In quantum information and quantum computation, a bipartite system provides a basic few-body framework for investigating significant properties of thermodynamics and statistical mechanics. A Hamiltonian model for a bipartite system is introduced to analyze the important role of interaction between bipartite subsystems in quantum non-equilibrium thermodynamics. We illustrate discrimination between such quantum thermodynamics and classical few-body non-equilibrium thermodynamics. By proposing a detailed balance condition of the bipartite system, we generally investigate the properties of the entropy and heat of our model, as well as the relation between them.
In quantum information and quantum computation, a bipartite system provides a basic few-body framework for investigating significant properties of thermodynamics and statistical mechanics. A Hamiltonian model for a bipartite system is introduced to analyze the important role of interaction between bipartite subsystems in quantum non-equilibrium thermodynamics. We illustrate discrimination between such quantum thermodynamics and classical few-body non-equilibrium thermodynamics. By proposing a detailed balance condition of the bipartite system, we generally investigate the properties of the entropy and heat of our model, as well as the relation between them.
A consistent theory of non-equilibrium thermodynamics for Markovian open quantum systems has been developed in the late seventies in analogy with Classical Irreversible Thermodynamics. The time-evolution of these open systems is usually described by means of effective master equations in Lindblad form, that turn out to be reliable when there is a separation of time-scales between system and environment, such that memory effects are negligible and the so-called Markovian approximation is justified. In this framework, the variations of energy and entropy in the system are consistently described, distinguishing between heat and work contributions and providing a statement of the second law of thermodynamics as positivity of the entropy production.\nHowever, there is empirical evidence that many physical systems like photosynthetic complexes,\nopto-mechanical resonators and superconducting qubits, just to mention a few, experience more general non-Markovian dynamics. The formulation of the laws of thermodynamics in a non-Markovian setting is matter of current research and represents the main topic of the present work. As a first step, we show that the entropy production defined as in the Markovian case can be negative for a class of non-Markovian dynamics. We argue that this outcome should not be interpreted as a violation of the second law of thermodynamics because the environment must be explicitly taken into account in the balance of entropy in the non-Markovian setting. In order to justify this claim we adopt a more general point of view, studying a closed bipartite quantum system, such that each of the two subsystems plays the role of a finite environment out of equilibrium for the other one. We concentrate on the balance of energy first and construct an effective Hamiltonian for each subsystem using physically reasonable requirements; then we define heat and work as in the standard Markovian treatment, with the effective Hamiltonian replacing the free Hamiltonian. It turns out that, in our framework, the work power is perfectly balanced between subsystems, while the correlations can store a part of energy locally inaccessible and exchange it with both subsystems in the form of heat.\nConcerning the balance of entropy, a quite general formulation of the second law of thermodynamics can be given as follows: under the assumption of a factorized initial state for the compound system, the sum of the total variations of the entropies in the two subsystems is always nonnegative. We show with an explicit example that this general formulation does not correspond to the statement presented in the framework of Markovian master equations, which should not be considered a priori the second law of thermodynamics.\nIn the last part of the thesis we concentrate of the so-called fluctuation relations, that are results extending the thermodynamic formalism beyond the behavior of average quantities. After reviewing the main theoretical outcomes, such as the Jarzynski equality and the Crooks fluctuation theorem, we describe a proposal to access experimentally the work performed on an ensemble of diatomic molecules by a time-dependent electric field coupled with their vibrational degree of freedom. This procedure could then be used to test the quantum Jarzynski equality. With respect to the results so far appeared in the literature, in which the left-hand side of the equality is inferred from an experiment and the right-hand side is computed according to a model, in our proposed setting we should be able to estimate from the experiment both the left-hand side and the right-hand side of the equality, independently.
We establish a fluctuation theorem for an open quantum bipartite system that explicitly manifests the role played by quantum correlation. Generally quantum correlations may substantially modify the universality of classical thermodynamic relations in composite systems. Our fluctuation theorem finds a non-equilibrium parameter of genuinely quantum nature that sheds light on the emerging quantum information thermodynamics. Specifically we show that the statistics of quantum correlation fluctuation obtained in a time-reversed process can provide a useful insight into addressing work and heat in the resulting thermodynamic evolution. We illustrate these quantum thermodynamic relations by two examples of quantum correlated systems.
Recent interest in aspects common to quantum information and condensed matter has prompted a flurry of activity at the border of these disciplines that were far distant until a few years ago. Numerous interesting questions have been addressed so far. Here an important part of this field, the properties of the entanglement in many-body systems, are reviewed. The zero and finite temperature properties of entanglement in interacting spin, fermion, and boson model systems are discussed. Both bipartite and multipartite entanglement will be considered. In equilibrium entanglement is shown tightly connected to the characteristics of the phase diagram. The behavior of entanglement can be related, via certain witnesses, to thermodynamic quantities thus offering interesting possibilities for an experimental test. Out of equilibrium entangled states are generated and manipulated by means of many-body Hamiltonians.
Quantum computing promises exponential speedups for specific computational tasks compared to classical computing. However, the inherent fragility of quantum states—their susceptibility to decoherence—poses a significant challenge to realizing this potential. This work investigates the crucial role of non-equilibrium thermodynamics in governing the dynamics of quantum computation. It argues that the efficiency of quantum algorithms is fundamentally linked to the non-equilibrium interactions between the quantum system (qubits) and its environment. A novel thermodynamic framework is proposed, moving beyond the traditional assumptions of equilibrium. This framework utilizes concepts from non-equilibrium statistical mechanics to model energy transfer and information flow between qubits and the surrounding environment, offering a pathway to understand and potentially mitigate decoherence. Specifically, we introduce a quantum computing heat engine model, formulated using non-equilibrium statistical ensembles, to quantify the impact of environmental fluctuations on qubit coherence. The core claim is that a new thermodynamic understanding is required for optimal quantum algorithm design and control. Key mathematical concepts include the Boltzmann entropy, the Landau free energy, and the quantum master equation. The analysis highlights the need for sophisticated control strategies that actively manage environmental fluctuations rather than passively attempting to isolate the quantum system.
During recent years the interest to dynamics of quantum systems has grown considerably. Quantum many body systems out of equilibrium often manifest behavior, different from the one predicted by standard statistical mechanics and thermodynamics in equilibrium. Since the dynamics of a many body quantum system typically involve many excited eigenstates, with a non-thermal distribution, the time evolution of such a system provides an unique way for investigation of non-equilibrium quantum statistical mechanics. Last decade such new subjects like quantum quenches, thermalization, pre-thermalization, equilibration, generalized Gibbs ensemble, etc. are among the most attractive topics of investigation in modern quantum physics. One of the most interesting themes in the study of dynamics of quantum many-body systems out of equilibrium is connected with the recently proposed important concept of dynamical quantum phase transitions. During the last few years a great progress has been achieved in studying of those singularities in the time dependence of characteristics of quantum mechanical systems, in particular, in understanding how the quantum critical points of equilibrium thermodynamics affect their dynamical properties. Dynamical quantum phase transitions reveal universality, scaling, connection to the topology, and many other interesting features. Here we review the recent achievements of this quickly developing part of low temperature quantum physics. The study of dynamical quantum phase transitions is especially important in context of their connection to the problem of the modern theory of quantum information, where namely non-equilibrium dynamics of many-body quantum system plays the major role.
In bipartite quantum systems commutation relations between the Hamiltonian of each subsystem and the interaction impose fundamental constraints on the dynamics of each partition. Here we investigate work, heat and entropy production in bipartite systems characterized by particular commutators between their local Hamiltonians and the interaction operator. We consider the formalism of (Weimer et al 2008 Europhys. Lett. 83 30008 ), in which heat (work) is identified with energy changes that (do not) alter the local von Neumann entropy, as observed in an effective local measurement basis. We demonstrate the consequences of the commutation relations on the work and heat fluxes into each partition, and extend the formalism to open quantum systems where one, or both, partitions are subject to a Markovian thermal bath. We also discuss the relation between heat and entropy in bipartite quantum systems out of thermal equilibrium, and reconcile the aforementioned approach with the second law of thermodynamics.