We present a succinct way to quantize Maxwell's equations. We begin by discussing the random nature of quantum observables. Then we present the quantum Maxwell's equations and give their physical meanings. Due to the mathematical homomorphism between the classical and quantum cases [1], the derivation of quantum Maxwell's equations can be simplified. First, one needs only to verify that the classical equations of motion are derivable from a Hamiltonian by energy-conservation arguments. Then the quantum equations of motion follow due to homomorphism, which applies to sum-separable Hamiltonians. Hence, we first show the derivation of classical Maxwell's equations using Hamiltonian theory. Then the derivation of the quantum Maxwell's equations follows in an analogous fashion. Finally, we apply this quantization procedure to the dispersive medium case. (This article is written for the classical electromagnetic community assuming little knowledge of quantum theory, an introduction of which can be found in [2, Lecs. 38 and 39].)
We present a succinct way to quantize Maxwell's equations. We begin by discussing the random nature of quantum observables. Then we present the quantum Maxwell's equations and give their physical meanings. Due to the mathematical homomorphism between the classical and quantum cases [1], the derivation of quantum Maxwell's equations can be simplified. First, one needs only to verify that the classical equations of motion are derivable from a Hamiltonian by energy-conservation arguments. Then the quantum equations of motion follow due to homomorphism, which applies to sum-separable Hamiltonians. Hence, we first show the derivation of classical Maxwell's equations using Hamiltonian theory. Then the derivation of the quantum Maxwell's equations follows in an analogous fashion. Finally, we apply this quantization procedure to the dispersive medium case. (This article is written for the classical electromagnetic community assuming little knowledge of quantum theory, an introduction of which can be found in [2, Lecs. 38 and 39].)
The quantum theory of relativistic particles, based on the first quantization technique similar to that used by Schroedinger and Dirac in formulating quantum mechanics, is reconsidered on the basis of a photon-like dispersion relation corresponding to the energy conservation equation of Einstein's special relativity. First, scalar quantum mechanics of particles operating with their wave functions is discussed. Using the first quantization of the photon-like dispersion relation, very simple new derivation of the Dirac equation is given. Then, vector field quantum mechanics is introduced, which defines vector fields associated with the relativistic particle. Basic equations for the vector-field quantum mechanics, similar to the source-free Maxwell equations, are derived. Following these equations, the particle's de Broglie wave can be considered as the transversal electromagnetic wave. Therefore, the wave-particle duality can be redefined as the electromagnetic wave-particle duality. Relationships between the scalar and vector field quantum mechanics are analyzed.
Quantum theory of photons based on the first quantization technique, similar to that used by Schrödinger in the formulation of quantum mechanics, is considered. First, scalar quantum mechanics of photons operating with the photon wave functions is discussed. Using the first quantization, the wave equation, the Schrödinger-like equations, and the Dirac equation for photons are derived. Then, vector quantum mechanics of photons is introduced, which defines the electromagnetic vector fields. Using the first quantization, the Maxwell equations for photons in a magneto-dielectric medium are obtained. Because the photon’s electric and magnetic fields satisfy the Maxwell equations, all that is known about the classical optical fields can be directly transferred to photons demonstrating their quantum diversity. Relationships between the scalar and vector quantum mechanics of photons and between the Dirac and Maxwell equations are analyzed. To describe the propagation of photons in dispersive media, modified Maxwell equations are introduced.
The notion that the electromagnetic field is quantized is usually inferred from observations such as the photoelectric effect and the black-body spectrum. However accounts of the quantization of this field are usually mathematically motivated and begin by introducing a vector potential, followed by the imposition of a gauge that allows the manipulation of the solutions of Maxwell's equations into a form that is amenable for the machinery of canonical quantization. By contrast, here we quantize the electromagnetic field in a less mathematically and more physically motivated way. Starting from a direct description of what one sees in experiments, we show that the usual expressions of the electric and magnetic field observables follow from Heisenberg's equation of motion. In our treatment, there is no need to invoke the vector potential in a specific gauge and we avoid the commonly used notion of a fictitious cavity that applies boundary conditions to the field.
Quantization of the electromagnetic field (called quantum electromagnetics here) has been a fascinating and important subject since its introduction by Dirac in 1927. However, this knowledge is often inaccessible to technologists such as engineers. This subject will be discussed in its simplest terms so that it can be easily understood by a larger community of researchers. To this end, a new way of motivating Hamiltonian mechanics is presented. Furthermore, a novel way of deriving the quantum equations of motion for electromagnetics and Maxwell's equations is presented.
: Our goal is to quantize Maxwell's equations, leading to a natural interpretation of light as being composed of photons. The key is that the quantization of harmonic oscillators (or, more prosaically, the mathematics of springs) is critical to understanding light. In particular, we show that the possible energies of light form a discrete set, linked to the classical frequency, giving us an interpretation for the photoelectric effect. Our Approach From Einstein's explanation of the photoelectric effect, light seems to be made up of photons, which in turn are somewhat particle-like. Can we start with the classical description of light as an electromagnetic wave solution to Maxwell's equations when there are no charges or currents, quantize, and then get something that can be identified with photons? That is the goal of this chapter. (As in the previous chapter, while all of this is standard, we will be following the outline given in chapter 2 of [41].) Maxwell's equations are linear. We will concentrate on the ‘monochromatic’ solutions, those with fixed frequency and direction. We will see that the Hamiltonians of these monochromatic solutions will have the same mathematical structure as a Hamiltonian for a harmonic oscillator. We know from the last chapter how to quantize the harmonic oscillator. More importantly, we saw that there are discrete eigenvalues and eigenvectors for the corresponding Hamiltonian operator. When we quantize the Hamiltonians for the monochromatic waves in an analogous fashion, we will again have discrete eigenvalues and eigenvectors. It is these eigenvectors that we can interpret as photons.
At the conceptual level, the quantization procedure replaces the pure particle description of classical mechanics by a particle-wave treatment satisfying the requirements of the fundamental wave–particle dualism. Technically, one can always start from a generalized wave equation and use it as a basis to discuss wave-front propagation in the form of rays following classical particle trajectories, see Sections 2.2.1 and 3.1. Consequently, any wave theory inherently contains that aspect of the wave–particle dualism. Especially, Maxwell's equations of electrodynamic theory include both wave and particle aspects of electromagnetic fields. Hence, it could be that there are no additional “quantum,” i.e., wave–particle dualistic aspects. However, as we discuss in this chapter, Maxwell's equations can be expressed in the framework of Hamilton's formulation of particle mechanics. This then suggests that in addition to the approximate ray-like behavior, electromagnetic fields do have a supplementary level of particle-like properties. Due to the fundamental axiom of wave–particle dualism, the additional particle-like aspects of electromagnetic fields must then also have a wave counterpart that can be axiomatically introduced via the canonical quantization scheme described in Section 3.2.3. Since the spatial dependency in Maxwell's equation contains wave–particle dualism already at the classical level, it is clear that the new level of quantization cannot be a simple real-space feature but has to involve some other space describing the structure of the electromagnetic fields. In fact, this quantization yields several very concrete implications such as quantization of the light energy, elementary fluctuations in the light-field amplitude and intensity, and more.