Abstract The very notion of a current fluctuation is problematic in the quantum context. We study that problem in the context of nonequilibrium statistical mechanics, both in a microscopic setup and in a Markovian model. Our answer is based on a rigorous result that relates the weak coupling limit of fluctuations of reservoir observables under a global unitary evolution with the statistics of the so-called quantum trajectories. These quantum trajectories are frequently considered in the context of quantum optics, but they remain useful for more general nonequilibrium systems. In contrast with the approaches found in the literature, we do not assume that the system is continuously monitored. Instead, our starting point is a relatively realistic unitary dynamics of the full system
Abstract The very notion of a current fluctuation is problematic in the quantum context. We study that problem in the context of nonequilibrium statistical mechanics, both in a microscopic setup and in a Markovian model. Our answer is based on a rigorous result that relates the weak coupling limit of fluctuations of reservoir observables under a global unitary evolution with the statistics of the so-called quantum trajectories. These quantum trajectories are frequently considered in the context of quantum optics, but they remain useful for more general nonequilibrium systems. In contrast with the approaches found in the literature, we do not assume that the system is continuously monitored. Instead, our starting point is a relatively realistic unitary dynamics of the full system
We derive a general scheme to obtain quantum fluctuation relations for dynamical observables in open quantum systems. For concreteness, we consider Markovian nonunitary dynamics that is unraveled in terms of quantum jump trajectories and exploit techniques from the theory of large deviations like the tilted ensemble and the Doob transform. Our results here generalize to open quantum system fluctuation relations previously obtained for classical Markovian systems and add to the vast literature on fluctuation relations in the quantum domain, but without resorting to the standard two-point measurement scheme. We illustrate our findings with three examples to highlight and discuss the main features of our general result.
Abstract We consider Markovian open quantum dynamics with weak unitary symmetries. Starting from the quantum master equation (QME) for the system alone, it is known that the joint dynamics of the system and its environment can be obtained by dilation, leading to a closed dynamics for a continuous matrix product state. Performing counting measurements on the environment gives rise to stochastic dynamics of quantum trajectories for the system, which when averaged yield back the QME. In this work, we identify necessary and sufficient conditions under which the dynamics of these different descriptions retain the weak symmetry of the QME and we characterise the resulting symmetries of the different descriptions in terms of their generators. We find that the joint dynamics always features a separable symmetry directly related to that of the QME, but for quantum trajectories the corresponding symmetry is present only if the counting measurement satisfies certain conditions.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
Starting from a generalization of the quantum trajectory theory [based on the stochastic Schr\"odinger equation (SSE)], non-Markovian models of quantum dynamics are derived. In order to describe non-Markovian effects, the approach used in this article is based on the introduction of random coefficients in the usual linear SSE. A major interest is that this allows a consistent theory of quantum measurement in continuous time to be developed for these non-Markovian quantum trajectory models. In this context, the notions of ``instrument,'' ``a priori,'' and ``a posteriori'' states can be introduced. The key point is that by starting from a stochastic equation on the Hilbert space of the system, we are able to respect the complete positivity of the mean dynamics for the statistical operator and the requirements of the axioms of quantum measurement theory. The flexibility of the theory is next illustrated by a concrete physical model of a noisy oscillator where non-Markovian effects come from the random environment, colored noises, randomness in the stimulating light, and delay effects. The statistics of the emitted photons and the heterodyne and homodyne spectra are studied, and we show how these quantities are sensitive to the non-Markovian features of the system dynamics, so that, in principle, the observation and analysis of the fluorescent light could reveal the presence of non-Markovian effects and allow for a measure of the spectra of the noises affecting the system dynamics.
Do stochastic Schr\"odinger equations, also known as unravelings, have a physical interpretation? In the Markovian limit, where the system on average obeys a master equation, the answer is yes. Markovian stochastic Schr\"odinger equations generate quantum trajectories for the system state conditioned on continuously monitoring the bath. For a given master equation, there are many different unravelings, corresponding to different sorts of measurement on the bath. In this paper we address the non-Markovian case, and in particular the sort of stochastic Schr\"odinger equation introduced by Strunz, Di\'osi, and Gisin [Phys. Rev. Lett. 82, 1801 (1999)]. Using a quantum-measurement theory approach, we rederive their unraveling that involves complex-valued Gaussian noise. We also derive an unraveling involving real-valued Gaussian noise. We show that in the Markovian limit, these two unravelings correspond to heterodyne and homodyne detection, respectively. Although we use quantum-measurement theory to define these unravelings, we conclude that the stochastic evolution of the system state is not a true quantum trajectory, as the identity of the state through time is a fiction.
This thesis considers quantum systems which interact with their surrounding environment. Specifically we consider the underlying stochastic dynamics which arise from the back-action of measurements performed in the environment. These quantum trajectories can be tracked by continuously monitoring the environment, as is now possible in modern experiments. We consider phenomena understood at the average level of the system state density matrix, and explore these at this more information rich level. This is especially relevant for experimental setups and implementation of quantum technologies. Firstly, we consider how systems exhibiting metastability behave at the level of stochastic quantum trajectories. In doing so we make comparisons to classical theories of metastability, where trajectories exhibit fast relaxation into distinct phases and slow transitions between them. We also illustrate when this phenomenology does not hold, with instead the emergence of a slow manifold in the form of a decoherence free subspace. We also highlight the useful role that quantum reset processes can play in the analysis of stochastic quantum trajectories. The dynamics of the stochastic quantum trajectories depends on the choice of environmental measurements. There are many choices which leave the average dynamics unchanged, but give different statistical ensembles of quantum trajectories. This gauge freedom of the average dynamics is well known. We derive the analogous result at the level of quantum trajectory ensembles; giving the measurement protocols which leave the generator of the stochastic trajectory dynamics unchanged. We also extend this to include joint trajectories of conditional system states and their associated measurement records, either full records or coarse-grained. Using these results on gauge freedoms of quantum trajectories, we consider the conditions under which the trajectory dynamics exhibit a weak unitary symmetry. We then consider under what conditions the joint state of the system and environment exhibit symmetric dynamics, including under various levels of dephasing. We find that the joint dynamics always features a separable symmetry directly related to that of the quantum master equation, but for quantum trajectories the corresponding symmetry is present only if the counting measurement satisfies certain conditions.