We present the first experimental demonstration of radiation pressure force deflection and direct laser cooling for barium monohydride (BaH) molecules resulting from multiple photon scattering. Despite a small recoil velocity (2.7 mm s −1 ) and a long excited state lifetime (137 ns), we use 1060 nm laser light exciting the X → A electronic transition of BaH to deflect a cryogenic buffer-gas beam and reduce its transverse velocity spread. Multiple experimental methods are employed to characterize the optical cycling dynamics and benchmark theoretical estimates based on rate equation models as well as solutions of the Lindblad master equation for the complete multilevel system. Broader implications for laser cooling and magneto-optical trapping of heavy-metal-containing molecules with narrow transition linewidths are presented. Our results pave the way for producing a new class of ultracold molecules—alkaline earth monohydrides—via direct laser cooling and trapping, opening the door to realizing a new method for delivering ultracold hydrogen atoms (Lane 2015 Phys . Rev . A 92 , 022511).
We demonstrate radiative force deflection by using an optical cycling of the $X{\phantom{\rule{0.16em}{0ex}}}^{2}{\mathrm{\ensuremath{\Sigma}}}_{1/2}^{+}\ensuremath{-}A{\phantom{\rule{0.16em}{0ex}}}^{2}{\mathrm{\ensuremath{\Pi}}}_{1/2}$ electronic transition in diatomic molecule magnesium monofluoride (MgF). For the (0,0) and (0,1) bands of the electronic transition, the Franck-Condon factors---obtained by the dispersed laser-induced fluorescence spectrum---are
f00=0.972 and
f01=0.028, which suggests that the vibrational branching is quasiclosed. Furthermore, the dark Zeeman sublevels are destabilized by applying an external magnetic field. The cycling fluorescence is clearly observed to reveal that the molecular beam is deflected by 4.9 mm via scattering $\ensuremath{\sim}200$ photons per molecule. This work is encouraging toward laser cooling and magneto-optical trapping of MgF molecules.
We demonstrate a quasioptical cycling for the $X(v=0)\ensuremath{\rightarrow}A({v}^{\ensuremath{'}}=0)$ transition and a radiative force-induced deflection on the buffer-gas-cooled BaF molecular beam. The laser-induced fluorescence enhancement with additional sidebands and a polarization modulation scheme indicates that the hyperfine states and the Zeeman sublevels are closed. The quasioptical cycling by repumping the $X(v=1)\ensuremath{\rightarrow}A({v}^{\ensuremath{'}}=0)$ leads to an $\ensuremath{\sim}0.8\ensuremath{-}\mathrm{mm}$ deflection of the beam via scattering $\ensuremath{\sim}150$ photons per molecule, in good agreement with the predictions from our multilevel rate equation model. Further improvement by closing the leakage
X(v=2) and $\mathrm{\ensuremath{\Delta}}$ state allows scattering of thousands of photons and laser cooling and slowing of BaF.