Hybrid quantum systems, which combines the advantages of different quantum systems, play an essential role in the realisation of quantum computation, especially as quantum memory. This thesis discusses the very promising hybrid quantum system based on the ensemble of negatively charged nitrogen-vacancy centers (NV-centers) in diamond and superconducting microwave cavities. The decoherence of this system, due to the inhomogeneous spin broadening, seems to be the major obstacle of utilising the NV-centers as a quantum information storage. This works focuses on the study of the dynamics of our NV-center spin ensemble strongly coupled to a superconducting resonator driven by pulse sequences with a carrier frequency equaling the cavity frequency. A precise knowledge of the spin broadening, which has a non-Lorentzian distribution, led to the observation of the so called 'cavity protection effect'. Furthermore this work demonstrates the enhancement of the damped Rabi oscillations between the spin ensemble and the cavity mode through appropriate chosing of the microwave pulses, which could change in the order of two magnitudes. Last we also confirmed the theoretical analysis of the crossover from markovian to non-markovian dynamics for our system, which is achieved for increasing coupling strength.
Hybrid quantum systems, which combines the advantages of different quantum systems, play an essential role in the realisation of quantum computation, especially as quantum memory. This thesis discusses the very promising hybrid quantum system based on the ensemble of negatively charged nitrogen-vacancy centers (NV-centers) in diamond and superconducting microwave cavities. The decoherence of this system, due to the inhomogeneous spin broadening, seems to be the major obstacle of utilising the NV-centers as a quantum information storage. This works focuses on the study of the dynamics of our NV-center spin ensemble strongly coupled to a superconducting resonator driven by pulse sequences with a carrier frequency equaling the cavity frequency. A precise knowledge of the spin broadening, which has a non-Lorentzian distribution, led to the observation of the so called 'cavity protection effect'. Furthermore this work demonstrates the enhancement of the damped Rabi oscillations between the spin ensemble and the cavity mode through appropriate chosing of the microwave pulses, which could change in the order of two magnitudes. Last we also confirmed the theoretical analysis of the crossover from markovian to non-markovian dynamics for our system, which is achieved for increasing coupling strength.
We study the dynamics of a spin ensemble strongly coupled to a single-mode resonator driven by external pulses. When the mean frequency of the spin ensemble is in resonance with the cavity mode, damped Rabi oscillations are found between the spin ensemble and the cavity mode which we describe very accurately, including the dephasing effect of the inhomogeneous spin broadening. We demonstrate that a precise knowledge of this broadening is crucial both for a qualitative and a quantitative understanding of the temporal spin-cavity dynamics. On this basis we show that coherent oscillations between the spin ensemble and the cavity can be enhanced by a few orders of magnitude, when driving the system with pulses that match special resonance conditions. Our theoretical approach is tested successfully with an experiment based on an ensemble of negatively charged nitrogen-vacancy centers in diamond strongly coupled to a superconducting coplanar single-mode waveguide resonator.
Based on the experiments [S. Putz et al., Nat. Phys. 10, 720 (2014); Nat. Photonics 11, 36 (2017)] on the hybrid quantum system of a superconducting microwave cavity coupled strongly to an inhomogeneous broadening spin ensemble, we use the exact master equation theory to investigate its non-Markovian decoherence dynamics under external driving fields. In the experiments, the spin ensemble is made of negatively charged nitrogen-vacancy defects in diamond. The exact master equation theory generalizes the fluctuation-dissipation relation and depicts in details the transient non-Markovian decoherence, in which the dissipation (relaxation) and fluctuations (noise or dephasing) dynamics is well described and the non-Markovian memory effect can be well characterized. We study the physical picture of the transient non-Markovian decoherence dynamics and explore how the non-Markovian decoherence induced by the inhomogeneous broadening of the spin ensemble is suppressed in the strong-coupling regime. We also show how the spectral hole burning generates localized bound states for the further decoherence suppression. Furthermore, we investigate the two-time correlations to show the relationships between quantum fluctuations and quantum memory.
Spin ensembles inside a cavity act as light-matter interfaces that play an eminentrole in the development of future quantum devices. An apparent asset of ensemble-based systems is the collective enhancement of the coupling strength, facilitating astrong interaction between the light and matter components. Particularly promisingin this regard, due to their convenient handling and integrability, are solid statespin ensembles such as nitrogen-vacancy centers in diamond, phosphorous donors in silicon, or rare earth doped crystals. Such ensemble-based setups, however, are almost inevitably inhomogeneously broadened as the different spins of the ensemble typically have different local environments leading to a spectral distribution in their transition frequencies. This so-called inhomogeneous broadening is a major source for decoherence in solid state systems and a major challenge to be addressed for future technical applications.In this thesis, we aim to provide the theoretical framework necessary to describeand understand various effects of inhomogeneously broadened spin ensembles coupled to a single-mode cavity—a system that has been realized in numerous different quantum optical setups and in very different parameter regimes.For macroscopic spin ensembles, i.e., ensembles consisting of a vast number ofspins, quantum fluctuations of the individual spins can typically be neglected, allowing a semiclassical description based on Maxwell-Bloch equations. Here, we study two prominent effects in the strongly nonlinear regime namely optical bistability, resembling a first-order phase transition, and critical slowing down. In particular, we show that the onset of bistability not only depends on the width of the spectral spin distribution but also strongly depends on its exact shape. Furthermore, we analyze the transient times of the cavity amplitude which show a power-law divergence when an external parameter is changed in the vicinity of the phase transition.This critical slowdown is demonstrated in collaboration with the group ofJörg Schmiedmayer at the Atominstitut of TU Wien. In the experiment, negativelycharged nitrogen vacancy centers in diamond are strongly coupled to a superconducting microwave resonator showing transient times of up to 11 hours.In mesoscopic spin ensembles with moderate numbers of constituents, quantumfluctuations gain importance, and semiclassical methods fail. We study thiscrossover between the semiclassical and the quantum regime using a cumulant expansion approach to study the semiclassical-to-quantum boundary for inhomogeneously broadened spin ensembles inside a cavity. In addition, we develop a time-adaptivevariational renormalization group method to calculate the full quantumdynamics of spin ensembles containing up to one hundred spins. With the aid ofthis method, we examine mesoscopic spin ensembles whose spin distributions form a comb-shaped structure. These so-called atomic frequency combs have promising properties for the storage of quantum information. On the one hand, we show that arbitrary multi-photon states are absorbed by the comb-shaped spin ensembleand re-emitted into the cavity at periodic time intervals. On the other hand, wedemonstrate that by means of such a spin ensemble a coherent input pulse can beconverted into periodic pulses of non-classical light.Finally, we address spin echoes, which are a fundamental part in nuclear magneticresonance as well as in electron spin resonance. Specifically, we transfer the Hahnecho to the strong coupling regime, where we find a new dynamical phenomenonfeaturing a periodic sequence of self-sustained echoes after a conventional Hahn echo pulse. In collaboration with the group of Hans Hübl at the Technical UniversityMunich, a first demonstration of this intriguing multiecho signature is presented inan electron spin resonance experiment with phosphorus donors in silicon.
In the last couple of years much effort has been dedicated to the development and the investigation of hybrid quantum devices, which combine the advantages of very dissimilar quantum systems for the realization of efficient quantum computation and communication technologies. Particularly interesting in this regard are solid-state quantum memories based on ensembles of spins (e.g. nitrogen vacancy defects in diamond or rare-earth doped crystals) coupled to superconducting microwave cavities. Here the spin-ensemble acts as a robust memory where the collective coupling to the cavity mode allows for the coherent transfer of quantum information. The major downside of ensembles inside solid-state systems is their natural tendency to exhibit inhomogeneous broadening of the transition frequencies, which makes experiments as well as their theoretical description very challenging. On the theoretical side it is primarily the computational complexity due to the exponential growth of the associated Hilbert space with the system size that inevitably calls for approximation schemes. To date, the theoretical description of large spin-cavity systems is mainly limited to weak driving fields, where the number of spin-excitations in the ensemble is negligible, corresponding to a Holstein-Primakoff approximation, or to mean-field approaches, where correlations within the system are neglected. In this thesis we aim to develop a model that accurately accounts for the dynamics of large inhomogeneously broadened spin ensembles, coupled to a single cavity mode, even in the case of strong driving fields. In particular we employ the generalized cumulant expansion method to account for correlations within the system, which allows us to go beyond the Holstein-Primakoff and mean-field approximations. As a first step, we demonstrate the applicability of the cumulant expansion technique to the well-studied Jaynes-Cummings model and investigate its main limitations. We then move on to the Tavis-Cummings model with multiple spins inside the cavity and generalize our approach to ensembles containing a very large number of spins (ca. 10 12). Our model aims not only to provide a proper description of ensemble-based quantum memories, but also to serve as a novel tool for the investigation of interesting new physics arising from cooperative effects in inhomogeneous ensembles.
In this paper, we investigate the strong-coupling quantum thermodynamics of a hybrid quantum system far from equilibrium, based on the renormalization theory of quantum thermodynamics we developed recently [Phys. Rev. Research 4, 023141 (2022)]. The strong-coupling hybrid system consists of a superconducting microwave cavity and a spin ensemble of the NV centers in diamond under external driving. The non-Markovian dynamics of this strong-coupling hybrid system has been experimentally explored and theoretically investigated. We apply the renormalization theory of quantum thermodynamics to study the transient quantum heat and work in this strong-coupling hybrid system. We find that the dissipation and fluctuation dynamics of the system induce the transient quantum heat current which shows significant non-Markovian effects. On the other hand, the energy and driving field renormalization produces quantum work power. In particular, the driving-induced work power can be largely enhanced by non-Markovian dynamics through the cavity coupling strongly with the spin ensemble at the resonance. Our results show that non-Markovian dynamics makes faster energy conversion of the heat and work.
Quantum entanglement is a kernel of quantum computation and quantum communication. We introduce a theoretical scheme to achieve the entanglement between two separated quantum nodes in a hybrid system. The proposed hybrid system based on diamond nitrogen-vacancy (NV) center spin ensemble is coherently coupled to a superconducting quantum circuit consisting of two quantum nodes and a quantum channel. Each node in our setup is composed of an NV center spin ensemble magnetically coupled to a superconducting coplanar resonator. The NV center spin ensemble composed of N identical and non-interacting NV spins, is placed in the magnetic field antinode of the superconducting coplanar resonator where the coupling is maximized. An array of superconducting quantum interference devices (SQUIDs) is inserted in the central conductor of resonator to make its frequency tunable with the magnetic flux threading through the SQUID loops. This flux is generated by passing current through an on-chip wire, so that the resonator can be brought in resonance with the NV center spins without changing their Zeeman splitting. Quantum qubits encoded into two separate nodes are connected by a vacuum superconducting coplanar resonator that is used as a quantum channel. This setup can potentially take the best elements of each individual system:NV center spin ensemble with longer coherence time capable of preparing, storing and releasing photonic quantum information, and the superconducting quantum circuits are easy to manipulate externally and can perform quantum logic gates to control quantum information rapidly. In order to realize the entanglement between two separated quantum nodes, firstly, we make a canonical transformation and obtain the Hamiltonian of the system that is reduced to two NV center spin ensembles resonantly coupled to a single mode of the superconducting coplanar resonator. Then we put forward the hybrid NV center spin-photon qubit encoding. In this hybrid encoding, the NV center spin and photon degrees of freedom enter on an equal footing into the definition of the qubit, in which case, quantum channel will switch on when three superconducting coplanar resonators are in resonance with each other, and all the manipulations can perform simply by tuning the frequencies of the superconducting coplanar resonators. Under the precise control of the evolution time, high fidelity entanglement between two separated quantum nodes is achieved. We show that this proposal can provide high fidelity quantum entanglement under realistic conditions, both in the resonant and the dispersive interaction cases. This hybrid quantum system will exhibit long coherence time and possess features like easy fabrication, integratability, and potential scalability. Furthermore, the quantum node composed of an NV center spin ensemble magnetically coupled to a superconducting coplanar resonator can be respectively integrated, which has practical applications in the realization of quantum information transmission and quantum entanglement among multiple quantum nodes.