We report the electric field ionization of the n=8--15 levels of Na using field pulses of rise time \ensuremath{\sim}1 \ensuremath{\mu}s. The passage from low to high field is adiabatic, and the fields required for \ensuremath{\Vert}
ml\ensuremath{\Vert}=0, 1, and 2 states are 3.12(9)\ifmmode\times\else\texttimes\fi{}
108${n}_{s}^{\mathrm{\ensuremath{-}}4}$ V/cm, 3.37(11)\ifmmode\times\else\texttimes\fi{}
108${n}_{s}^{\mathrm{\ensuremath{-}}4}$ V/cm, and 3.68(21)\ifmmode\times\else\texttimes\fi{}
108${n}_{s}^{\mathrm{\ensuremath{-}}4}$ V/cm. Here
ns is the effective quantum number in the ionizing field. These values are in agreement with those determined previously for higher-lying states.
Pulsed dye lasers are used to excite sodium atoms into a coherent superposition of high Rydberg
nd(2D23,2D25) states. Analysis of the field ionization behavior of these atoms reveals the time evolution of the superposition state. Rapid application of a weak electric field projects different components of the superposition state onto states having identifiably different field ionization behavior. Analysis of the signal from subsequent field ionization as a function of the time of weak-field application reveals fine-structure quantum beats. These beats result from the time development of the original superposition state. Measurements of the fine-structure quantum beat frequency are presented for the principal quantum numbers
n=32,34,35,36,38,and40.