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CRC Press eBooks

- Theory of Angular Momentum

S. Rajasekar, R. Velusamy

Published Dec 11, 2014• 25 citations
Publisher

Abstract

A particle moving along a straight-line has a linear momentum mv. A revolving particle has angular momentum due to its mass and angular velocity. In classical mechanics, orbital angular momentum is the vector product of position (r) and linear momentum (p): L = r× p . (11.1) Let us imagine the electron as a small ball, revolving about some axis. It possesses angular momentum. Precisely, the angular momentum vector is a vector pointing along the axis of rotation with magnitude proportional to the speed of rotation. A vector which changes sign under space inversion (parity operation) is called a polar vector . r and p are polar vectors as they change sign. Since L = (−r)× (−p), L does not change sign under parity operation. Such vectors which do not change sign under parity operation are called axial vectors or psuedo-vectors. Classically, the angular momentum of the electron could have any magnitude. In quantum mechanics the orbital angular momentum operator is obtained by replacing p by −i~∇. The angular position of a particle is the angle at which it is located in two-dimensional polar coordinates.

DOI
10.1201/b17899-15

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A particle moving along a straight-line has a linear momentum mv. A revolving particle has angular momentum due to its mass and angular velocity. In classical mechanics, orbital angular momentum is the vector product of position (r) and linear momentum (p): L = r× p . (11.1) Let us imagine the electron as a small ball, revolving about some axis. It possesses angular momentum. Precisely, the angular momentum vector is a vector pointing along the axis of rotation with magnitude proportional to the speed of rotation. A vector which changes sign under space inversion (parity operation) is called a polar vector . r and p are polar vectors as they change sign. Since L = (−r)× (−p), L does not change sign under parity operation. Such vectors which do not change sign under parity operation are called axial vectors or psuedo-vectors. Classically, the angular momentum of the electron could have any magnitude. In quantum mechanics the orbital angular momentum operator is obtained by replacing p by −i~∇. The angular position of a particle is the angle at which it is located in two-dimensional polar coordinates.
A particle moving along a straight-line has a linear momentum mv. A revolving particle has angular momentum due to its mass and angular velocity. Let us imagine the electron as a small ball, revolving about some axis. It possesses angular momentum. Precisely, the angular momentum vector is a vector pointing along the axis of rotation with magnitude proportional to the speed of rotation. In classical mechanics the symmetry of a physical system leads to conservation laws. If the space is isotropic, it possesses rotational symmetry. The number of elements in a group is called its order. A group with finite number of elements is called a finite group whereas an infinite group contains infinite number of elements. An infinite group may further be either discrete or continuous. In fact, it is impossible to tell whether an electron is spinning. The word spin is a convenient way of representing the intrinsic angular momentum of a particle.
The orbital angular momentum of a particle in quantum mechanics is defined exactly as in classical mechanics. Before developing any properties of the angular momentum operators, students must know the commutation relations they satisfy with themselves, with the momentum operator, and with the position operator. The angular momentum operator is very closely related to rotations of the system. Students should compare the ability of the angular momentum operator to generate infinitesimal rotations, with the corresponding property of the linear momentum p. The chapter provides the theory of the orbital angular momentum sufficiently to study the problem of a particle in a central potential.
The angular momentum plays an important role in quantum mechanics. It is no longer an ordinary vector, instead it is a vector operator, whose three components do not commute with each other. In quantum mechanics, the angular momentum becomes a vector operator. A general angular momentum is defined as a vector operator whose components are Hermitian operators satisfying the commutation relations similar to those for the orbital angular momentum. In order to obtain the eigenvalues and eigenfunctions, it is more convenient to express the orbital angular momentum operators in spherical polar coordinates. Spin angular momentum is an intrinsic property of elementary particles. In quantum computing, a qubit or quantum bit is a quantum version of the classical binary bit physically realized in a two-state quantum-mechanical system.
Abstract In this chapter we introduce the concept of orbital angular momentum into the mathematical language of quantum mechanics. We discuss the commutation relations of the corresponding operators and their roles as generators of rotations in the context of the theory of Lie groups and Lie algebras, focusing on the three-dimensional rotation group SO(3). We further examine how scalar and vector-valued operators transform under spatial rotations. We then turn to the derivation of the eigenfunctions and eigenvalues of the angular-momentum operators, for which we follow a dual approach in analogy to that employed for the harmonic oscillator in Chapter 5. Using both the algebraic ladder-operator method and an analytical method using spherical polar coordinates we discover the relevant azimuthal and magnetic quantum numbers and their relation to the spherical harmonics and the Legendre polynomials
This chapter focuses on the concept of rotational motion. It explains that energy and angular momentum for a particle rotating in two- or three-dimensions are quantized and satisfied cyclic boundary conditions, which imply the quantization of angular momentum's magnitude and z-component. The electronic structure of atoms showcases rotational motion because electrons orbit around nuclei and spin on their axis. The chapter details the solutions for the Schrödinger equation and the vector model of angular momentum. It also discusses the concept of space quantization revolving around the quantum mechanical result of a rotating body that may not take up an arbitrary orientation concerning some specified axis.
The quantum mechanical description of the azimuthal rotation angle and the orbital angular momentum around the polar axis differs greatly from the description of position and momentum. This has led to a controversy over the existence of a self-adjoint angle operator in the literature. It is possible to circumvent the problems of defining a self-adjoint operator for a periodic variable by using trigonometric functions of operators as a basis for the quantum mechanical description. This approach, however, does not allow us to study the properties of the angle operator itself. By using a state space of an arbitrarily large yet finite number of dimensions, it is possible to introduce angle and orbital angular momentum as a conjugate pair of variables both represented by Hermitian matrices. After physical and measurable quantities have been calculated in this state space the number of dimensions is allowed to tend to infinity in a limiting procedure. The first part of this chapter reviews the difficulties associated with the quantum mechanical formulation of angle and orbital angular momentum and presents a way to overcome these problems using a finite-dimensional state space. In the second part this formulation is generalised to include the phenomenon of non-integer orbital angular momentum. This part is based on a chapter of the PhD thesis of Götte [1], where further details may be found. Introduction The correct description of a periodic variable such as a rotation angle or the optical phase has been a long standing problem in quantum mechanics. At the root of the problem is the question of whether the variable itself is restricted in a 2 π radian range or whether it evolves continuously without bound.