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Bulletin of the American Physical Society

Projected wave function study of Z$_2$ spin liquids on the kagome lattice for the spin-1/2 quantum Heisenberg antiferromagnet

Federico Becca, Yasir Iqbal, Didier Poilblanc

Published Feb 29, 2012• 6 citations
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Motivated by recent density-matrix renormalization group (DMRG) calculations [Yan, Huse, and White, Science 332, 1173 (2011)], which claimed that the ground state of the nearest-neighbor spin-$1/2$ Heisenberg antiferromagnet on the kagome lattice geometry is a fully gapped spin liquid with numerical signatures of ${\mathbb{Z}}_{2}$ gauge structure, and a further theoretical work [Lu, Ran, and Lee, Phys. Rev. B 83, 224413 (2011)], which gave a classification of all Schwinger-fermion mean-field fully symmetric ${\mathbb{Z}}_{2}$ spin liquids on the kagome lattice, we have thoroughly studied Gutzwiller-projected fermionic wave functions by using quantum variational Monte Carlo techniques, hence implementing exactly the constraint of one fermion per site. In particular, we investigated the energetics of all ${\mathbb{Z}}_{2}$ candidates (gapped and gapless) that lie in the neighborhood of the energetically competitive U(1) gapless spin liquids. By using a state-of-the-art optimization method, we were able to conclusively show that the U(1) Dirac state is remarkably stable with respect to all ${\mathbb{Z}}_{2}$ spin liquids in its neighborhood, and in particular for opening a gap toward the so-called ${\mathbb{Z}}_{2}[0,\ensuremath{\pi}]\ensuremath{\beta}$ state, which was conjectured to describe the ground state obtained by the DMRG method. Finally, we also considered the addition of a small second nearest-neighbor exchange coupling of both antiferromagnetic and ferromagnetic type, and obtained similar results, namely, a U(1) Dirac spin-liquid ground state.

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Motivated by recent density-matrix renormalization group (DMRG) calculations [Yan, Huse, and White, Science 332, 1173 (2011)], which claimed that the ground state of the nearest-neighbor spin-1/21/21/2 Heisenberg antiferromagnet on the kagome lattice geometry is a fully gapped spin liquid with numerical signatures of Z2{\mathbb{Z}}_{2}Z2​ gauge structure, and a further theoretical work [Lu, Ran, and Lee, Phys. Rev. B 83, 224413 (2011)], which gave a classification of all Schwinger-fermion mean-field fully symmetric Z2{\mathbb{Z}}_{2}Z2​ spin liquids on the kagome lattice, we have thoroughly studied Gutzwiller-projected fermionic wave functions by using quantum variational Monte Carlo techniques, hence implementing exactly the constraint of one fermion per site. In particular, we investigated the energetics of all Z2{\mathbb{Z}}_{2}Z2​ candidates (gapped and gapless) that lie in the neighborhood of the energetically competitive U(1) gapless spin liquids. By using a state-of-the-art optimization method, we were able to conclusively show that the U(1) Dirac state is remarkably stable with respect to all Z2{\mathbb{Z}}_{2}Z2​ spin liquids in its neighborhood, and in particular for opening a gap toward the so-called ${\mathbb{Z}}_{2}[0,\ensuremath{\pi}]\ensuremath{\beta}$ state, which was conjectured to describe the ground state obtained by the DMRG method. Finally, we also considered the addition of a small second nearest-neighbor exchange coupling of both antiferromagnetic and ferromagnetic type, and obtained similar results, namely, a U(1) Dirac spin-liquid ground state.
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Theory of spin liquid on the kagome lattice and application to ZnCu3_33​(OH)6_66​Cl2_22​: Projected wavefunction study
We present a general review of the projective symmetry group classification of fermionic quantum spin liquids for lattice models of spin S=1/2S=1/2S=1/2. We then introduce a systematic generalization of the approach for symmetric Z2{\mathbb{Z}}_{2}Z2​ quantum spin liquids to the one of chiral phases (i.e., singlet states that break time reversal and lattice reflection, but conserve their product). We apply this framework to classify and discuss possible chiral spin liquids on triangular and kagome lattices. We give a detailed prescription on how to construct quadratic spinon Hamiltonians and microscopic wave functions for each representation class on these lattices. Among the chiral Z2{\mathbb{Z}}_{2}Z2​ states, we study the subset of U(1) phases variationally in the antiferromagnetic ${J}_{1}\text{\ensuremath{-}}{J}_{2}\text{\ensuremath{-}}{J}_{d}$ Heisenberg model on the kagome lattice. We discuss static spin structure factors and symmetry constraints on the bulk spectra of these phases.