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Integrated Diamond Nonlinear Optics

Pawel Latawiec

Published Mar 15, 2018• 0 citations
OpenAlex

Abstract

The past decade has seen an explosion of development in new devices, modalities, and architectures for advanced sensing, computation, and communication. This growth has been driven by the massive investments of large consumer-tech companies in data-hungry domains of customer interest. As these companies develop their products and seek a competitive edge, technologies which can provide advantage across application areas by making computation cheaper, or sensors more knowledgeable, or communication faster, are attracting more interest in and outside academia. Photonics, or the study of how to manipulate light, is a broad-based platform that inherently delivers on these promises. Although photonics has been a part of daily life since the invention of the laser, modern needs and aspirational designs which meet those needs far exceed the capabilities of the platforms which have traditionally constituted the photonics toolkit.\nThere are two specific areas where standard photonic materials are lacking - support for visible wavelengths and functionality for quantum optics. Currently, there are many implementations of systems which use visible light or quantum optics on the tabletop, but the drive to scale these technologies and deliver them to the consumer encounters a roadblock in their size and cost. Visible light sensors, for instance, could greatly benefit from conversion into an integrated photonics platform, where the optical components are printed onto a small substrate. However, the standard materials used for such systems (silicon and indium phosphide) absorb visible light, and other materials (like silicon nitride) do not have the attributes required for advanced functionality. More compellingly, there exist very few material platforms which can host the quantum defects required for next-generation technologies like quantum computation or secure communication.\nThe past decade has seen extensive research into an emerging material platform which can deliver on the ability to bring integrated visible photonics and quantum optics to the same chip - diamond. With a broad transparency region (from UV to the far infrared) and high refractive index, diamond makes an excellent material for run-of-the-mill photonic devices. More importantly, it harbors atom-like defects in its crystal lattice - the nitrogen-vacancy, silicon-vacancy, and germanium-vacancy centers, among many more - which provide a direct interface between the photons circulating within the diamond device and the quantum world. Taken together, these simple properties of diamond constitute a powerful approach towards implementation of advanced quantum technologies, such as repeaters for secure quantum communication or even, one day, computers.\nBefore that future arrives, diamond's capability must first be developed. Diamond has only been available in significant quantities for research use for about a decade, and as such, the processing technologies which are taken for granted in silicon or silicon nitride-based work must be redeveloped. Within the context of photonic devices, we discuss different fabrication strategies and their implications for device design. For visible light devices especially, we investigate methods to reduce sidewall roughness for etched structures.\nInterfacing with diamond photonic structures also brings its own unique set of challenges due to its high refractive index and very small material footprint. To this end, we develop a method termed "loaded tapered-fiber coupling" to optically access large, free-standing diamond devices. For size-limited diamond resonators and waveguides, we also develop auxiliary optical waveguides to act as spot-converters for visible wavelengths, an improvement on previous techniques for telecom-range wavelengths.\nFinally, by synthesizing these improvements in fabrication, we embark on a set of experiments in diamond microresonators. Nonlinear optics is an excellent testbed for such improvements, both for diamond's superlative properties in that regard and their high sensitivity to improvements in fabrication. First, we look at a process known as Raman lasing by constructing long path-length resonators.This technique involves the shifting of an input photon by 40 THz via the interaction with the diamond's crystal lattice.The first demonstration in a diamond integrated device was shown with a pump wavelength of 1600 nm, with an output that was tuned over 100 nm and a low threshold. Leveraging the developments in visible photonics for diamond, a second Raman laser was demonstrated, this time at near-visible (720 nm) wavelengths.This too had a Stokes output which was tunable to over 100 nm and a very low threshold. Raman-specific effects such as polarization conversion were also investigated.\nA cousin to the Raman effect, the Kerr nonlinearity plays a key role in so-called microresonator (or Kerr) frequency combs. We survey the possibilities and difficulties in implementation for a diamond platform, highlighting the competition between the Kerr and Raman nonlinearities. Although the outlook for a technologically relevant Kerr comb in diamond is ultimately pessimistic, avenues for improvement are highlighted. Namely, we investigate via simulation a related class of effects, known as supercontinuum generation.Taking advantage of subtleties of the Raman process in diamond, we can find a preferred geometry which enables generation of a broadband light spectrum natively in diamond.\nFinally, we look at alternative applications of diamond, particularly in high-power systems. Due to its excellent thermal conductivity and power-handling capacity, optics fashioned purely out of diamond can show significant advantages compared to other materials. We end with a discussion of the design principles and results stemming from this work.

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The past decade has seen an explosion of development in new devices, modalities, and architectures for advanced sensing, computation, and communication. This growth has been driven by the massive investments of large consumer-tech companies in data-hungry domains of customer interest. As these companies develop their products and seek a competitive edge, technologies which can provide advantage across application areas by making computation cheaper, or sensors more knowledgeable, or communication faster, are attracting more interest in and outside academia. Photonics, or the study of how to manipulate light, is a broad-based platform that inherently delivers on these promises. Although photonics has been a part of daily life since the invention of the laser, modern needs and aspirational designs which meet those needs far exceed the capabilities of the platforms which have traditionally constituted the photonics toolkit.\nThere are two specific areas where standard photonic materials are lacking - support for visible wavelengths and functionality for quantum optics. Currently, there are many implementations of systems which use visible light or quantum optics on the tabletop, but the drive to scale these technologies and deliver them to the consumer encounters a roadblock in their size and cost. Visible light sensors, for instance, could greatly benefit from conversion into an integrated photonics platform, where the optical components are printed onto a small substrate. However, the standard materials used for such systems (silicon and indium phosphide) absorb visible light, and other materials (like silicon nitride) do not have the attributes required for advanced functionality. More compellingly, there exist very few material platforms which can host the quantum defects required for next-generation technologies like quantum computation or secure communication.\nThe past decade has seen extensive research into an emerging material platform which can deliver on the ability to bring integrated visible photonics and quantum optics to the same chip - diamond. With a broad transparency region (from UV to the far infrared) and high refractive index, diamond makes an excellent material for run-of-the-mill photonic devices. More importantly, it harbors atom-like defects in its crystal lattice - the nitrogen-vacancy, silicon-vacancy, and germanium-vacancy centers, among many more - which provide a direct interface between the photons circulating within the diamond device and the quantum world. Taken together, these simple properties of diamond constitute a powerful approach towards implementation of advanced quantum technologies, such as repeaters for secure quantum communication or even, one day, computers.\nBefore that future arrives, diamond's capability must first be developed. Diamond has only been available in significant quantities for research use for about a decade, and as such, the processing technologies which are taken for granted in silicon or silicon nitride-based work must be redeveloped. Within the context of photonic devices, we discuss different fabrication strategies and their implications for device design. For visible light devices especially, we investigate methods to reduce sidewall roughness for etched structures.\nInterfacing with diamond photonic structures also brings its own unique set of challenges due to its high refractive index and very small material footprint. To this end, we develop a method termed "loaded tapered-fiber coupling" to optically access large, free-standing diamond devices. For size-limited diamond resonators and waveguides, we also develop auxiliary optical waveguides to act as spot-converters for visible wavelengths, an improvement on previous techniques for telecom-range wavelengths.\nFinally, by synthesizing these improvements in fabrication, we embark on a set of experiments in diamond microresonators. Nonlinear optics is an excellent testbed for such improvements, both for diamond's superlative properties in that regard and their high sensitivity to improvements in fabrication. First, we look at a process known as Raman lasing by constructing long path-length resonators.This technique involves the shifting of an input photon by 40 THz via the interaction with the diamond's crystal lattice.The first demonstration in a diamond integrated device was shown with a pump wavelength of 1600 nm, with an output that was tuned over 100 nm and a low threshold. Leveraging the developments in visible photonics for diamond, a second Raman laser was demonstrated, this time at near-visible (720 nm) wavelengths.This too had a Stokes output which was tunable to over 100 nm and a very low threshold. Raman-specific effects such as polarization conversion were also investigated.\nA cousin to the Raman effect, the Kerr nonlinearity plays a key role in so-called microresonator (or Kerr) frequency combs. We survey the possibilities and difficulties in implementation for a diamond platform, highlighting the competition between the Kerr and Raman nonlinearities. Although the outlook for a technologically relevant Kerr comb in diamond is ultimately pessimistic, avenues for improvement are highlighted. Namely, we investigate via simulation a related class of effects, known as supercontinuum generation.Taking advantage of subtleties of the Raman process in diamond, we can find a preferred geometry which enables generation of a broadband light spectrum natively in diamond.\nFinally, we look at alternative applications of diamond, particularly in high-power systems. Due to its excellent thermal conductivity and power-handling capacity, optics fashioned purely out of diamond can show significant advantages compared to other materials. We end with a discussion of the design principles and results stemming from this work.
Luminescent lattice defects (so called “color centers”) in diamond provide a robust, solid-state architecture for exploring quantum optics, with many facilitating direct access to highly coherent electron and nuclear spins. The past two decades have seen tremendous advances in our ability to prepare and control the quantum states of these atom-like systems. For instance, demonstrations that leverage the diamond nitrogen vacancy (NV–) center as a spin-photon interface have included the generation of indistinguishable photons, a quantum bit memory exceeding 1 second, entanglement of two distance solid-state qubits, and deterministic long distance quantum teleportation. While diamond color centers are an attractive platform for scalable quantum information processing, the diamond solid-state matrix, by its very nature, inhibits efficient photon collection into either free-space or fiber-optical systems. Due to its large refractive index, emitted photons are inevitably trapped within the diamond crystal by total internal reflection, limiting count rates and overall scalability of information processing via quantum optical protocols. To this end, there has been significant progress towards integrating individual diamond color centers within well-defined radiation channels: namely, those provided by monolithic diamond nanophotonic networks. Currently, on-chip low loss (~ few db/cm) diamond waveguide networks are available, as well as key passive photonic elements like micron scale ring and disk resonators and photonic crystal cavities, with high optical quality (Q) factors. Specifically, we recently demonstrated a scalable ‘angled-etching’ nanofabrication method for realizing nanophotonic networks starting from bulk single-crystal diamond substrates (MJ Burek et al., Nano Letters 2012, MJ Burek et al., Nat Comm. 2014). Angled-etching employs anisotropic oxygen-based plasma etching at an oblique angle to the substrate surface, resulting in suspended optical structures with triangular cross-sections. Using this approach, we demonstrated high Q-factor (> 10^5) optical nanocavities fabricated in bulk single-crystal diamond, operating over a wide wavelength range (visible to telecom). Beyond isolated photonic devices, we have further developed free-standing angled-etched waveguides which efficiently route photons between diamond optical nanocavities, while maintaining physical support through attachment to the bulk substrate. Although on-chip diamond nanophotonics realized by angled-etching continue to mature, efficient off-chip optical coupling schemes which provide near seamless transition of photons on-chip into commercial optical fibers remain an outstanding challenge. This is especially pertinent in applications involving single photons, such as quantum optics with diamond color centers. Herein, we demonstrate a high efficiency fiber-optical interface with aforementioned on-chip diamond nanophotonic networks, achieving > 90% power coupling at both telecom and visible wavelengths. The coupling scheme utilizes a single mode optical fiber, with one end fabricated into a conical taper, to adiabatically transition guided light between on-chip tapered diamond waveguides and off-chip optical fiber networks. Additionally, we develop techniques to robustly pigtail single-mode fibers with diamond waveguide couplers, yielding a packaged technology that may potentially enable deployment in harsh environments, including vacuum, sub-Kelvin cryogenics, or even liquid/biological environments. With these newly developed optical integration schemes, single-crystal diamond is now a viable integrated nanophotonics platform, servicing a range of applications, from non-linear optics and chemical sensing, to quantum science and cavity optomechanics.
Very recently, the interest for quantum technologies by the scientific community and industry has strongly increased. Different types of implementations have been proposed as a practical implementation for a quantum bit. In particular, quantum photonics is a strong candidate for such applications. We are interested in using single photons and single spins in diamond as a solid state host matrix (nanodiamonds or membranes). Integration of nanosources of light is currently a major bottleneck preventing the realisation of all-photonic chips for quantum technologies and nanophotonics applications. Ideally, one needs optical circuitry, on-chip photodetection and on-chip generation of quantum states of light (single photons, entangled photons…). Our recent work on a new platform for quantum photonics using integrated optics can offer an easier and robust way to create compact quantum circuits that can be on chip and scalable. In this context, the coupling between waveguides and single photon emitters is critical. The goal of our research is to efficiently couple single photon emitters with a new platform made of optical glass waveguides. These waveguides are based on the so-called ion-exchange glass technology and is know in the photonics industry for quite some time but has never been used in the context of quantum technologies. Efficient light-matter interface is of primordial importance in this system. To achieve this goal, several paths are undertaken such as the use of dielectric and plasmonic structuration in order to increase the light interaction with the waveguide or to develop fabrication techniques to insert the emitters directly inside the guide (for nanodiamonds). We will show what is our current state of the art for placing single emitters at the right place on our optical waveguides made of ion-exchange in glass and in particular what can be done to improve our first promising results in order to get near unity coupling between the optical bus and single photon emitters. We will show first results with semiconductor nanocrystals (NCs) but also using nitrogen-vacancy and silicon-vacancy defects in nanodiamond. The very first step in of our approach consists in the design of the structured waveguide using electromagnetic FDTD. We demonstrated that it is possible to achieve more than 90% coupling. In practice, before using coloured centres in diamond, we started working with CdSe/ZnS semiconductor nanocrystals. So far, we use straight waveguides defined to be single modes at the nominal wavelength of the emission line of the nanoemitters. The positioning of nanoemitters is still a challenge to be achieved. We developed an original technique based on photopolymerisation of light where the nanocrystals are grafted into a light sensitive polymer and can be placed at adequate positions.
Integrated photonic circuits promise to be foundational for applications in quantum information and sensing technologies, through their ability to confine and manipulate light. A key role in such technologies may be played by spin-active quantum emitters, which can be used to store quantum information or as sensitive probes of the local environment. A leading candidate is the negatively charged nitrogen vacancy (NV−) diamond color center, whose ground spin state can be optically read out, exhibiting long (≈1 ms) coherence times at room temperature. These properties have driven research toward the integration of photonic circuits in the bulk of diamond with the development of techniques allowing fabrication of optical waveguides. In particular, femtosecond laser writing has emerged as a powerful technique, capable of writing light guiding structures with 3D configurations as well as creating NV complexes. In this Perspective, the physical mechanisms behind laser fabrication in diamond will be reviewed. The properties of waveguides, single- and ensemble-NV centers, will be analyzed, together with the possibility to combine such structures in integrated photonic devices, which can find direct application in quantum information and sensing.
The field of photonic integrated circuits (PIC) has flourished in the past two decades, fueling numerous cutting-edge applications across sensing, networking, data interconnect, and quantum information processing. As a guiding material for PIC, Si3_33​N4_44​ has seen extensive use for its ultra-low loss, broad transparency, and diversity in implementation across both thin and thick films. Although the standard, traditional silicon dioxide (SiO2_22​) on silicon (Si) substrates that underpin the majority of Si3_33​N4_44​ photonics face drawbacks in the form of long-wavelength transparency limited by SiO2_22​, high-stress deposition for anomalous dispersion thick-film Si3_33​N4_44​, and leakage loss to the Si layer for low-confinement thin-film Si3_33​N4_44​. Featuring increased long-wavelength transparency into the mid-infrared, low-stress deposition of Si3_33​N4_44​, and a low index, this work investigates sapphire substrates as alternate hosts for Si3_33​N4_44​ photonics with greater spectral coverage and reduced fabrication complexity. This work presents a robust method of fabricating ultra-low loss photonic integrated circuits on a 500-nm-thick Si3_33​N4_44​-on-sapphire platform, exhibiting record-low losses below 0.1  dB/cm0.1 \rm \;dB/cm0.1dB/cm. Implemented using this process are high-Q microrings with intrinsic quality factors in excess of 4.5×1064.5\times10^64.5×106 and coupled-ring photonic molecules to support nonlinear gain. Leveraging the achievable low loss and high-Q, this work further reports the first demonstration of Kerr-comb and soliton generation on the Si3_33​N4_44​-on-sapphire platform. These advances in loss, quality factor, and soliton generation on this versatile, broad-transparency platform pave the way for future work in spectroscopy and quantum-enhanced sensing across previously prohibited spectral regions for Si3_33​N4_44​ photonics with reduced fabrication complexity.
Large Kerr nonlinearities are of significant interest for photonic quantum information processing and can be applied towards developing deterministic single photon sources and implementing deterministic quantum logic gates. The required strong nonlinear interaction between photons can be achieved by enhancing the light-matter interaction using alkali vapors interacting with a tightly confined optical mode area, such as that of a waveguide. The guiding properties of the waveguide over long distances helps in achieving a long interaction length while simultaneously increasing the atom-photon coupling by maintaining a small mode area over the entire guiding length. In this thesis, we explore the large effective Kerr nonlinearities (γ) of Rubidium vapor interacting with the optical mode of hollow-core photonic band-gap fibers (Rb-PBGF) and the tightly confined evanescent field of air-clad silicon nitride waveguides (Rb-chip). We have demonstrated efficient and noiseless frequency conversion at low power levels leveraging the large γ for the Rb-PBGF system. As proof of principle, we have also generated spectrally bright quantum correlated photon-pairs in a warm Rb vapor-cell and have proposed an extension of the experiment in the Rb-PBGF platform, which could lead to near unit photon pair generation efficiency. During the course of the study, we have also significantly improved the Rb-PBGF system by attaining an almost continuous operation lasting for several hours (1000X longer) while generating optical depths (OD's) ~ 50, which are required to attain single photon-level nonlinearity in the Rb-PBGF system. Developing on-chip CMOS [complimentary metal-oxide-semiconductor] compatible Rb vapor based platforms can not only achieve large γ, but also significantly reduce the footprint of the device and make it more compatible with other chip-based platforms. In our present work, we have demonstrated the feasibility of this approach by achieving extended interaction time-scales for, air-clad silicon nitride waveguides coated with aluminum oxide and evanescently coupled to warm Rb vapor. The thin aluminum oxide layer has greatly helped in preventing corrosive damage caused by Rb to the nitride surface that have improved the operational lifetimes by a factor > 100. During the course of our study, we realized the limitations of known platforms towards generating tunable sources of single photons at near-visible wavelengths; a wavelength regime at which great progress has been made for quantum storage and detection. Towards the end of this work, we have experimentally demonstrated a broadband frequency comb at near-visible wavelengths by engineering anomalous dispersion for higher order waveguide modes in silicon nitride microresonators. The underling process of parametric wave-mixing being the same for frequency combs and correlated photon-pair generation; our work opens new possibilities for developing spectrally narrow single photon sources in the near-visible which are compatible with highly nonlinear alkali vapor based systems like the Rb-PBGF and Rb-chip platform.