Abstract Quantum entanglement is a basic ingredient in the formalism of quantum mechanics and was held by Heisenberg as its most emblematic feature. But although all its consequences could be foreseen from the start, it took half a century before experiments were carried out to test its more intriguing predictions. One reason was that sufficiently sensitive tools, like lasers, were not yet available, but there was also a lack of interest and imagination among theoreticians, who did not realize its full potential. When experiments were finally realized and opened a ‘weird and ghostlike quantum world’, they were first met with surprise and doubt. In the first experiments on entanglement it was purposely created (using chain-decays or down-conversion), but entanglement is actually a ubiquitous phenomenon appearing in most physical processes, although surviving over so short time-scales that it is usually not observed. The present work deals with ‘measurement-induced entanglement’ in scattering, and starts with a process where its effects can actually be studied in the sub-femtosecond range in a time-resolved manner, the Compton scattering of neutrons. Based on results from this method, the conditions for observing similar effects in other scattering processes are discussed. First, the mechanisms for entanglement creation by a scattering particle are mentioned, then the conditions for observing measurable consequences of it on scattering cross-sections: a very limited number of scattering centers, large zero-point motions of the scatterers and no strong interaction with environment which leads to decoherence.
Abstract Quantum entanglement is a basic ingredient in the formalism of quantum mechanics and was held by Heisenberg as its most emblematic feature. But although all its consequences could be foreseen from the start, it took half a century before experiments were carried out to test its more intriguing predictions. One reason was that sufficiently sensitive tools, like lasers, were not yet available, but there was also a lack of interest and imagination among theoreticians, who did not realize its full potential. When experiments were finally realized and opened a ‘weird and ghostlike quantum world’, they were first met with surprise and doubt. In the first experiments on entanglement it was purposely created (using chain-decays or down-conversion), but entanglement is actually a ubiquitous phenomenon appearing in most physical processes, although surviving over so short time-scales that it is usually not observed. The present work deals with ‘measurement-induced entanglement’ in scattering, and starts with a process where its effects can actually be studied in the sub-femtosecond range in a time-resolved manner, the Compton scattering of neutrons. Based on results from this method, the conditions for observing similar effects in other scattering processes are discussed. First, the mechanisms for entanglement creation by a scattering particle are mentioned, then the conditions for observing measurable consequences of it on scattering cross-sections: a very limited number of scattering centers, large zero-point motions of the scatterers and no strong interaction with environment which leads to decoherence.
In general, nuclei and electrons in condensed matter and/or molecules are entangled, due to the prevailing (electromagnetic) interactions. As a matter of fact, the "environment" interacting with a microscopic system of interest (e.g. a proton) causes the destruction of the entanglement. This process, called decoherence, has until now prevented experimenters from directly accessing atomic and/or nuclear entanglement effects in real experiments. However, our neutron and electron Compton scattering experiments from protons (H-atoms) in several condensed systems and molecules at ambient conditions demonstrated a new striking effect, i.e. an "anomalous" decrease of scattering intensity from protons, which seem to become partially "invisible" to the neutrons. This effect, which has no interpretation within conventional neutron scattering theory, is proposed to be caused by the non-unitary time evolution (due to decoherence) during the ultrashort, but finite, time-window of the neutron-proton scattering process. Due to the large energy (several eV) and momentum (20-200 Å −1 ) transfers of these experiments the collisional time between the probe particle and a struck proton is 100–1000 attoseconds long. It is shown that, due to this short timescale, the scattering process must be theoretically treated within quantum dynamics of open quantum systems. New experimental neutron Compton scattering results from a single crystal KHCO 3 are presented. They provide the first direct evidence for a connection between the momentum distribution and the "anomalous" scattering intensity of H. Additionally, recent experiments with electron-atom Compton scattering at momentum transfers are mentioned, which reveal the presence of this effect even in scattering from single H 2 molecules in the gas phase. Theoretical discussions "from first principles" are presented, also in relation to the quantum Zeno effect, which underline the crucial role of decoherence in the considered experiments. The experimental results and their qualitative interpretation show that epithermal neutrons being available at spallation sources (e.g. ISIS/UK, SNS/USA or ESS/Sweden), and electron spectrometers with large scattering angles, provide tools for investigating new physical and chemical phenomena in the sub-femtosecond timescale.
Nuclei and electrons in condensed matter and/or molecules are usually entangled, due to the prevailing electromagnetic interactions. Usually, the “environment” of a microscopic scattering system (e.g., a proton) causes an ultrafast decoherence, thus making atomic and/or nuclear entanglement effects not directly accessible to experiments. However, neutron Compton scattering (NCS) and electron Compton scattering represent ultrafast techniques operating in the sub-femtosecond timescale, thus opening a way for investigation of such dehoherence and short-lived entanglement phenomena of atoms in molecules and condensed matter. The experimental context of NCS and a new striking scattering effect from protons (H-atoms) in several condensed systems and molecules are described. In short, one observes an “anomalous” decrease of scattering intensity from protons, which seem to become partially “invisible” to the neutrons. The experiments apply large energy (several electronvolts) and momentum (10–200 Å −1 transfers, and the collisional (or scattering) time between the neutron and a struck proton is only 100–1000 attoseconds long. Similar results are also obtained with electron-atom Compton scattering at large momentum transfers. As an example, we present new NCS experimental results from a single crystal, which also provide new physical insights into the attosecond quantum dynamics of protons in molecules and condensed matter. Theoretical discussions and models are presented which show that the effect under consideration is caused by the non-unitary time evolution (due to decoherence) of open quantum systems during the ultrashort, but finite, time-window of the neutron-proton scattering process. The conceptual connection with the well known Quantum Zeno Effect is pointed out. The experimental results, together with their qualitative interpretation “from first principles,” show that epithermal neutrons being available at spallation sources, and electron spectrometers providing large momentum transfers, may represent novel tools for investigation of thus far unknown physical and chemical attosecond phenomena.
Abstract Quantum entanglement in scattering processes has most often been treated in general terms only. A few examples of detailed calculations exist for atomic systems but for nuclear processes it is an almost unexplored area, although it may be important for interpretation of some measured quantities. The present treatment is a study of the time-development of the deuteron-like compound state created in the n – p scattering process. The increase and decay of neutron–proton entanglement in this state is calculated for low transferred momenta over the atto-second range. It is well known that the very high value for the bound proton cross sections ( σ = 81.9 barns) is caused by a specific feature in the deuteron, a virtual 0+ state close to its binding level. In scattering this state causes a negative phase shift δ s in the outgoing neutron wave function, increasing linearly with the transferred momentum. This phase shift is produced during a short-lived virtual energy transfer Δ E in exciting the 0+ state and Δ E is estimated here from the ratio of the phase shift δ observed and the time Δ t it takes to create the entanglement. It is further argued that the nuclear excitation decreases after the n – p encounter in proportion to the degree of n – p entanglement calculated, i.e. as long as the scattering state has deuteron characteristics. This phase shift is neglected in low energy neutron scattering text-books (which are based on the Fermi pseudo potential) and may be negligible for thermal neutron scattering, but will be important already at epithermal energies (0.1–1 eV). The phase shift has measurable consequences in interpretation of INS (inelastic neutron scattering) since its associated energy shift increases quadratically with the transferred momentum. It explains quantitatively certain anomalies found in scattering on water, where water vibration modes are excited far below the expected transferred momentum limit. This paper ends with a short discussion about quantum entanglement in scattering processes in general, with the present example as a starting point.
The theory of quantum information constitutes the functional value of the quantum entanglement, i.e., quantum entanglement is essential for high fidelity of quantum protocols, while fundamental physical processes behind the formation of quantum entanglement are less relevant for practical purposes. In the present work, we explore physical mechanisms leading to the emergence of quantum entanglement in the initially disentangled system. In particular, we analyze spin entanglement of outgoing electrons in a nonrelativistic quantum (e,2e) collision on a target with one active electron. Our description exploits the time-dependent scattering formalism for typical conditions of scattering experiments, and contrary to the customary stationary formalism operates with realistic scattering states. We quantify the spin entanglement in the final scattering channel through the pair concurrence and express it in terms of the experimentally measurable spin-resolved (e,2e) triple differential cross sections. Besides, we consider Bell's inequality and inspect the regimes of its violation in the final channel. We address both the pure and the mixed initial spin state cases and uncover kinematical conditions of the maximal entanglement of the outgoing electron pair. The numerical results for the pair concurrence, entanglement of formation, and violation of Bell's inequality obtained for the (e,2e) ionization process of atomic hydrogen show that the entangled electron pairs indeed can be formed in the (e,2e) collisions even with spin-unpolarized projectile and target electrons in the initial channel. The positive entanglement balance---the difference between entanglements of the initial and final electron pairs---can be measured in the experiment.
Several recent experiments on liquid and solid samples containing protons or deuterons show an interesting anomaly, which is a shortfall in the intensity of energetic neutrons scattered by the samples. Previously we demonstrated that quantum correlations in the spatial and spin degrees of freedom of the hydrogen isotopes lead to entanglement in scattering and a reduction in the scattered intensity. The viability of short-lived quantum correlations as the cause of the observed anomalies is further explored and found to be entirely feasible. General features of the basic premiss, that quantum entanglement reduces the scattered signal, are discussed and the interpretation of the neutron scattering experiments is set in context to related work on other systems. For the experiments in question, the duration of a scattering event, τ s , is a fraction of a femtosecond which is extremely short compared to solid-state relaxation times. Increasing τ s , by suitably changing experimental conditions, restores the intensity to the standard value calculated from the single atom cross-section and concentration of particles. Our physical picture of the restoration is evolution with increasing τ s from a pure state of the particles (described by a wavefunction) to a mixed state (described by a density matrix) that is created, through decoherence, by steadily engaging the solid-state environment of the particles.