High-sensitivity Quantum Diamond Sensing and Applications

Christian L. Degen

Marco Capelli, Abe, Hiroshi, Takeshi Ohshima +6 more

The nitrogen-vacancy (NV) centre in diamond is a perfect candidate for quantum sensing applications applied to numerous fields of science. Past studies improved the sensitivity of diamonds containing NV centres by increasing their density or prolonging their coherence time. However, few studies discussed the effects of other defects inside the diamond crystal on the sensitivity of the NV centres. In this study, we demonstrated the implication of single substitutional nitrogen defects on the fluorescence emission, charge state stability, coherence time and sensitivity of the NV centres. We found that there is an optimal concentration of nitrogen defects that allows diamond samples to have a high-density of NV centres and high fluorescence without significantly affecting the coherence time. This results will inform the correct choice of diamond characteristics for current and future quantum sensing applications with the NV centres.

睦子 波多野, Mutsuko Hatano

Marco Capelli, Hiroshi Abe, Takeshi Ohshima +6 more

The nitrogen-vacancy (NV) centre in diamond is a perfect candidate for quantum sensing applications applied to numerous fields of science. Past studies improved the sensitivity of diamonds containing NV centres by increasing their density or prolonging their coherence time. However, few studies discussed the effects of other defects inside the diamond crystal on the sensitivity of the NV centres. In this study, we demonstrated the implication of single substitutional nitrogen defects on the fluorescence emission, charge state stability, coherence time and sensitivity of the NV centres. We found that there is an optimal concentration of nitrogen defects that allows diamond samples to have a high-density of NV centres and high fluorescence without significantly affecting the coherence time. This results will inform the correct choice of diamond characteristics for current and future quantum sensing applications with the NV centres.

Atsumi Yoshimura, Ayumi Kanamoto, Naota Sekiguchi +9 more

Diamond quantum sensors utilizing nitrogen-vacancy (NV) centers in diamond can measure a tiny magnetic-field variation at room temperature with a high linearity and high spatial resolution. Because of these advantages, they have been actively studied for application to measure a biomagnetic field. In biomagnetic sensing applications, it is effective to measure at multiple points simultaneously with high sensitivity. In this study, we developed a highly sensitive diamond quantum sensor that can simultaneously measure the magnetic field at two points at the millimeter interval. We used two diamonds that were split from one HPHT-grown diamond and placed them at the 3-mm interval. A laser-induced fluorescence from the two diamonds were detected by a single photodiode. We applied different bias magnetic fields to each diamond, and thus the magnetic resonances at these diamonds had different resonance frequencies. By applying microwave fields whose frequencies were modulated at different modulation frequencies, the magnetic fields at the two diamonds can be obtained independently after demodulation. The noise spectral densities in the magnetic field measurement at the two diamonds’ locations. Since the measurement was performed outside a magnetic shield, a severe low-frequency environmental noise from railways and power line (50 Hz) noise peaks were observed. We evaluated the field sensitivities at the two diamonds to be 22 pT/√Hz in 25-300 Hz range with neglecting the power-line noise peaks and the environment noise peaks. The capability of simultaneously measuring a magnetic field at two points with the such high sensitivities will facilitate the biomagnetic sensing applications.

Jihongbo Shen, Heng Yuan, Hongyu Tao +6 more

Magnetometry based on diamond nitrogen-vacancy (NV) centers has been extensively studied for applications requiring diverse capabilities, spanning from nanometer spatial resolution to subpicotesla sensitivity. Among various applications, diamond magnetometers can demonstrate high sensitivity magnetic sensing within millimeter-scale size for endoscopic applications. However, the trade-off between sensitivity and spatial resolution of diamond magnetometry makes it difficult to achieve such a probe. In this study, we present a millimeter-scale rigid diamond magnetometer probe with enhanced sensitivity via optimizing the optical design. By coupling the frustum diamond with the miniaturized compound parabolic concentrator (CPC) lens, we enhance the fluorescence collection efficiency by 37% within 4 mm diameter, and the achieved sensitivity is 200 pT/Hz1/2 based on the sample with the resonance linewidth of ~8 MHz. With this verified structure, endoscopes with mm-size probe and picotesla sensitivity can be projected for surgical and industrial applications in the future.