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Geometry and symmetries of multi-particle systems

U. Fano, Dmitry Green, John L. Bohn, Thomas A. Heim

Published Jan 1, 1999• 21 citations
OpenAlex

Abstract

Abstract. The quantum dynamical evolution of atomic and molecular aggregates, from their compact to their fragmented states, is parametrized by a single collective radial parameter. Treating all the remaining particle coordinates in d dimensions democratically, as a set of angles orthogonal to this collective radius or by equivalent variables, by-passes all independent-particle approximations. The invariance of the total kinetic energy under arbitrary d-dimensional transformations which preserve the radial parameter gives rise to novel quantum numbers and ladder operators interconnecting its eigenstates at each value of the radial parameter. We develop the systematics and technology of this approach, introducing the relevant mathematics tutorially, by analogy to the familiar theory of angular momentum in three dimensions. The angular basis functions so obtained are treated in a manifestly coordinate-free manner, thus serving as a flexible generalized basis for carrying out detailed studies of wave function evolution in multi-particle systems.

Related papers

Geometry and symmetries of multi-particle systems

U Fano, Dmitry Green, J L Bohn +1 more

The quantum dynamical evolution of atomic and molecular aggregates, from their compact to their fragmented states, is parametrized by a single collective radial parameter. Treating all the remaining particle coordinates in d dimensions democratically, as a set of angles orthogonal to this collective radius or by equivalent variables, bypasses all independent-particle approximations. The invariance of the total kinetic energy under arbitrary d -dimensional transformations which preserve the radial parameter gives rise to novel quantum numbers and ladder operators interconnecting its eigenstates at each value of the radial parameter. We develop the systematics and technology of this approach, introducing the relevant mathematics tutorially, by analogy to the familiar theory of angular momentum in three dimensions. The angular basis functions so obtained are treated in a manifestly coordinate-free manner, thus serving as a flexible generalized basis for carrying out detailed studies of wavefunction evolution in multi-particle systems.

arXiv:physics/9905052•Journal of Physics B Atomic Molecular and Optical Physics•Jan 1, 1999•35 citations

Generalization to Three Dimensions

Walter Wilcox

Synopsis: Direct product spaces are encountered in the generalization to higher dimensions, and the connection to wave function separability is discussed. The spherical coordinate basis is introduced in preparation for discussing spherically symmetric potentials. Angular momentum operators and properties are examined, and a complete set of compatible observables is determined. The angular momentum eigenvalues and eigenstates are determined using ladder operators, and the connection to spherical harmonics is made. The stage is set for understanding the Schrödinger radial equation.

CRC Press eBooks•Aug 23, 2019•0 citations

Generalization to Three Dimensions

Walter Wilcox

Synopsis: Direct product spaces are encountered in the generalization to higher dimensions, and the connection to wave function separability is discussed. ƒe spherical coordinate basis is introduced in preparation for discussing spherically symmetric potentials. Angular momentum operators and properties are examined, and a complete set of compatible observables is determined. ƒe angular momentum eigenvalues and eigenstates are determined using ladder operators and the connection to spherical harmonics is made. ƒe stage is set for understanding the Schrödinger radial equation.

CRC Press eBooks•Apr 19, 2016•0 citations

Second-quantization and irreducible tensorial sets

Z. Rudzikas

General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.

Cambridge University Press eBooks•Dec 4, 1997•0 citations

All transformations of coordinates that separate the center of mass kinetic energy, their group structure and geometry

L. Fortunato

The most general transformations of coordinates that allow for the exact separation of the kinetic energy operator of a quantum many-body system into total center of mass kinetic energy and internal kinetic energy are found and discussed. It is found (i) that the suitable transformations, depending on the number of particles, have a certain number of free parameters and this allows for the generalization of the Jacobi coordinates to a much larger class of coordinates with the same properties and (ii) that there is a new, uncommon, additive group structure hidden in the transformation matrices that is connected to certain geometric properties of the set of coordinates.

arXiv:0910.2811•Journal of Physics A Mathematical and Theoretical•Jan 19, 2010•2 citations

Quantum Principles and Particles, Second Edition

Walter Wilcox

QUANTUM PRINCIPLES Perspective and Principles Prelude to Quantum Mechanics Stern-Gerlach Experiment Idealized Stern-Gerlach Results Classical Model Attempts Wave Functions for Two Physical-Outcome Case Process Diagrams, Operators, and Completeness Further Properties of Operators/Modulation Operator Reformulation Operator Rotation Bra-Ket Notation/Basis States Transition Amplitudes Three-Magnet Setup Example-Coherence Hermitian Conjugation Unitary Operators A Very Special Operator Matrix Representations Matrix Wave Function Recovery Expectation Values Wrap Up Problems Free Particles in One Dimension Photoelectric Effect Compton Effect Uncertainty Relation for Photons Stability of Ground States Bohr Model Fourier Transform and Uncertainty Relations Schrodinger Equation Schrodinger Equation Example Dirac Delta Functions Wave Functions and Probability Probability Current Time Separable Solutions Completeness for Particle States Particle Operator Properties Operator Rules Time Evolution and Expectation Values Wrap-Up Problems Some One-Dimensional Solutions to the Schrodinger Equation Introduction The Infinite Square Well: Differential Solution The Infinite Square Well: Operator Solution The Finite Potential Barrier Step Potential The Harmonic Oscillator The Attractive Kronig-Penny Model Bound State and Scattering Solutions Problems Hilbert Space and Unitary Transformations Introduction and Notation Inner and Outer Operator Products Operator-Matrix Relationship Hermitian Operators and Eigenkets Gram-Schmidt Orthogonalization Process Compatible Operators Uncertainty Relations and Incompatible Operators Simultaneously Measureable Operators Unitary Transformations and Change of Basis Coordinate Displacements and Unitary Transformations Schrodinger and Heisenburg Pictures of Time Evolution Free Gaussian Wave Packet in the Heisenberg Picture Potentials and the Ehrenfest Theorem Problems Three Static Approximation Methods Introduction Time-Independent Perturbation Theory Examples of Time-Independent Perturbation Theory Aspects of Degenerate Perturbation Theory WKB Semiclassical Approximation Use of the WKB Approximation in Barrier Penetration Use of the WKB Approximation in Bound States Variational Methods Problems Generalization to Three Dimensions Cartesian Basis States and Wave Functions in Three Dimensions Position/Momentum Eigenket Generalization Example: Three-Dimensional Infinite Square Well Spherical Basis States Orbital Angular Momentum Operator Effect of Angular Momentum on Basis States Energy Eigenvalue Equation and Angular Momentum Complete Set of Observables for the Radial Schrodinger Equation Specification of Angular Momentum Eigenstates Angular Momentum Eigenvectors and Spherical Harmonics Completeness and Other Properties of Spherical Harmonics Radial Eigenfunctions Problems QUANTUM PARTICLES The Three-Dimensional Radial Equation Recap of the Situation The Free Particle The Infinite Spherical Well Potential The Deuteron The Coulomb Potential: Initial Considerations The Coulomb Potential: 2-D Harmonic Oscillator Comparison The Confined Coulombic Model Problems Addition of Angular Momenta General Angular-Momentum Eigenstate Properties Combining Angular Momenta for Two Systems Explicit Example of Adding Two Spin 1/2 Systems Explicit Example of Adding Orbital Angular Momentum and Spin 1/2 Hydrogen Atom and the Choice of Basis States Hydrogen Atom and Perturbative Energy Shifts Problems Spin and Statistics The Connection between Spin and Statistics Building Wave Functions with Identical Particles Particle Occupation Basis More on Fermi-Dirac Statistics Interaction Operator and Feynman Diagrams Implications of Detailed Balance Cubical Enclosures and Particle States Maxwell-Boltzmann Statistics Bose-Einstein Statistics Fermi-Dirac Statistics The Hartree-Fock Equations Problems Quantum Particle Scattering Introduction The One-Dimensional Integral Schrodinger Equation Reflection and Transmission Amplitudes One-Dimensional Delta-Function Scattering Step-Function Potential Scattering The Born Series The Three-Dimensional Integral Schrodinger Equation The Helmholtz Equation and Plane Waves Cross Sections and the Scattering Amplitude Scattering Phase Shifts Finite-Range Potential Scattering The Three-Dimensional Born Series Identical Particle Scattering Proton-Proton Scattering Problems Connecting to the Standard Model Introduction Discrete Symmetries Parity Time Reversal Charge Conjugation Particle Primer Particle Interactions Quantum Electrodynamics Quantum Chromodynamics Weak Interactions Beyond the Standard Model Supersymmetry Superstrings Postlude Helpful Introductory Books on Particle and String Physics More Advanced Books on Particle and String Physics Problems Appendix: Notation Comments and Comparisons Appendix: Lattice Models Appendix: 2-D Harmonic Oscillator Wave Function Normalization Appendix: Allowed Standard Model Interactions Appendix: Weak Flavor Mixing Appendix: The Ising Model and More Index

•Aug 27, 2019•0 citations
Abstract. The quantum dynamical evolution of atomic and molecular aggregates, from their compact to their fragmented states, is parametrized by a single collective radial parameter. Treating all the remaining particle coordinates in d dimensions democratically, as a set of angles orthogonal to this collective radius or by equivalent variables, by-passes all independent-particle approximations. The invariance of the total kinetic energy under arbitrary d-dimensional transformations which preserve the radial parameter gives rise to novel quantum numbers and ladder operators interconnecting its eigenstates at each value of the radial parameter. We develop the systematics and technology of this approach, introducing the relevant mathematics tutorially, by analogy to the familiar theory of angular momentum in three dimensions. The angular basis functions so obtained are treated in a manifestly coordinate-free manner, thus serving as a flexible generalized basis for carrying out detailed studies of wave function evolution in multi-particle systems.
The quantum dynamical evolution of atomic and molecular aggregates, from their compact to their fragmented states, is parametrized by a single collective radial parameter. Treating all the remaining particle coordinates in d dimensions democratically, as a set of angles orthogonal to this collective radius or by equivalent variables, bypasses all independent-particle approximations. The invariance of the total kinetic energy under arbitrary d -dimensional transformations which preserve the radial parameter gives rise to novel quantum numbers and ladder operators interconnecting its eigenstates at each value of the radial parameter. We develop the systematics and technology of this approach, introducing the relevant mathematics tutorially, by analogy to the familiar theory of angular momentum in three dimensions. The angular basis functions so obtained are treated in a manifestly coordinate-free manner, thus serving as a flexible generalized basis for carrying out detailed studies of wavefunction evolution in multi-particle systems.
Synopsis: Direct product spaces are encountered in the generalization to higher dimensions, and the connection to wave function separability is discussed. The spherical coordinate basis is introduced in preparation for discussing spherically symmetric potentials. Angular momentum operators and properties are examined, and a complete set of compatible observables is determined. The angular momentum eigenvalues and eigenstates are determined using ladder operators, and the connection to spherical harmonics is made. The stage is set for understanding the Schrödinger radial equation.
Synopsis: Direct product spaces are encountered in the generalization to higher dimensions, and the connection to wave function separability is discussed. ƒe spherical coordinate basis is introduced in preparation for discussing spherically symmetric potentials. Angular momentum operators and properties are examined, and a complete set of compatible observables is determined. ƒe angular momentum eigenvalues and eigenstates are determined using ladder operators and the connection to spherical harmonics is made. ƒe stage is set for understanding the Schrödinger radial equation.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.
The most general transformations of coordinates that allow for the exact separation of the kinetic energy operator of a quantum many-body system into total center of mass kinetic energy and internal kinetic energy are found and discussed. It is found (i) that the suitable transformations, depending on the number of particles, have a certain number of free parameters and this allows for the generalization of the Jacobi coordinates to a much larger class of coordinates with the same properties and (ii) that there is a new, uncommon, additive group structure hidden in the transformation matrices that is connected to certain geometric properties of the set of coordinates.
QUANTUM PRINCIPLES Perspective and Principles Prelude to Quantum Mechanics Stern-Gerlach Experiment Idealized Stern-Gerlach Results Classical Model Attempts Wave Functions for Two Physical-Outcome Case Process Diagrams, Operators, and Completeness Further Properties of Operators/Modulation Operator Reformulation Operator Rotation Bra-Ket Notation/Basis States Transition Amplitudes Three-Magnet Setup Example-Coherence Hermitian Conjugation Unitary Operators A Very Special Operator Matrix Representations Matrix Wave Function Recovery Expectation Values Wrap Up Problems Free Particles in One Dimension Photoelectric Effect Compton Effect Uncertainty Relation for Photons Stability of Ground States Bohr Model Fourier Transform and Uncertainty Relations Schrodinger Equation Schrodinger Equation Example Dirac Delta Functions Wave Functions and Probability Probability Current Time Separable Solutions Completeness for Particle States Particle Operator Properties Operator Rules Time Evolution and Expectation Values Wrap-Up Problems Some One-Dimensional Solutions to the Schrodinger Equation Introduction The Infinite Square Well: Differential Solution The Infinite Square Well: Operator Solution The Finite Potential Barrier Step Potential The Harmonic Oscillator The Attractive Kronig-Penny Model Bound State and Scattering Solutions Problems Hilbert Space and Unitary Transformations Introduction and Notation Inner and Outer Operator Products Operator-Matrix Relationship Hermitian Operators and Eigenkets Gram-Schmidt Orthogonalization Process Compatible Operators Uncertainty Relations and Incompatible Operators Simultaneously Measureable Operators Unitary Transformations and Change of Basis Coordinate Displacements and Unitary Transformations Schrodinger and Heisenburg Pictures of Time Evolution Free Gaussian Wave Packet in the Heisenberg Picture Potentials and the Ehrenfest Theorem Problems Three Static Approximation Methods Introduction Time-Independent Perturbation Theory Examples of Time-Independent Perturbation Theory Aspects of Degenerate Perturbation Theory WKB Semiclassical Approximation Use of the WKB Approximation in Barrier Penetration Use of the WKB Approximation in Bound States Variational Methods Problems Generalization to Three Dimensions Cartesian Basis States and Wave Functions in Three Dimensions Position/Momentum Eigenket Generalization Example: Three-Dimensional Infinite Square Well Spherical Basis States Orbital Angular Momentum Operator Effect of Angular Momentum on Basis States Energy Eigenvalue Equation and Angular Momentum Complete Set of Observables for the Radial Schrodinger Equation Specification of Angular Momentum Eigenstates Angular Momentum Eigenvectors and Spherical Harmonics Completeness and Other Properties of Spherical Harmonics Radial Eigenfunctions Problems QUANTUM PARTICLES The Three-Dimensional Radial Equation Recap of the Situation The Free Particle The Infinite Spherical Well Potential The Deuteron The Coulomb Potential: Initial Considerations The Coulomb Potential: 2-D Harmonic Oscillator Comparison The Confined Coulombic Model Problems Addition of Angular Momenta General Angular-Momentum Eigenstate Properties Combining Angular Momenta for Two Systems Explicit Example of Adding Two Spin 1/2 Systems Explicit Example of Adding Orbital Angular Momentum and Spin 1/2 Hydrogen Atom and the Choice of Basis States Hydrogen Atom and Perturbative Energy Shifts Problems Spin and Statistics The Connection between Spin and Statistics Building Wave Functions with Identical Particles Particle Occupation Basis More on Fermi-Dirac Statistics Interaction Operator and Feynman Diagrams Implications of Detailed Balance Cubical Enclosures and Particle States Maxwell-Boltzmann Statistics Bose-Einstein Statistics Fermi-Dirac Statistics The Hartree-Fock Equations Problems Quantum Particle Scattering Introduction The One-Dimensional Integral Schrodinger Equation Reflection and Transmission Amplitudes One-Dimensional Delta-Function Scattering Step-Function Potential Scattering The Born Series The Three-Dimensional Integral Schrodinger Equation The Helmholtz Equation and Plane Waves Cross Sections and the Scattering Amplitude Scattering Phase Shifts Finite-Range Potential Scattering The Three-Dimensional Born Series Identical Particle Scattering Proton-Proton Scattering Problems Connecting to the Standard Model Introduction Discrete Symmetries Parity Time Reversal Charge Conjugation Particle Primer Particle Interactions Quantum Electrodynamics Quantum Chromodynamics Weak Interactions Beyond the Standard Model Supersymmetry Superstrings Postlude Helpful Introductory Books on Particle and String Physics More Advanced Books on Particle and String Physics Problems Appendix: Notation Comments and Comparisons Appendix: Lattice Models Appendix: 2-D Harmonic Oscillator Wave Function Normalization Appendix: Allowed Standard Model Interactions Appendix: Weak Flavor Mixing Appendix: The Ising Model and More Index