The phase structures of one-dimensional quantum sine-Gordon–Thirring model with N-impurities coupling are studied in this paper. The effective actions at finite temperature are derived by means of the perturbation and non-perturbation functional integrals method. The stability of coexistence phase is analyzed respectively in the weak and strong coupling case. It is shown that the coexistence phase is not stable when fermions have an attractive potential g < 0, and the stable coexistence phase can form when fermions have an exclude potential g > 0.