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Journal of Experimental and Theoretical Physics

Changes in the Atomic Absorption Spectrum in the Field of a Light Wave. I

A. M. Bonch-Bruevich, N. N. Kostin, V. A. Khodovoǐ, V. V. Khromov

Published Jan 1, 1969• 7 citations
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The absorption and reflection spectrum of probe light, interacting with a degenerate two-level system of any transition in the Cs D1 line driven by standing-wave, is experimentally studied. The effect that absorption changes from a transparency dip to an absorption peak when the travelling coupling field is replaced by the standing-wave field can only occur in the hyperfine transition Fg↔Fe ≤ Fg (Fg and Fe are the total angular momentum of the ground and the excited levels respectively), and in this case, a reflection of probe can be generated. It is also examined that the absorption coefficient and reflection efficiency in the transition of Fg > Fe are much higher than that in Fg = Fe. For the transition of Fg < Fe, where coherent population trapping cannot be established, the absorption does not change the sign, and there is no reflection to be observed when the coupling is switched from a travelling to a standing-wave field. As a consequence, only the degenerate two-level systems, where the population is trapped in the ground states, can exhibit steep absorption and reflection of the probe light with a standing-wave coupling. Furthermore, the reflection spectra with an asymmetric profile as the function of one- and two-photon detunings are obtained, which is theoretically explained by the phase mismatch compensation during the process of four-wave mixing in an atomic system. This shows that under the condition of coherent population trapping the nonlinear reflection can be improved with one- and two-photon detunings in a degenerate two-level system.
Two-photon light absorption by an atom situated near to surface of a solid with spectral features in the vicinity of resonance frequencies of transitions of atoms is theoretically investigated. These features can be caused, for example, polariton or exiton resonance of a solid. It is shown, that the two-photon light absorption an atom situated near to surface can essentially differ from those in a free space. The spectrum of a two-photon absorption becomes asymmetric over the difference between exciting light frequency and resonant transition frequency of the atom. It is established, that even small spectral features of solid can give rise to significant changes of a spectrum of a two-photon absorption of light. It is established also, that such changes of a spectrum of a two- photon absorption of light are nonlinear increased with increase of the intensity of the exciting light and with approach of the atom to the surface of solid.