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Quantum thermal equilibration from equipartition

A. V. Ponomarev, S. Denisov, Peter Hänggi A, John A. Gemmer

Published Jan 1, 2012• 10 citations
OpenAlex

Abstract

The problem of mutual equilibration between two finite, identical quantum systems, A and B, prepared initially at different temperatures is elucidated. We show that the process of energy exchange between the two systems leads to accurate equipartition within energy shells in the Hilbert space of the total non-interacting, composite system, A \otimes B. This scenario occurs under the general condition of a weak interaction between the systems. We predict that the sole hypothesis of such equipartition is sufficient to obtain a relaxation of the peers, A and B, towards a common thermal-like state. This conjecture is fully corroborated by an exact diagonalization of several quantum models.

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The problem of mutual equilibration between two finite, identical quantum systems, A and B, prepared initially at different temperatures is elucidated. We show that the process of energy exchange between the two systems leads to accurate equipartition within energy shells in the Hilbert space of the total non-interacting, composite system, A \otimes B. This scenario occurs under the general condition of a weak interaction between the systems. We predict that the sole hypothesis of such equipartition is sufficient to obtain a relaxation of the peers, A and B, towards a common thermal-like state. This conjecture is fully corroborated by an exact diagonalization of several quantum models.
The problem of mutual equilibration between two finite, identical quantum systems, A and B , prepared initially at different temperatures is elucidated. We show that the process of energy exchange between the two systems leads to accurate equipartition within energy shells in the Hilbert space of the total non-interacting, composite system, A ⊗ B . This scenario occurs under the general condition of a weak interaction between the systems. We predict that the sole hypothesis of such equipartition is sufficient to obtain a relaxation of the peers, A and B , towards a common thermal-like state. This conjecture is fully corroborated by an exact diagonalization of several quantum models.
Two identical finite quantum systems prepared initially at different temperatures, isolated from the environment, and subsequently brought into contact are demonstrated to relax towards Gibbs-like quasiequilibrium states with a common temperature and small fluctuations around the time-averaged expectation values of generic observables. The temporal thermalization process proceeds via a chain of intermediate Gibbs-like states. We specify the conditions under which this scenario occurs and corroborate the quantum equilibration with two different models.
Two identical finite quantum systems prepared initially at different temperatures, isolated from the environment, and subsequently brought into contact are demonstrated to relax towards Gibbs-like quasi-equilibrium states with a common temperature and small fluctuations around the time-averaged expectation values of generic observables. The temporal thermalization process proceeds via a chain of intermediate Gibbs-like states. We specify the conditions under which this scenario occurs and corroborate the quantum equilibration with two different models.
Using a unitary time evolution scheme, we demonstrate an approach towards a Gibbs-like equilibrium state, with a common temperature and a chemical potential, of two metallic grains connected by a weak link prepared with a different number of noninteracting electrons. This unitary equilibration is achieved by coupling the link to a third finite mesoreservoir that can emulate dephasing and inelastic processes. The two quantum systems equilibrate but do not evolve towards a canonical state when mimicking dephasing effects only. Exact numerical results are supported by analytic calculations based on an extension of the quantum Langevin equation approach, providing the dynamics of the total density matrix.
One of the main questions of research on quantum many-body systems following unitary out of equilibrium dynamics is to find out how local expectation values equilibrate in time. For non-interacting models, this question is rather well understood. However, the best known bounds for general quantum systems are vastly crude, scaling unfavorable with the system size. Nevertheless, empirical and numerical evidence suggests that for generic interacting many-body systems, generic local observables, and sufficiently well-behaved states, the equilibration time does not depend strongly on the system size, but only the precision with which this occurs does. In this discussion paper, we aim at giving very simple and plausible arguments for why this happens. While our discussion does not yield rigorous results about equilibration time scales, we believe that it helps to clarify the essential underlying mechanisms, the intuition and important figure of merits behind equilibration. We then connect our arguments to common assumptions and numerical results in the field of equilibration and thermalization of closed quantum systems, such as the eigenstate thermalization hypothesis as well as rigorous results on interacting quantum many-body systems. Finally, we complement our discussions with numerical results - both in the case of examples and counter-examples of equilibrating systems.
A generic non-integrable (unitary) out-of-equilibrium quantum process, when interrogated across many times, is shown to yield the same statistics as an (non-unitary) equilibrated process. In particular, using the tools of quantum stochastic processes, we prove that under loose assumptions, quantum processes equilibrate within finite time intervals. Sufficient conditions for this to occur are that multitime observables are coarse grained in both space and time, and that the initial state overlaps with many different energy eigenstates. These results help bridge the gap between (unitary) quantum and (non-unitary) statistical physics, i.e., when all multitime properties and correlations are well approximated by stationary quantities, which includes non-Markovianity and temporal entanglement. We discuss implications of this result for the emergence of classical stochastic processes from multitime measurements of an underlying genuinely quantum system.