We extend the tools of quantum resource theories to scenarios in which multiple quantities (or resources) are present, and their interplay governs the evolution of physical systems. We derive conditions for the interconversion of these resources, which generalise the first law of thermodynamics. We study reversibility conditions for multi-resource theories, and find that the relative entropy distances from the invariant sets of the theory play a fundamental role in the quantification of the resources. The first law for general multi-resource theories is a single relation which links the change in the properties of the system during a state transformation and the weighted sum of the resources exchanged. In fact, this law can be seen as relating the change in the relative entropy from different sets of states. In contrast to typical single-resource theories, the notion of free states and invariant sets of states become distinct in light of multiple constraints. Additionally, generalisations of the Helmholtz free energy, and of adiabatic and isothermal transformations, emerge. We thus have a set of laws for general quantum resource theories, which generalise the laws of thermodynamics. We first test this approach on thermodynamics with multiple conservation laws, and then apply it to the theory of local operations under energetic restrictions.
We extend the tools of quantum resource theories to scenarios in which multiple quantities (or resources) are present, and their interplay governs the evolution of physical systems. We derive conditions for the interconversion of these resources, which generalise the first law of thermodynamics. We study reversibility conditions for multi-resource theories, and find that the relative entropy distances from the invariant sets of the theory play a fundamental role in the quantification of the resources. The first law for general multi-resource theories is a single relation which links the change in the properties of the system during a state transformation and the weighted sum of the resources exchanged. In fact, this law can be seen as relating the change in the relative entropy from different sets of states. In contrast to typical single-resource theories, the notion of free states and invariant sets of states become distinct in light of multiple constraints. Additionally, generalisations of the Helmholtz free energy, and of adiabatic and isothermal transformations, emerge. We thus have a set of laws for general quantum resource theories, which generalise the laws of thermodynamics. We first test this approach on thermodynamics with multiple conservation laws, and then apply it to the theory of local operations under energetic restrictions.
We extend the tools of quantum resource theories to scenarios in which multiple quantities (or resources) are present, and their interplay governs the evolution of physical systems. We derive conditions for the interconversion of these resources, which generalise the first law of thermodynamics. We study reversibility conditions for multi-resource theories, and find that the relative entropy distances from the invariant sets of the theory play a fundamental role in the quantification of the resources. The first law for general multi-resource theories is a single relation which links the change in the properties of the system during a state transformation and the weighted sum of the resources exchanged. In fact, this law can be seen as relating the change in the relative entropy from different sets of states. In contrast to typical single-resource theories, the notion of free states and invariant sets of states become distinct in light of multiple constraints. Additionally, generalisations of the Helmholtz free energy, and of adiabatic and isothermal transformations, emerge. We thus have a set of laws for general quantum resource theories, which generalise the laws of thermodynamics. We first test this approach on thermodynamics with multiple conservation laws, and then apply it to the theory of local operations under energetic restrictions.
Resource theories are a set of tools, coming from the field of quantum information theory, that find applications in the study of several physical scenarios. These theories describe the physical world from the perspective of an agent, who acts over a system to modify its quantum state, while having at disposal a limited set of operations. A noticeable example of a physical theory which has recently been described with these tools is quantum thermodynamics, consisting in the study of thermodynamic phenomena at the nano-scale. In the standard approach to resource theories, it is usually the case that the constraints over the set of available operations single out a unique resource. In this thesis, we extend the resource theoretic framework to include situations where multiple resources can be identified, and we apply our findings to the study of quantum thermodynamics, to gain a better understanding of quantities like work and heat in the microscopic regime. We introduce a mathematical framework to study resource theories with multiple resources, and we explore under which conditions these multi-resource theories are reversible. Furthermore, we investigate the interconversion of resources, i.e., in which situations it is possible to exchange between two different kinds of resources. We then apply this formalism to quantum thermodynamics, where the two resources under consideration are energy and entropy. This multi-resource theory allows us to explore thermodynamics when the system under examination is closed or coupled with a thermal environment with a finite size. In addition to our work on multi-resource theories, we study the states of equilibrium of closed systems, known as passive states, and analyse under which circumstances it is possible to extract energy from these states. We show that passivity is energetically unstable, and that, even for closed systems, the only stable states are those with a well-defined temperature.
The second law of thermodynamics is the cornerstone of physics, characterizing the convertibility between thermodynamic states through a single function, entropy. Given the universal applicability of thermodynamics, a fundamental question in quantum information theory is whether an analogous second law can be formulated to characterize the convertibility of resources for quantum information processing by a single function. In 2008, a promising formulation was proposed, linking resource convertibility to the optimal performance of a variant of the quantum version of hypothesis testing. Central to this formulation was the generalized quantum Stein's lemma, which aimed to characterize this optimal performance by a measure of quantum resources, the regularized relative entropy of resource. If proven valid, the generalized quantum Stein's lemma would lead to the second law for quantum resources, with the regularized relative entropy of resource taking the role of entropy in thermodynamics. However, in 2023, a logical gap was found in the original proof of this lemma, casting doubt on the possibility of such a formulation of the second law. In this work, we address this problem by developing alternative techniques to successfully prove the generalized quantum Stein's lemma under a smaller set of assumptions than the original analysis. Based on our proof, we reestablish and extend the second law of quantum resource theories, applicable to both static resources of quantum states and a fundamental class of dynamical resources represented by classical-quantum (CQ) channels. These results resolve the fundamental problem of bridging the analogy between thermodynamics and quantum information theory.
How far can we take the resource theoretic approach to explore physics? Resource theories like LOCC, reference frames and quantum thermodynamics have proven a powerful tool to study how agents who are subject to certain constraints can act on physical systems. This approach has advanced our understanding of fundamental physical principles, such as the second law of thermodynamics, and provided operational measures to quantify resources such as entanglement or information content. In this work, we significantly extend the approach and range of applicability of resource theories. Firstly we generalize the notion of resource theories to include any description or knowledge that agents may have of a physical state, beyond the density operator formalism. We show how to relate theories that differ in the language used to describe resources, like micro and macroscopic thermodynamics. Finally, we take a top-down approach to locality, in which a subsystem structure is derived from a global theory rather than assumed. The extended framework introduced here enables us to formalize new tasks in the language of resource theories, ranging from tomography, cryptography, thermodynamics and foundational questions, both within and beyond quantum theory.
The ideas of thermodynamics have proved fruitful in the setting of quantum information theory, in particular the notion that when the allowed transformations of a system are restricted, certain states of the system become useful resources with which one can prepare previously inaccessible states. The theory of entanglement is perhaps the best-known and most well-understood resource theory in this sense. Here, we return to the basic questions of thermodynamics using the formalism of resource theories developed in quantum information theory and show that the free energy of thermodynamics emerges naturally from the resource theory of energy-preserving transformations. Specifically, the free energy quantifies the amount of useful work which can be extracted from asymptotically many copies of a quantum system when using only reversible energy-preserving transformations and a thermal bath at fixed temperature. The free energy also quantifies the rate at which resource states can be reversibly interconverted asymptotically, provided that a sublinear amount of coherent superposition over energy levels is available, a situation analogous to the sublinear amount of classical communication required for entanglement dilution.
Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. We generalize thermodynamic resource theories to exchanges of observables other than heat, to baths other than heat baths, and to free energies other than the Helmholtz free energy. These generalizations are illustrated with "grand-potential" theories that model movements of heat and particles. Free operations include unitaries that conserve energy and particle number. From this conservation law and from resource-theory principles, the grand-canonical form of the free states is derived. States are shown to form a quasiorder characterized by free operations, d majorization, the hypothesis-testing entropy, and rescaled Lorenz curves. We calculate the work distillable from-and we bound the work cost of creating-a state. These work quantities can differ but converge to the grand potential in the thermodynamic limit. Extending thermodynamic resource theories beyond heat baths, we open diverse realistic systems to modeling with one-shot statistical mechanics. Prospective applications such as electrochemical batteries are hoped to bridge one-shot theory to experiments.