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Dissipative Time Evolution of Observables in Non-equilibrium Statistical Quantum Systems

Herbert Nachbagauer

Published Jan 1, 1998• 0 citations
OpenAlex

Abstract

We discuss differential-- versus integral--equation based methods describing out--of thermal equilibrium systems and emphasize the importance of a well defined reduction to statistical observables. Applying the projection operator approach, we investigate on the time evolution of expectation values of linear and quadratic polynomials in position and momentum for a statistical anharmonic oscillator with quartic potential. Based on the exact integro-differential equations of motion, we study the first and naive second order approximation which breaks down at secular time-scales. A method is proposed to improve the expansion by a non--perturbative resummation of all quadratic operator correlators consistent with energy conservation for all times. Motion cannot be described by an effective Hamiltonian local in time reflecting non-unitarity of the dissipative entropy generating evolution. We numerically integrate the consistently improved equations of motion for large times. We relate entropy to the uncertainty product, both being expressible in terms of the observables under consideration.

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We discuss differential-- versus integral--equation based methods describing out--of thermal equilibrium systems and emphasize the importance of a well defined reduction to statistical observables. Applying the projection operator approach, we investigate on the time evolution of expectation values of linear and quadratic polynomials in position and momentum for a statistical anharmonic oscillator with quartic potential. Based on the exact integro-differential equations of motion, we study the first and naive second order approximation which breaks down at secular time-scales. A method is proposed to improve the expansion by a non--perturbative resummation of all quadratic operator correlators consistent with energy conservation for all times. Motion cannot be described by an effective Hamiltonian local in time reflecting non-unitarity of the dissipative entropy generating evolution. We numerically integrate the consistently improved equations of motion for large times. We relate entropy to the uncertainty product, both being expressible in terms of the observables under consideration.
We propose a new approximation-technique to deal with the exact macroscopic integro-differential evolution equations of statistical systems which self-consistently accounts for dissipative effects. Concentrating on one and two point equal-time correlators, we develop the self-consistent method and apply it to a scalar field theory with quartic self-interaction. We derive the effective equations of motion and the corresponding macroscopic effective Hamiltonian. Non-locality in time appears in a natural way necessary to account for entropy generating processes.
The motion of a particle subject to an external force and coupled to a large number of harmonic oscillators is reducible to a nonlinear integro-differential equation for the position operator. This is achieved by eliminating the degrees of freedom corresponding to the motion of the oscillators. Upon this elimination the commutator of the position and the mechanical momentum of the particle becomes time dependent and a c number for a quadratic potential, but in general a q number for other fields of force. For a harmonically bound particle interacting with the heat bath the time evolution of the position and momentum operators are given in terms of the solutions of an integro-differential equation. Certain forms of the coupling of the motion of the particle to the heat bath allow for further reduction of these equations to quartic differential equations with constant coefficients. For these cases the time dependence of the position-momentum commutator, the energy of the particle as well as the heat bath are studied.
We consider non-equilibrium open statistical systems, subject to potentials and to external “heat baths” (hb) at thermal equilibrium at temperature T (either with ab initio dissipation or without it). Boltzmann’s classical equilibrium distributions generate, as Gaussian weight functions in momenta, orthogonal polynomials in momenta (the position-independent Hermite polynomialsHn’s). The moments of non-equilibrium classical distributions, implied by the Hn’s, fulfill a hierarchy: for long times, the lowest moment dominates the evolution towards thermal equilibrium, either with dissipation or without it (but under certain approximation). We revisit that hierarchy, whose solution depends on operator continued fractions. We review our generalization of that moment method to classical closed many-particle interacting systems with neither a hb nor ab initio dissipation: with initial states describing thermal equilibrium at T at large distances but non-equilibrium at finite distances, the moment method yields, approximately, irreversible thermalization of the whole system at T, for long times. Generalizations to non-equilibrium quantum interacting systems meet additional difficulties. Three of them are: (i) equilibrium distributions (represented through Wigner functions) are neither Gaussian in momenta nor known in closed form; (ii) they may depend on dissipation; and (iii) the orthogonal polynomials in momenta generated by them depend also on positions. We generalize the moment method, dealing with (i), (ii) and (iii), to some non-equilibrium one-particle quantum interacting systems. Open problems are discussed briefly.
The time evolution of the correlation functions of an ensemble of anharmonic N-component oscillators with O(N) symmetry is described by a flow equation, exact up to corrections of order 1/N21/N^21/N2. We find effective irreversibility. Nevertheless, analytical and numerical investigation reveals that the system does not reach thermal equilibrium for large times, even when N→∞N\to \inftyN→∞. Depending on the initial distribution, the dynamics is asymptotically stable or it exhibits growing modes which break the conditions for the validity of the 1/N expansion for large time. We investigate both classical and quantum systems, the latter being the limit of an O(N) symmetric scalar quantum field theory in zero spatial dimensions.
We investigate the time evolution of a classical ensemble of isolated periodic chains of O(N)O(N)O(N)-symmetric anharmonic oscillators. Our method is based on an exact evolution equation for the time dependence of correlation functions. We discuss its solutions in an approximation which retains all contributions in next-to-leading order in a 1/N1/N1/N expansion and preserves time reflection symmetry. We observe effective irreversibility and approximate thermalization. At large time the system approaches stationary solutions in the vicinity of, but not identical to, thermal equilibrium. The ensemble therefore retains some memory of the initial condition beyond the conserved total energy. Such behavior with incomplete thermalization is referred to as ``mesoscopic dynamics.'' It is expected for systems in a small volume. Surprisingly, we find that the nonthermal asymptotic stationary solutions do not change for large volume. This raises questions on Boltzmann's conjecture that macroscopic isolated systems thermalize.