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Vestnik Tomskogo gosudarstvennogo universiteta Matematika i mekhanika

ANALYTICAL SOLUTION OF THE SCHRÖDINGER INTEGRAL EQUATION

Mikhail Alekseevich Bubenchikov, Aleksey Mikhailovich BUBENCHIKOV, Soninbayar Jambaa, Alexander Lun-Fu, Anna Sergeevna Chelnokova

Published Jan 1, 2020• 0 citations
Publisher

Abstract

In this paper, the question about the use of wave dynamics for solving problems of membrane separation of helium isotopes in the gas state at cryogenic temperatures is considered. The dimensionless form of the stationary Schrödinger differential equation is obtained. Following that, the integral representation form of the wave function is written. This form, which is equivalent to the classical equation, is similar to the integral equation with a degenerate core; however, it contains a modulus of the argument with a shift along the real axis. Using the shift operator, the existing exponential function in the Schrödinger integral equation can be split into a differential operator and an exponential function of the argument module which does not contain a shift. The Fourier identity allows reducing the exponent of the modulus of the argument to a regular exponent. Next, based on the general property of a differential operator acting on an exponent, it is possible to calculate the spectral functions of the problem and write down the distribution for the wave function. This distribution is ultimately expressed through the spectra of the potential barrier. Thereafter, the structure and the spectrum of the composite barrier are considered. With the expression determining the reflection coefficient, it is found that the double-barrier system can have a resonant passage of one of the components in the sequence of distances between the layers of the membrane.

DOI
10.17223/19988621/67/1

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In this paper, the question about the use of wave dynamics for solving problems of membrane separation of helium isotopes in the gas state at cryogenic temperatures is considered. The dimensionless form of the stationary Schrödinger differential equation is obtained. Following that, the integral representation form of the wave function is written. This form, which is equivalent to the classical equation, is similar to the integral equation with a degenerate core; however, it contains a modulus of the argument with a shift along the real axis. Using the shift operator, the existing exponential function in the Schrödinger integral equation can be split into a differential operator and an exponential function of the argument module which does not contain a shift. The Fourier identity allows reducing the exponent of the modulus of the argument to a regular exponent. Next, based on the general property of a differential operator acting on an exponent, it is possible to calculate the spectral functions of the problem and write down the distribution for the wave function. This distribution is ultimately expressed through the spectra of the potential barrier. Thereafter, the structure and the spectrum of the composite barrier are considered. With the expression determining the reflection coefficient, it is found that the double-barrier system can have a resonant passage of one of the components in the sequence of distances between the layers of the membrane.
An analytical solution to the problem of wave transport of matter through composite hyper-fine barriers is constructed. It is shown that, for a composite membrane consisting of two identical ultra-thin layers, there are always distances between the layers at which the resonant passage of one of the components is realized. Resonance makes it possible to separate de Broiler waves of particles with the same properties, which differ only in masses. Broad bands of hyper-selective separation of a hydrogen isotope mixture are found at the temperature of 40 K.
Abstract The use of hydrogen and helium as a fuel requires well-developed technologies for the separation of gas mixtures, in particular, separation of isotopes of an element. The presence of quantum effects makes such processes possible, and the proposed system of two potential barriers enhances the differences in the passage of isotopes through two layers of matter providing high separation efficiency. The probability of atoms passing through composite barriers is derived from the solving of stationary Schrodinger equation.
Motions of particles through a permeable barrier are studied from the standpoint of Schrodinger wave dynamics. We consider time evolution of a substance concentration spot in the vicinity of one or two potential barriers. To solve the problem we developed a computer technology for integration of the non-stationary Schrödinger equation. The technology is based on symbol mapping and the matrix exponential method which was applied earlier to solve the classical heat equation. The developed theory is relevant to development of nanotechnology, in particular, to studies on permeability of nanoporous membranes.
The stationary Schrodinger equation depending on spatial coordinates has been considered. The problem of obtaining a differential relationship for the wave function squared was posed. By extracting Schrodinger's equation itself from this relationship a differential equation for a physically interpretable quantity, i.e. the probability density (wave function squared), has been formulated. As an example the one-dimensional case admitting a simple analytic solution was considered. The solution obtained is shown to be a solution squared of the corresponding nonlinear differential equation for the probability density. In the final section a more general non-stationary case was considered for the potential involving a time-dependent term, such potentials are found in the non-stationary perturbation theory. The constant in separating the variables remains real. Thus the procedure considered proves to be similar to that presented above for the stationary equation.