Schrödinger's equation can be considered as a diffusion equation with a diffusion coefficient β2=ℏ/2m. In this article, we explore the implications of this view. Rewriting the wave function in a polar form and transforming Schrödinger's equation into two real equations, we show that one of them reduces to the continuity equation, and the other, a nonlinear dynamical equation for the probability density. Considering these two equations as if they were the basic equations of quantum mechanics, we apply them to several one-dimensional quantum systems. We show the dispersive properties in the probability densities of stationary states of a particle in a rigid box and in harmonic potential; quasi-classical Gaussian probability densities of a free particle; and coherent states and squeezed states of the harmonic oscillator. We also present the soliton as a quantum mechanical representation of a free particle. We discuss the meaning of the diffusion coefficient β2 for each quantum system using a density plot.
Schrödinger's equation can be considered as a diffusion equation with a diffusion coefficient β2=ℏ/2m. In this article, we explore the implications of this view. Rewriting the wave function in a polar form and transforming Schrödinger's equation into two real equations, we show that one of them reduces to the continuity equation, and the other, a nonlinear dynamical equation for the probability density. Considering these two equations as if they were the basic equations of quantum mechanics, we apply them to several one-dimensional quantum systems. We show the dispersive properties in the probability densities of stationary states of a particle in a rigid box and in harmonic potential; quasi-classical Gaussian probability densities of a free particle; and coherent states and squeezed states of the harmonic oscillator. We also present the soliton as a quantum mechanical representation of a free particle. We discuss the meaning of the diffusion coefficient β2 for each quantum system using a density plot.
The description of a particle in the quantum system is probabilistic. In the ordinary quantum mechanics the total probability of finding the particle is conserved, i.e. the probability is normalized for all the times. To find a non-constant total probability an imaginary term should be added to the potential energy which is not physical. Recently, generalizations of the ordinary Schrödinger equation have been proposed by using the Feynman path integral and analogy between the Schrödinger equation and diffusion equation. In this work, an integro-differential Schrödinger equation is proposed by using analogy between the Schrödinger equation and diffusion equation. The equation is obtained from the continuous time random walk model with diverging jump length variance and generic waiting time probability density. The equation generalizes the ordinary and fractional Schrödinger equations. One can show that the integro-differential Schrödinger equation can describe a non-constant total probability for a free particle, and it includes the exponential decay which is fundamental for the description of radioactive decay.
In (1) it is shown how the Schrodinger equation can be “forced” in a sense to follow from the Fokker-Planck classical stochastic equation which contains a classical probability density. Other approaches in the literature which are similar use continuity equations and also a classical density. The key to all of these approaches is to assume, in an ad hoc manner it seems, that classical probability is equivalent to W*(x)W(x) where W(x) is a complex function called the wavefunction. In principle, one may write a density as W*(x)W(x). This is mathematically correct even if, for the sake of argument, it is ad hoc. The problem is that for a constant density (i.e. constant momentum and speed), one does not know if W(x)=exp(ipx) or W(x)=exp(-ipx). We consider here the arguments shown in (1). If a free particle has a density(x)=1/L, it may be associated with W(x) = exp(ipx)/sqrt(L). A free particle density, however, is associated with constant p (momentum) and assumes one knows x(t). If one considers the free particle to be trapped in a one-dimensional box with infinite potential walls, it travels to the right with p and then to the left with -p. The density(x) classically is 1/L, where L is the length of the box. The density is constant in time, but the direction of motion is a function of time. Thus, information is lost considering an equation such as the Fokker-Planck equation which uses a density function which does not track the direction of motion in time. In particular, writing density(x) = W*(x)W(x), which is done in (1) and applying this density to a bound particle in a box with infinite walls leads to an equation linear in W(x). Thus exp(ipx) and exp(-ipx) are both possible solutions if V(x)=0. Given that the conservation type equation obtained from the Fokker-Planck (or continuity) equation is linear in W, exp(ipx)+exp(-ipx) is a solution. Thus there is interference which leads to a density which does not match a constant classical density which should apply to a particle moving to the right and then to the left in a bound state because one assumed a classical picture a priori. Simply suggesting that density classical = W*(x)W(x) mathematically does not mean that the a priori classical picture may be dropped. As a result, we argue that there exists a contradiction in approaches which write classical density as W*(x)W(x) and then obtain the Schrodinger equation. As a remedy, we suggest that W(x) does not follow from a theory of classical density=W*(x)W(x), but vice versa. One needs equation which deal with W(x) a priori, and once it is found, one may create a classical density through W*(x)W(x).
This paper elucidates the dual structure of the Schrödinger dynamics in two correlated stages: (1) We first derive the real-valued Schrödinger equation from scratch without referring to classical mechanics, wave mechanics, nor optics, and thereby attain a concrete and clear interpretation of the Schrödinger (wave) function. Beginning with a factorization of the density distribution function of the particles to two component vectors in configuration space, we impose very simple conditions on them such as translational invariance of space-time and the conservation of flux under a given potential function. A real-valued path-integral is formulated as a Green function for the real-valued Schrödinger equation. (2) We then study a quantum stochastic path dynamics in a manner compatible with the Schrödinger equation. The relation between them is like the Langevin dynamics with the diffusion equation. Each quantum path describes a \textquotedblleft trajectory\textquotedblright\ in configuration space representing, for instance, a singly launched electron in the double-slit experiment that leaves a spot one by one at the measurement board, while accumulated spots give rise to the fringe pattern as predicted by the absolute square of the Schrödinger function. We start from the relationship between the Ito stochastic differential equation, the Feynman-Kac formula, and the associated parabolic partial differential equations, to one of which\ the Schrödinger equation is transformed. The physical significance of the quantum intrinsic stochasticity and the indirect correlation among the quantum paths and so on are discussed. The self-referential nonlinear interrelationship between the Schrödinger functions (regarded as a whole) and the quantum paths (as its parts) is identified as the ultimate mystery in quantum dynamics.
BACKGROUND: Sequel to the work on the quantization of nonconservative systems using fractional calculus and quantization of a system with Brownian motion, which aims to consider the dissipation effects in quantum-mechanical description of microscale systems. RESULTS: The canonical quantization of a system represented classically by one-dimensional Fick's law, and the diffusion equation is carried out according to the Dirac method. A suitable Lagrangian, and Hamiltonian, describing the diffusive system, are constructed and the Hamiltonian is transformed to Schrodinger's equation which is solved. An application regarding implementation of the developed mathematical method to the analysis of diffusion, osmosis, which is a biological application of the diffusion process, is carried out. Schrödinger's equation is solved. CONCLUSIONS: The plot of the probability function represents clearly the dissipative and drift forces and hence the osmosis, which agrees totally with the macro-scale view, or the classical-version osmosis.
The Schrödinger equation assumes that a particle behaves as a wave and yields a solution in terms of wave function and the energy of the particle under consideration. Once the wave function is known, then everything about the particle can be deduced from the wave function. This chapter covers the development of the Schrödinger wave equation and its applications to one-dimensional systems. Time-dependent and time-independent Schrödinger equations, bound and scattering states, probability density, probability current and expectation values, the solution of the time-independent 1D-Schrödinger equation for a free particle, infinite as well as finite potential wells, potential steps, and the finite potential barrier are discussed in detail in the chapter. The phenomenon of tunneling, relevance and the importance of the free particle, potential wells and potential barriers to contemporary fields of physics and chemistry, periodic solids and their band structures, the Kronig-Penney model, confined states in quantum wells, and wires and dots are other topics presented in innovative manners in the chapter. The importance of the topics presented here is demonstrated through carefully chosen solved examples and unsolved exercises from contemporary fields of sciences.
We show that a physical correspondence between Brownian motion and quantum mechanics can be established by formal analytic continuation if Wick rotation ( t \→ i t ) is replaced by the mirror symmetric, complex conjugate time transformation t \→ ± i t . Invariance of the square modulus of the wave function under this transformation reveals a tight connection between Born's interpretation of the probability density and the proper time t 2 = −it+it , as being both the result of a time symmetry breaking in the informational content of the microscopic (quantum) world, which takes place as we move to a macroscopic level. We find that under the transformation t \→ ± i t , the Schrödinger equation and its complex conjugate conforms with a stochastic-mechanical model of the Brownian motion of a particle. From the present analysis, Nelson's osmotic velocity arises naturally and the quantum phase function admits a classical interpretation in terms of a continuous (scalar) potential field that influences the motion of the particle. The maximum phase variation defines the direction of the osmotic and current velocity. Whereas the paper focuses on the correlation between quantum mechanics and Ficks's second law for a constant diffusion coefficient, a discussion is also provided on the possibility of a quantum mechanical formulation for anomalous diffusion, where the diffusion coefficient is a function of space and/or time.