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Koninklijke Nederlandse Akademie van Wetenschappen Proceedings Series B Physical Sciences

Observations concerning anomalous disperision of light in gases

W. H. Julius, H. B. van der Plaats

Published Jan 1, 1910• 0 citations
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We report anomalous light-induced drift of potassium vapor in mixtures of Ne with another rare gas. The drift velocity versus laser frequency curve shows a strong deviation from the dispersion curve predicted by the standard theory of light-induced drift based on velocity-independent collision rates. The observed drift velocity versus frequency curves have three zero-crossings. For a qualitative explanation of the results, a strong collision model with velocity-dependent collision rates is used. The partial pressures that cancel normal light-induced drift also provide accurate ratios of cross section for potassium collisions with the various buffer gases. The observation of anomalous light-induced drift in a simple atomic system offers the opportunity to relate the results to potential curves. \textcopyright{} 1996 The American Physical Society.

Physical Review A•Jun 1, 1996•19 citations
This paper is a theoretical study of the spectral features of the velocity of light-induced drift (LID) of lithium atoms ( 7 Li and 6 Li) in a binary mixture of noble gases: Ne + Ar, Ne + Kr, and Ne + Xe. The spectral shape of the LID signal is predicted to depend strongly on the fraction ξ of neon in the buffer mixture in the range ξ≈0.8–0.9 (ξ= N Ne / N b , where N Ne is the neon concentration, and N b is the total concentration of the buffer particles). When the velocity of anomalous LID is treated as a function of the radiation frequency, it is found to have one, three, five, or seven zeros and to differ substantially from the dispersion-curve-like behavior with one zero predicted by the standard LID theory with velocity-independent transport collision rates. The reason for these additional zeros of the drift velocity is the alternating-sign dependence on the lithium-atom velocity of the relative difference of transport rates of collisions between buffer particles and excited and unexcited atoms. What is also established is that the anomalous LID of lithium atoms can be observed at almost all temperatures, depending on the value of ξ. At a fixed temperature, anomalous LID can be observed only in a narrow range of values of the fraction of neon in the buffer mixture, Δξ≈0.02. The results make possible highly precise testing in the LID experiments of the interatomic potentials used in calculations of the velocity spectrum of anomalous LID.
The spectral features of the light-induced drift (LID) velocity of caesium atoms in inert buffer gases are studied theoretically. A strong temperature dependence of the spectral LID line shape of Cs atoms in Ar or Kr atmosphere in the vicinity of T ~ 1000 K is predicted. It is shown that the anomalous LID of Cs atoms in binary buffer mixtures of two different inert gases can be observed at virtually any (including ambient) temperature, depending on the content of the components in these mixtures. The results obtained make it possible to precisely test the interatomic interaction potentials in the experiments on the anomalous LID.
We report anomalous light-induced drift of potassium vapor in mixtures of Ne with another rare gas. The drift velocity versus laser frequency curve shows a strong deviation from the dispersion curve predicted by the standard theory of light-induced drift based on velocity-independent collision rates. The observed drift velocity versus frequency curves have three zero-crossings. For a qualitative explanation of the results, a strong collision model with velocity-dependent collision rates is used. The partial pressures that cancel normal light-induced drift also provide accurate ratios of cross section for potassium collisions with the various buffer gases. The observation of anomalous light-induced drift in a simple atomic system offers the opportunity to relate the results to potential curves. \textcopyright{} 1996 The American Physical Society.