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The geometry of passivity for quantum systems and a novel elementary derivation of the Gibbs state

Nikolaos Koukoulekidis, Alexander, Rhea, Hebdige, Tom, Jennings, David

Published Mar 15, 2021• 8 citations
OpenAlex

Abstract

Passivity is a fundamental concept that constitutes a necessary condition for any quantum system to attain thermodynamic equilibrium, and for a notion of temperature to emerge. While extensive work has been done that exploits this, the transition from passivity at a single-shot level to the completely passive Gibbs state is technically clear but lacks a good over-arching intuition. Here, we reformulate passivity for quantum systems in purely geometric terms. This description makes the emergence of the Gibbs state from passive states entirely transparent. Beyond clarifying existing results, it also provides novel analysis for non-equilibrium quantum systems. We show that, to every passive state, one can associate a simple convex shape in a 2-dimensional plane, and that the area of this shape measures the degree to which the system deviates from the manifold of equilibrium states. This provides a novel geometric measure of athermality with relations to both ergotropy and β--athermality.

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Passivity is a fundamental concept that constitutes a necessary condition for any quantum system to attain thermodynamic equilibrium, and for a notion of temperature to emerge. While extensive work has been done that exploits this, the transition from passivity at a single-shot level to the completely passive Gibbs state is technically clear but lacks a good over-arching intuition. Here, we reformulate passivity for quantum systems in purely geometric terms. This description makes the emergence of the Gibbs state from passive states entirely transparent. Beyond clarifying existing results, it also provides novel analysis for non-equilibrium quantum systems. We show that, to every passive state, one can associate a simple convex shape in a 2-dimensional plane, and that the area of this shape measures the degree to which the system deviates from the manifold of equilibrium states. This provides a novel geometric measure of athermality with relations to both ergotropy and β--athermality.
Passivity is a fundamental concept that constitutes a necessary condition for any quantum system to attain thermodynamic equilibrium, and for a notion of temperature to emerge. While extensive work has been done that exploits this, the transition from passivity at a single-shot level to the completely passive Gibbs state is technically clear but lacks a good over-arching intuition. Here, we reformulate passivity for quantum systems in purely geometric terms. This description makes the emergence of the Gibbs state from passive states entirely transparent. Beyond clarifying existing results, it also provides novel analysis for non-equilibrium quantum systems. We show that, to every passive state, one can associate a simple convex shape in a 2 -dimensional plane, and that the area of this shape measures the degree to which the system deviates from the manifold of equilibrium states. This provides a novel geometric measure of athermality with relations to both ergotropy and β --athermality.
Passivity is a fundamental concept in thermodynamics that demands a quantum system's energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept of complete passivity, thermal states and the emergence of a thermodynamic temperature. Here we only consider a single system and show that every passive state except the thermal state is unstable under a weaker form of reversibility. Indeed, we show that given a single copy of any athermal quantum state, an optimal amount of energy can be extracted from it when we utilise a machine that operates in a reversible cycle. This means that for individual systems, the only form of passivity that is stable under general reversible processes is complete passivity, and thus provides a physically motivated identification of thermal states when we are not operating in the thermodynamic limit.
We give a simple and intuitive proof that the only states which are completely passive, i.e., those states from which work cannot be extracted even with infinitely many copies, are Gibbs states at positive temperatures. The proof makes use of the idea of virtual temperatures, i.e., the association of temperatures to pairs of energy levels (transitions). We show that (1) passive states are those where every transition is at a positive temperature and (2) completely passive states are those where every transition is at the same positive temperature.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
Abstract Passivity is a fundamental concept in thermodynamics that demands a quantum system’s energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept of complete passivity, thermal states and the emergence of a thermodynamic temperature. Here we only consider a single system and show that every passive state except the thermal state is unstable under a weaker form of reversibility. Indeed, we show that given a single copy of any athermal quantum state, an optimal amount of energy can be extracted from it when we utilise a machine that operates in a reversible cycle. This means that for individual systems, the only form of passivity that is stable under general reversible processes is complete passivity, and thus provides a physically motivated identification of thermal states when we are not operating in the thermodynamic limit.
Gibbs states play a central role in quantum statistical mechanics as the standard description of thermal equilibrium. Traditionally, their use is justified either by a heuristic, a posteriori reasoning, or by derivations based on notions of typicality or passivity. In this work, we show that Gibbs states are completely characterized by assuming dynamical stability of the system itself and of the system in weak contact with an arbitrary environment. This builds on and strengthens a result by Frigerio, Gorini, and Verri (1986), who derived Gibbs states from dynamical stability using an additional assumption that they referred to as the "zeroth law of thermodynamics", as it concerns a nested dynamical stability of a triple of systems. We prove that this "zeroth law" is redundant and that an environment consisting solely of harmonic oscillators is sufficient to single out Gibbs states as the only dynamically stable states.