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Relaxation phenomena at criticality

Andrea Gambassi

Published Jan 1, 2008• 24 citations
OpenAlex

Abstract

The collective behaviour of statistical systems close to critical points is characterized by an extremely slow dynamics which, in the thermodynamic limit, eventually prevents them from relaxing to an equilibrium state after a change in the thermodynamic control parameters. The non-equilibrium evolution following this change displays some of the features typically observed in glassy materials, such as ageing, and it can be monitored via dynamic susceptibilities and correlation functions of the order parameter, the scaling behaviour of which is characterized by universal exponents, scaling functions, and amplitude ratios. This universality allows one to calculate these quantities in suitable simplified models and field-theoretical methods are a natural and viable approach for this analysis. In addition, if a statistical system is spatially confined, universal Casimir-like forces acting on the confining surfaces emerge and they build up in time when the temperature of the system is tuned to its critical value. We review here some of the theoretical results that have been obtained in recent years for universal quantities, such as the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the Ising model with Glauber dynamics in the bulk. The non-equilibrium dynamics of the Casimir force acting in a film is discussed within the Gaussian model.

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Relaxation phenomena at criticality

Andrea Gambassi

The collective behaviour of statistical systems close to critical points is characterized by an extremely slow dynamics which, in the thermodynamic limit, eventually prevents them from relaxing to an equilibrium state after a change in the thermodynamic control parameters. The non-equilibrium evolution following this change displays some of the features typically observed in glassy materials, such as ageing, and it can be monitored via dynamic susceptibilities and correlation functions of the order parameter, the scaling behaviour of which is characterized by universal exponents, scaling functions, and amplitude ratios. This universality allows one to calculate these quantities in suitable simplified models and field-theoretical methods are a natural and viable approach for this analysis. In addition, if a statistical system is spatially confined, universal Casimir-like forces acting on the confining surfaces emerge and they build up in time when the temperature of the system is tuned to its critical value. We review here some of the theoretical results that have been obtained in recent years for universal quantities, such as the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the Ising model with Glauber dynamics in the bulk. The non-equilibrium dynamics of the Casimir force acting in a film is discussed within the Gaussian model.

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Ageing and non-equilibrium critical phenomena in Monte Carlo simulations

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It is considered the non-equilibrium critical evolution of statistical systems which displays some features, such as ageing and violation of the fluctuation-dissipation theorem. We review here some theoretical results of computations that have been obtained in recent years for universal quantities, such as the exponents determining the scaling behaviour of dynamic response and correlation functions and the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the 3D pure and diluted Ising models with Glauber dynamics. We analyse an influence of critical fluctuations, different non-equilibrium initial states and presence of nonmagnetic impurities in spin systems on two-time dependence of correlation and response functions on characteristic time variables as waiting time t w and time of observation t – t w with t > t w . We discuss the obtained values of non-equilibrium exponents for autocorrelation and response functions and values of the universal long-time limit of the fluctuation-dissipation ratio X ∞ . Analysis of simulation results show that the insertion of disorder leads to new values of X ∞ with X ∞ diluted > X ∞ pure .

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In the past few years, systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this everlasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put on the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation–dissipation relations are discussed and in particular the concept of fluctuation–dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The renormalization-group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them, the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular, the results for models A, B and C dynamics of the O ( N ) Ginzburg–Landau Hamiltonian, and model A dynamics of the weakly dilute Ising magnet and of the φ 3 theory are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of model A dynamics is also addressed within the mean-field approximation.

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Non-equilibrium critical dynamics

Uwe Claus Täuber

We now begin our exposition of universal dynamic scaling behavior that emerges under non-equilibrium conditions. We are mainly concerned with the relaxational models A and B here, but also touch on other dynamic universality classes. First, we consider non-equilibrium critical relaxation from a disordered initial state, and compute the associated universal scaling exponents within the dynamic renormalization group framework. Related phenomena in the early-time regime, prior to reaching temporally translationally invariant asymptotics, are ‘aging’ and a non-equilibrium fluctuation-dissipation ratio, both of which have enjoyed prominence in the literature on ‘glassy’ kinetics. In this context, we derive the critical initial slip exponent for the order parameter, and briefly discuss interesting persistence properties. Second, we explore the long-time scaling laws in phase ordering kinetics and coarsening for the relaxational models, following a fast temperature ‘quench’ into the ordered phase, in systems with either non-conserved or conserved order parameters. Aside from a few explicit computations in the spherical model limit (wherein the number of order parameter components n → ∞), we largely employ phenomenological considerations and scaling theory, stressing the importance of topological defects for energy dissipation during coarsening. Next we address the question how violations of Einstein's relation that links relaxation coefficients and noise correlations might affect the asymptotic dynamic critical scaling behavior. Whereas in systems with non-conserved order parameter typically the equilibrium scaling laws are recovered in the vicinity of the critical point, in contrast genuinely novel universality classes may emerge in the case of a conserved parameter, provided it is driven out of equilibrium in a spatially anisotropic fashion.

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In the past few years systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this ever-lasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put to the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation-dissipation relations are discussed and in particular the concept of fluctuation-dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The Renormalization-Group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular the results for Model A, B, and C dynamics of the O(N) Ginzburg-Landau Hamiltonian, and Model A dynamics of the weakly dilute Ising magnet and of a \phi^3 theory, are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of Model A dynamics is also addressed within the mean-field approximation.

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Aging and non-equilibrium critical phenomena in Monte Carlo simulations of 3D pure and diluted Ising models

Pavel Vladimirovich Prudnikov, Vladimir V. Prudnikov, Evgenii A. Pospelov +2 more

We investigate the non-equilibrium critical evolution of statistical systems and describe of its some features, such as aging and violation of the fluctuation-dissipation theorem. We consider some theoretical results of computations for universal quantities that have been obtained in recent years, such as the exponents determining the scaling behavior of dynamic response and correlation functions and the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics. We derive our original Monte Carlo simulation results for 3D pure and diluted Ising models with Glauber and Metropolis dynamics. For these models, we analyze the influence of critical fluctuations, different non-equilibrium initial states, and the presence of nonmagnetic impurities on the two-time dependence of correlation and response functions on characteristic time variables, such as waiting time |$t_{\rm w}$| and time of observation |$t - t_{\rm w}$| with |$t>t_{\rm w}$|⁠. We discuss the obtained values of the non-equilibrium exponents for the autocorrelation and response functions and values of the universal long-time limit of the fluctuation-dissipation ratio |$X^{\infty }$|⁠. Our simulation results demonstrate that the insertion of disorder leads to new values of |$X^{\infty }$| with |$X_{\rm diluted}^{\infty }>X_{\rm pure}^{\infty }$|⁠.

Progress of Theoretical and Experimental Physics•May 1, 2015•18 citations
The collective behaviour of statistical systems close to critical points is characterized by an extremely slow dynamics which, in the thermodynamic limit, eventually prevents them from relaxing to an equilibrium state after a change in the thermodynamic control parameters. The non-equilibrium evolution following this change displays some of the features typically observed in glassy materials, such as ageing, and it can be monitored via dynamic susceptibilities and correlation functions of the order parameter, the scaling behaviour of which is characterized by universal exponents, scaling functions, and amplitude ratios. This universality allows one to calculate these quantities in suitable simplified models and field-theoretical methods are a natural and viable approach for this analysis. In addition, if a statistical system is spatially confined, universal Casimir-like forces acting on the confining surfaces emerge and they build up in time when the temperature of the system is tuned to its critical value. We review here some of the theoretical results that have been obtained in recent years for universal quantities, such as the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the Ising model with Glauber dynamics in the bulk. The non-equilibrium dynamics of the Casimir force acting in a film is discussed within the Gaussian model.
The collective behaviour of statistical systems close to critical points is characterized by an extremely slow dynamics which, in the thermodynamic limit, eventually prevents them from relaxing to an equilibrium state after a change in the thermodynamic control parameters. The non-equilibrium evolution following this change displays some of the features typically observed in glassy materials, such as ageing, and it can be monitored via dynamic susceptibilities and correlation functions of the order parameter, the scaling behaviour of which is characterized by universal exponents, scaling functions, and amplitude ratios. This universality allows one to calculate these quantities in suitable simplified models and field-theoretical methods are a natural and viable approach for this analysis. In addition, if a statistical system is spatially confined, universal Casimir-like forces acting on the confining surfaces emerge and they build up in time when the temperature of the system is tuned to its critical value. We review here some of the theoretical results that have been obtained in recent years for universal quantities, such as the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the Ising model with Glauber dynamics in the bulk. The non-equilibrium dynamics of the Casimir force acting in a film is discussed within the Gaussian model.
It is considered the non-equilibrium critical evolution of statistical systems which displays some features, such as ageing and violation of the fluctuation-dissipation theorem. We review here some theoretical results of computations that have been obtained in recent years for universal quantities, such as the exponents determining the scaling behaviour of dynamic response and correlation functions and the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the 3D pure and diluted Ising models with Glauber dynamics. We analyse an influence of critical fluctuations, different non-equilibrium initial states and presence of nonmagnetic impurities in spin systems on two-time dependence of correlation and response functions on characteristic time variables as waiting time t w and time of observation t – t w with t > t w . We discuss the obtained values of non-equilibrium exponents for autocorrelation and response functions and values of the universal long-time limit of the fluctuation-dissipation ratio X ∞ . Analysis of simulation results show that the insertion of disorder leads to new values of X ∞ with X ∞ diluted > X ∞ pure .
In the past few years, systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this everlasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put on the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation–dissipation relations are discussed and in particular the concept of fluctuation–dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The renormalization-group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them, the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular, the results for models A, B and C dynamics of the O ( N ) Ginzburg–Landau Hamiltonian, and model A dynamics of the weakly dilute Ising magnet and of the φ 3 theory are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of model A dynamics is also addressed within the mean-field approximation.
We now begin our exposition of universal dynamic scaling behavior that emerges under non-equilibrium conditions. We are mainly concerned with the relaxational models A and B here, but also touch on other dynamic universality classes. First, we consider non-equilibrium critical relaxation from a disordered initial state, and compute the associated universal scaling exponents within the dynamic renormalization group framework. Related phenomena in the early-time regime, prior to reaching temporally translationally invariant asymptotics, are ‘aging’ and a non-equilibrium fluctuation-dissipation ratio, both of which have enjoyed prominence in the literature on ‘glassy’ kinetics. In this context, we derive the critical initial slip exponent for the order parameter, and briefly discuss interesting persistence properties. Second, we explore the long-time scaling laws in phase ordering kinetics and coarsening for the relaxational models, following a fast temperature ‘quench’ into the ordered phase, in systems with either non-conserved or conserved order parameters. Aside from a few explicit computations in the spherical model limit (wherein the number of order parameter components n → ∞), we largely employ phenomenological considerations and scaling theory, stressing the importance of topological defects for energy dissipation during coarsening. Next we address the question how violations of Einstein's relation that links relaxation coefficients and noise correlations might affect the asymptotic dynamic critical scaling behavior. Whereas in systems with non-conserved order parameter typically the equilibrium scaling laws are recovered in the vicinity of the critical point, in contrast genuinely novel universality classes may emerge in the case of a conserved parameter, provided it is driven out of equilibrium in a spatially anisotropic fashion.
In the past few years systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this ever-lasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put to the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation-dissipation relations are discussed and in particular the concept of fluctuation-dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The Renormalization-Group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular the results for Model A, B, and C dynamics of the O(N) Ginzburg-Landau Hamiltonian, and Model A dynamics of the weakly dilute Ising magnet and of a \phi^3 theory, are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of Model A dynamics is also addressed within the mean-field approximation.
We investigate the non-equilibrium critical evolution of statistical systems and describe of its some features, such as aging and violation of the fluctuation-dissipation theorem. We consider some theoretical results of computations for universal quantities that have been obtained in recent years, such as the exponents determining the scaling behavior of dynamic response and correlation functions and the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics. We derive our original Monte Carlo simulation results for 3D pure and diluted Ising models with Glauber and Metropolis dynamics. For these models, we analyze the influence of critical fluctuations, different non-equilibrium initial states, and the presence of nonmagnetic impurities on the two-time dependence of correlation and response functions on characteristic time variables, such as waiting time |twt_{\rm w}tw​| and time of observation |t−twt - t_{\rm w}t−tw​| with |t>twt>t_{\rm w}t>tw​|⁠. We discuss the obtained values of the non-equilibrium exponents for the autocorrelation and response functions and values of the universal long-time limit of the fluctuation-dissipation ratio |X∞X^{\infty }X∞|⁠. Our simulation results demonstrate that the insertion of disorder leads to new values of |X∞X^{\infty }X∞| with |Xdiluted∞>Xpure∞X_{\rm diluted}^{\infty }>X_{\rm pure}^{\infty }Xdiluted∞​>Xpure∞​|⁠.