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Optics and Spectroscopy

Relativistic decay of atomic states. Energy approach

M. N. Driker, Л. Н. Иванов

Published Aug 1, 1980• 0 citations
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Two-photon decay of hydrogenlike ions is studied within the framework of second-order perturbation theory, based on the relativistic Dirac's equation. Special attention is paid to the effects arising from the summation over the negative-energy (intermediate virtual) states that occur in such a framework. In order to investigate the role of these states, detailed calculations have been carried out for the $2{s}_{1/2}\ensuremath{\rightarrow}1{s}_{1/2}$ and $2{p}_{1/2}\ensuremath{\rightarrow}1{s}_{1/2}$ transitions in neutral hydrogen H as well as for hydrogenlike xenon Xe53+{\text{Xe}}^{53+}Xe53+ and uranium U91+{\text{U}}^{91+}U91+ ions. We found that for a correct evaluation of the total and energy-differential decay rates, summation over the negative-energy part of Dirac's spectrum should be properly taken into account both for high-ZZZ and low-ZZZ atomic systems.
In this talk we discuss how to combine aspects of the theory of stable relativistic particles and of the theory of non-relativistic decaying particles into a relativistic theory of unstable particles and resonances. For the theory of stable relativistic particles we use Wigner’s description by unitary irreducible representations (UIR) of the Poincaré group [ 1 ] which has been the foundation for relativistic quantum mechanics and field theory [ 2 ]. For the non-relativistic decaying particles we use a time asymmetric quantum mechanics in which the Hilbert space axiom, that allows only symmetric (unitary group) time evolution, is replaced by time asymmetric boundary conditions which lead to an irreversible , semigroup time evolution [ 3 ]. In the limit in which certain contributions to the energy continuum are neglected, this new quantum mechanics leads to the Weisskopf-Wigner approximate methods [ 4 ] for decay, and to the Breit-Wigner energy distribution [ 5 ] for the resonance lineshape. We thus generalize and combine two fundamental contributions of Wigner into a description of relativistic resonances and decaying states. The central concept of this description is the relativistic Gamow vector, which is a generalized eigenvector (ket) of the self-adjoint invariant square mass operator https://www.w3.org/1998/Math/MathML" display="inline"> M 2 = P μ P μ P μ = P 1 μ + P 2 μ in resonance scattering 1±2→ R →3±4) with a complex eigenvalue, a relativistic Breit-Wigner energy distribution, and an exponential time evolution governed by a semigroup of continuous operators in the space of kets.