coherence times and the easy manipulation with microwave pulses, electron spins hold a potential for the realization of quantum memories. Here, we test diluted oxovanadium tetraphenyl porphyrin (VO(TPP)) as a prototypical molecular spin system for the Storage/Retrieval of microwave pulses when embedded into planar superconducting microwave resonators. We first investigate the efficiency of several pulse sequences in addressing the spins. The Carr-Purcell and the Uhrig Dynamical Decoupling enhance the memory time up to three times with threeπpulses. We then successfully store and retrieve trains of up to 5 small pulses by using a single recovery pulse. These results demonstrate the memory capabilities of molecular spin ensembles when embedded into quantum circuits.
Room-temperature, easy-to-operate quantum memories are essential building blocks for future long distance quantum information networks operating on an intercontinental scale, because devices like quantum repeaters, based on quantum memories, will have to be deployed in potentially remote, inaccessible locations. Here we demonstrate controllable, broadband and efficient storage and retrieval of weak coherent light pulses at the single-photon level in warm atomic cesium vapor using the robust far off-resonant Raman memory scheme. We show that the unconditional noise floor of this technically simple quantum memory is low enough to operate in the quantum regime, even in a room-temperature environment.
Quantum memory capable of storage and retrieval of flying photons on demand is crucial for developing quantum information technologies. However, the devices needed for long-distance links are different from those envisioned for local processing. We present the first hybrid quantum memory-enabled network by demonstrating the interconnection and simultaneous operation of two types of quantum memory: an atomic ensemble-based memory and an all-optical Loop memory. Interfacing the quantum memories at room temperature, we observe a well-preserved quantum correlation and a violation of Cauchy-Schwarz inequality. Furthermore, we demonstrate the creation and storage of a fully-operable heralded photon chain state that can achieve memory-built-in combining, swapping, splitting, tuning, and chopping single photons in a chain temporally. Such a quantum network allows atomic excitations to be generated, stored, and converted to broadband photons, which are then transferred to the next node, stored, and faithfully retrieved, all at high speed and in a programmable fashion.
This article reviews efforts to build a new type of quantum device, which combines an ensemble of electronic spins with long coherence times, and a small-scale superconducting quantum processor. The goal is to store over long times arbitrary qubit states in orthogonal collective modes of the spin-ensemble, and to retrieve them on-demand. We first present the protocol devised for such a multi-mode quantum memory. We then describe a series of experimental results using NV (as in nitrogen vacancy) center spins in diamond, which demonstrate its main building blocks: the transfer of arbitrary quantum states from a qubit into the spin ensemble, and the multi-mode retrieval of classical microwave pulses down to the single-photon level with a Hahn-echo like sequence. A reset of the spin memory is implemented in-between two successive sequences using optical repumping of the spins.