Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

European Journal of Physics

Semi-classical methods, angular momentum, and non-analytic problems

Nelia Mann, Jessica Matli, T. M. Pham

Published Jan 14, 2021• 3 citations
Publisher

Abstract

Abstract We explore the semi-classical Sommerfeld method of quantization as applied to states with nonzero angular momentum, and show that it leads to qualitatively and quantitatively useful information about systems with spherically symmetric potentials. We begin by reviewing the traditional application of this model to hydrogen, and discuss the way Einstein–Brillouin–Keller (EBK) quantization resolves a mismatch between Sommerfeld states and true quantum mechanical states. We then analyze systems with logarithmic and Yukawa potentials, and compare the results of Sommerfeld and EBK quantization to those from solving Schrödinger’s equation. We show that the semi-classical quantization techniques provide insight into the spread of energy levels associated with a given principle quantum number, as well as giving quantitatively accurate approximations for the energies. We also argue that analyzing systems in this manner involves an interesting application of numerical methods, as well as providing insight into the connections between classical and quantum mechanical physics.

DOI
10.1088/1361-6404/abdb9c

Related papers

Old Quantization, Angular Momentum, and Nonanalytic Problems

Nelia Mann, Jessica Matli, Tuan Minh Pham

We explore the method of old quantization as applied to states with nonzero angular momentum, and show that it leads to qualitatively and quantitatively useful information about systems with spherically symmetric potentials. We begin by reviewing the traditional application of this model to hydrogen, and discuss the way Einstein-Brillouin-Keller quantization resolves a mismatch between old quantization states and true quantum mechanical states. We then analyze systems with logarithmic and Yukawa potentials, and compare the results of old quantization to those from solving Schrodinger's equation. We show that the old quantization techniques provide insight into the spread of energy levels associated with a given principal quantum number, as well as giving quantitatively accurate approximations for the energies. Analyzing systems in this manner involves an educationally valuable synthesis of multiple numerical methods, as well as providing deeper insight into the connections between classical and quantum mechanical physics.

arXiv:2009.01014•Aug 31, 2020•0 citations

Re-examining the value of old quantization and the Bohr atom approach

Todd S. Garon, Nelia Mann, Ellen M. McManis

We use old quantization to predict features of the energy spectrum for bound states in spherically symmetric potentials. We review the application of this method to simple quantum mechanical systems with known analytic results and show that old quantization, while not generally capable of predicting the exact quantum-mechanical spectrum, does consistently give useful information. We then apply the method to a logarithmic potential and compare the results with a numerically calculated spectrum. Finally, we use these techniques to predict the number of bound states in the Yukawa potential and again compare the results with those obtained numerically. In all cases old quantization provides good predictive power for the main features of the true quantum-mechanical problem, and thus can serve as a “back-of-the-envelope” technique for providing rough, qualitative information about the system.

American Journal of Physics•Jan 22, 2013•7 citations

Numerical implementation of Einstein-Brillouin-Keller quantization for arbitrary potentials

Andrew J. Larkoski, David G. Ellis, Lorenzo J. Curtis

The Einstein-Brillouin-Keller (EBK) quantization equation is used to determine the energy levels of a two-body system with an arbitrary central potential that allows for bound states. The treatment is based on the conservation laws and avoids both the Newtonian and Schrödinger differential equations. Because analytic solutions for the energy levels do not exist in general, the EBK condition is applied using the Newton-Raphson method and the radial probability density is computed. Potentials appropriate for a diatomic molecule are considered and the effect of the angular momentum on the radial distribution, the nature of the classical orbits, and the possibility of closed orbits is studied.

American Journal of Physics•Jul 1, 2006•18 citations

Semiclassical Quantization in Many Dimensions

Roy D. Williams

We examine the semiclassical limit of the quantum energy spectrum in many dimensions: by means of a WKB-like ansatz leading to Einstein-Brillouin-Keller (EBK) quantization, by means of a path integral, hence associating a bound state with a particular classical periodic trajectory, and by the Birkhoff-Gustavson (BG) transformation to action-angle variables. We extend the EBK method to many-fermion systems using coherent states; and apply both EBK using surfaces of section, and the BG transformation to an SU(3) schematic nuclear shell model. We describe a new algorithm for finding periodic trajectories of a Lagrangian system with polynomial potential. It is applied to the Henon-Heiles system with good results, and these trajectories are used to quantize the system. The EBK and BG methods have some success, while periodic trajectory quantization fails. We discuss possible reasons for this failure and future approaches to these problems.

•Oct 31, 2019•0 citations

Semiclassical theory of spin-orbit coupling

Robert G. Littlejohn, William G. Flynn

Newly developed methods for finding the semiclassical or WKB eigenvalues and eigenfunctions for vector wave fields are applied to spinning particles moving in central potentials subject to spin-orbit forces. The new methods are like the familiar Bohr-Sommerfeld or Einstein-Brillouin-Keller quantization methods for scalar wave fields, but involve additional issues relating to Berry's phase, gauge structures, and monopolelike singularities. All these extra issues occur in the asymptotics of spin-orbit coupling. The role of angular momentum and conservation laws is particularly interesting, due to the role played by gauge fields in the classical-quantum correspondence. The work presented is a contribution to ongoing semiclassical studies of shell structure in nuclei and other fermion systems such as metal clusters, as well as an example of the general methods of semiclassical vector wave quantization.

Physical Review A•Jun 1, 1992•49 citations

Quantizing Angular Momentum via the Simple Harmonic Oscillator

Charles P. Friedman, Edwin F. Taylor

The quantization of orbital angular momentum can be introduced simply through the model of the two- and three-dimensional simple harmonic oscillator. Most of the analysis is carried out in the familiar Cartesian coordinate system in which the simple harmonic oscillator Schrödinger equation is separable. Angular momentum eigenfunctions are constructed by superposition, and the resulting functions easily transformed into spherical coordinates. The angle-dependent parts of the solutions are the spherical harmonics, which are the orbital angular momentum eigenfunctions for all central potentials including the Coulomb potential of the hydrogen atom. The method also introduces the separation of variables technique and provides practice in applying the concepts of completeness, orthogonality, superposition of states, and alternative representations.

American Journal of Physics•Sep 1, 1971•3 citations
Abstract We explore the semi-classical Sommerfeld method of quantization as applied to states with nonzero angular momentum, and show that it leads to qualitatively and quantitatively useful information about systems with spherically symmetric potentials. We begin by reviewing the traditional application of this model to hydrogen, and discuss the way Einstein–Brillouin–Keller (EBK) quantization resolves a mismatch between Sommerfeld states and true quantum mechanical states. We then analyze systems with logarithmic and Yukawa potentials, and compare the results of Sommerfeld and EBK quantization to those from solving Schrödinger’s equation. We show that the semi-classical quantization techniques provide insight into the spread of energy levels associated with a given principle quantum number, as well as giving quantitatively accurate approximations for the energies. We also argue that analyzing systems in this manner involves an interesting application of numerical methods, as well as providing insight into the connections between classical and quantum mechanical physics.
We explore the method of old quantization as applied to states with nonzero angular momentum, and show that it leads to qualitatively and quantitatively useful information about systems with spherically symmetric potentials. We begin by reviewing the traditional application of this model to hydrogen, and discuss the way Einstein-Brillouin-Keller quantization resolves a mismatch between old quantization states and true quantum mechanical states. We then analyze systems with logarithmic and Yukawa potentials, and compare the results of old quantization to those from solving Schrodinger's equation. We show that the old quantization techniques provide insight into the spread of energy levels associated with a given principal quantum number, as well as giving quantitatively accurate approximations for the energies. Analyzing systems in this manner involves an educationally valuable synthesis of multiple numerical methods, as well as providing deeper insight into the connections between classical and quantum mechanical physics.
We use old quantization to predict features of the energy spectrum for bound states in spherically symmetric potentials. We review the application of this method to simple quantum mechanical systems with known analytic results and show that old quantization, while not generally capable of predicting the exact quantum-mechanical spectrum, does consistently give useful information. We then apply the method to a logarithmic potential and compare the results with a numerically calculated spectrum. Finally, we use these techniques to predict the number of bound states in the Yukawa potential and again compare the results with those obtained numerically. In all cases old quantization provides good predictive power for the main features of the true quantum-mechanical problem, and thus can serve as a “back-of-the-envelope” technique for providing rough, qualitative information about the system.
The Einstein-Brillouin-Keller (EBK) quantization equation is used to determine the energy levels of a two-body system with an arbitrary central potential that allows for bound states. The treatment is based on the conservation laws and avoids both the Newtonian and Schrödinger differential equations. Because analytic solutions for the energy levels do not exist in general, the EBK condition is applied using the Newton-Raphson method and the radial probability density is computed. Potentials appropriate for a diatomic molecule are considered and the effect of the angular momentum on the radial distribution, the nature of the classical orbits, and the possibility of closed orbits is studied.
We examine the semiclassical limit of the quantum energy spectrum in many dimensions: by means of a WKB-like ansatz leading to Einstein-Brillouin-Keller (EBK) quantization, by means of a path integral, hence associating a bound state with a particular classical periodic trajectory, and by the Birkhoff-Gustavson (BG) transformation to action-angle variables. We extend the EBK method to many-fermion systems using coherent states; and apply both EBK using surfaces of section, and the BG transformation to an SU(3) schematic nuclear shell model. We describe a new algorithm for finding periodic trajectories of a Lagrangian system with polynomial potential. It is applied to the Henon-Heiles system with good results, and these trajectories are used to quantize the system. The EBK and BG methods have some success, while periodic trajectory quantization fails. We discuss possible reasons for this failure and future approaches to these problems.
Newly developed methods for finding the semiclassical or WKB eigenvalues and eigenfunctions for vector wave fields are applied to spinning particles moving in central potentials subject to spin-orbit forces. The new methods are like the familiar Bohr-Sommerfeld or Einstein-Brillouin-Keller quantization methods for scalar wave fields, but involve additional issues relating to Berry's phase, gauge structures, and monopolelike singularities. All these extra issues occur in the asymptotics of spin-orbit coupling. The role of angular momentum and conservation laws is particularly interesting, due to the role played by gauge fields in the classical-quantum correspondence. The work presented is a contribution to ongoing semiclassical studies of shell structure in nuclei and other fermion systems such as metal clusters, as well as an example of the general methods of semiclassical vector wave quantization.
The quantization of orbital angular momentum can be introduced simply through the model of the two- and three-dimensional simple harmonic oscillator. Most of the analysis is carried out in the familiar Cartesian coordinate system in which the simple harmonic oscillator Schrödinger equation is separable. Angular momentum eigenfunctions are constructed by superposition, and the resulting functions easily transformed into spherical coordinates. The angle-dependent parts of the solutions are the spherical harmonics, which are the orbital angular momentum eigenfunctions for all central potentials including the Coulomb potential of the hydrogen atom. The method also introduces the separation of variables technique and provides practice in applying the concepts of completeness, orthogonality, superposition of states, and alternative representations.