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Exploring connections between open quantum systems, relativity and complex quantum networks

Boris Sokolov

Published Dec 5, 2020• 0 citations
OpenAlex

Abstract

This thesis is a collection of works focusing on interrelations between the fields of special relativity, open quantum systems and complex networks. As each of the aforementioned fields encompasses a huge variety of topics, the thesis contains a selection of particular connections. The first half of the thesis considers an open quantum systems approach to the description of relativistic phenomena. As the aforementioned phenomena often involve dynamically evolving counterparts, some non-Markovian aspects of open quantum systems are initially explored. Conditions for complete positivity are derived for a type of phase-covariant time-local master equation and then applied to a non-Markovian master equation with heuristically-derived decay rates. This is relevant in cases when the physicality of the master equation cannot be postulated. The first relativistic system considered is a superposition of coherent states in a gravitational gradient. It is shown to exhibit decoherence induced by gravitational time dilation through interaction between inner degrees of freedom and the centre of mass of the superposition. The decoherence is quantified using various, widely-used non-classicality measures. The decoherence rates are then compared to decoherence induced by classical noise to roughly evaluate the experimental precision necessary to detect gravitationally induced decoherence. In the second relativistic system, the Unruh effect is modeled as an open system where an Unruh-deWitt detector is interacting with bosonic fields. A master equation with time-dependent decay rates for the open system is derived by assuming a non-conventional spacetime path profile for the detector. A particular parameter governing the physical evolution is identified. The system is shown to exhibit non-Markovianity within the completely positive domain of the master equation, the latter ensured by the conditions derived before. The second half of the thesis starts with a definition of complex networks, which are yet not a commonly used tool in quantum physics. The concept of pairwise tomography networks is then introduced as a way to represent many-body quantum states. As the number of pairwise connections grows quadratically with the number of nodes, an efficiently scaling measurement scheme to recover the pairwise tomography networks is presented. The scheme and the concept of pairwise tomography networks are demonstrated to be useful in various applications and the results of a proof-of-principle experiment are shown. One application explored is a paradigmatic spin chain model known as the XX model. A pairwise entanglement network representation of the XX model is shown to suggest new phenomena such as gradual establishment of quasi-long range order accompanied by a symmetry regarding single-spin concurrence distributions. The existence of structural classes and a cyclic self-similarity in the state are revealed.

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Quantum mechanics exhibits a broad collection of theoretical results in complete agreement with experimental evidence. Besides showing unquestionable success in the description of isolated systems, it can be also successfully used to characterize non-isolated quantum system. In such a case, phenomena like dissipation, diffusion or decoherence. The theory of open quantum systems provides the framework where such features can be conveniently explained. \nThis thesis is about decoherence and collapse models. Albeit conceptually they are very far from each other, they both belong the framework of open quantum systems. Indeed, they consider systems interacting with an external entity: an environment for decoherence models, a noise for collapse models. Although the external influence has different origin, they can be described by similar dynamical equations and, to confirm or falsify them, the same experimental tests can be performed. \nThe quantum Brownian motion model can be considered the paradigm of decoherence models. We provide an exact and analytic equation for the time evolution of the operators and we show that the corresponding equation for the states is equivalent to well-known results in the literature. Our derivation allows to compute the time evolution of physically relevant quantities in a much easier way than previous formulations. Moreover, we are not bound to compute the time evolution of the state of the system, which in general is a complicated task. The explicit dependence on the initial state appears only in the initial expectation values and not in the dynamics. This makes possible the derivation of expectation values also for nontrivial states. \nAnother decoherence model we considered is a recently proposed model, based on the mass-energy equivalence. The model describes a decoherence source acting universally on every system whose superposition is extended on positions experiencing different gravitational potentials. We studied the conditions under which this mechanism becomes the dominant decoherence effect in typical interferometric experiments. We show that current experiments are off by several orders of magnitude. New ideas are needed to achieve the necessary requirements. \nThe second part of this thesis concerns collapse models, in particular the Continuous Spontaneous Localization (CSL) model. We focus on experimental tests that can probe it. In this respect, experiments can be grouped in two classes: interferometric tests and non-interferometric ones. The first class includes those experiments, which directly create and detect quantum superpositions of the center of mass of massive systems. The strongest bounds on the CSL parameters come from the second class of non-interferometric experiments, which are sensitive to small position displacements and detect CSL-induced diffusion in position. \nWe investigate how we can benefit from the non-interferometric perspective given by optomechanical setups, which have reached high sensitivities as force and position sensors. Three examples are considered.\nFirst, we compute the upper bounds on the CSL parameters, which can be inferred by the gravitational wave detectors LIGO, LISA Pathfinder and AURIGA.\nSecond, we report new results from an experiment based on a high-quality cantilever cooled to millikelvin temperature. High accuracy measurements of the cantilever thermal fluctuations reveal a nonthermal force noise of unknown origin. This excess noise is compatible with the CSL heating predicted by Adler. Several physical mechanisms able to explain the observed noise have been ruled out.\nThird, we propose an unattempted non-interferometric test aimed to investigate the still unexplored region of the CSL parameter space. Our proposal relies on torsional degrees of freedom rather than the usual vibrational ones. We believe that the test that has been put forward here, will eventually probe the unexplored CSL parameter space.

•Feb 6, 2018•0 citations

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Quantum mechanics has both deepened our understanding of the physical reality and allowed development of quantum technologies beating their classical counterparts in efficiency, security, and sensitivity. As a major downside, the quantum properties behind these technologies are very sensitive to the effects the system’s interaction with its environment. The theory of open quantum systems describes how such interaction influences the system, and as a consequence, how the quantum features are lost, controlled, and possibly returned by manipulating the environment. This thesis begins with a short description of the most relevant features and results of the open quantum system theory. We continue by presenting some commonly used measures to quantify the information encoded in quantum systems and the correlations between spatially or temporally separated parties. The literature review ends with discussion of non-Markovianity and memory effects which combine the fields of open quantum systems and quantum information in a natural way. The rest of the thesis presents the main results of Publications I – VII. We study the memory effects and physicality conditions of open system dynamics described by the vast family of phase-covariant master equations. We show how the open quantum system picture can be exploited to design probing protocols to extract information without knowing how the probe and system interact. Such protocols are considered also from the point-of view of efficiently obtaining the information required in the probing, both in theory and by experimental implementation. The experiment serves also as evidence for applicability of recently developed geometric tools to design informationally incomplete measurements for solving so-called membership problems. We present and experimentally realize a protocol where control over intial correlations between polarization and frequency gives full freedom to implement any dephasing dynamics in the open system polarization, thus dictating how its information content changes in time. We study the two-qubit memory effects of dephasing dynamics and compare them to the effect of such noise in the transmission efficiency in superdense coding. Optimal noise configurations in different situations are found. Finally, we characterize the families of initial states for which the decay of quantum correlations depends or does not depend on the noise location.

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Theoretical investigations of open quantum systems have uncovered a wide variety of unique dynamical phenomena. For instance, current research in quantum information technology aims to control and utilize time-delayed system-reservoir interactions and phonon-induced dynamical dissipative processes for the design of novel chip-integrated quantum optical devices. This thesis develops and advances multiple theoretical approaches for the accurate and efficient description of open quantum systems, where a high degree of information compression is essential to extract crucial information from the open system degrees of freedom which scale exponentially with the system size. The presented methods range from correlation expansions to second-order perturbative master equations, real-time path integral formulations, numerical realizations of high-dimensional tensor networks and, based on the most recent theoretical developments, machine learning implementations in the form of artificial neural networks. We explore all of these techniques with respect to their compression efficiency, performance and representational limits by applying them to a variety of physical setups and scenarios. Firstly, emerging non-Markovian memory effects in open quantum systems are investigated, e.g., resulting from interactions with a structured phonon environment or time-discrete coherent quantum feedback, leading to information exchange and a time-delayed dynamical interplay between system and reservoir. Examined systems range from solid state p-wave topological superconductors coupled to a structured phonon environment, where a memory-induced stabilization and recovery of topological properties is observed, to semiconductor quantum dot nanostructures exhibiting complete population inversion and unidirectional quantum transport as a result of dissipation-induced non-Markovian system-reservoir interactions, and quantum emitters simultaneously subjected to coherent quantum feedback and a decoherence-inducing structured phonon reservoir, leading to the formation of dynamical dissipative structures and population trapping. Secondly, novel machine learning techniques based on artificial neural networks are investigated, enabling simulations of symmetric open quantum spin-1/2 systems with Markovian dynamics. Combining their potential for parallelization and efficient Hilbert space truncation, they facilitate unmatched degrees of information compression and numerical performance for large systems. In this thesis, we expand the representational limits of the restricted Boltzmann machine neural network architecture by developing novel hybrid sampling strategies for a highly customizable compression of configuration space, rendering accurate and efficient simulations of asymmetric systems feasible. Finally, the applicability of the neural network is extended beyond pure spin-1/2 systems by introducing a neural bit encoding scheme for Fock number states, facilitating high performing calculations of large hybrid open quantum systems with bosonic degrees of freedom.

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This thesis investigates two thematic lines of research, both underpinned by non-Markovian system-reservoir interactions in quantum optics. The overarching focus is on modelling the open system dynamics in a non-perturbative fashion, broadly on - though not restricted to - instances when the environment is structured. A theory is developed by means of enlarging the open system over environmental degrees of freedom to include memory effects in its dynamics. This is achieved using an established technique that involves mapping a bosonic environment onto a 1D chain of harmonic oscillators. Within this setting, we apply a Heisenberg equation-of-motion approach to derive an exact set coupled differential equations for the open system and a single auxiliary oscillator of the chain. The combined equations are shown to have their interpretation rooted in a quantum Markov stochastic process. Including the auxiliary chain oscillator as part of the original system then enables us to obtain an exact master equation for the enlarged system, avoiding any need for the Born-Markov approximations. Our method is valid for a dissipative two-state system, with cases of multiple excitations and added driving discussed. Separately, we apply the framework of quantum Darwinism to an atom-cavity system, and, subsequently, to a more general multiple-environment model. In both cases, the time-dependent spread of correlations between the open system and fractions of the environment is analysed during the course of the decoherence process. The degree to which information is redundant across different fractions is checked to infer the emergence of classicality. In the second case, we go further and present a decomposition of information in terms of its quantum and classical correlations. A quantitative measure of redundancy is also studied with regard to its ability to witness non-Markovian behaviour. Besides fundamental interest, our results have application to quantum information processing and quantum technologies, keeping in mind the potential beneficial use of non-Markovian effects in reservoir engineering.

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The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.

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•Jan 1, 2011•2 citations
This thesis is a collection of works focusing on interrelations between the fields of special relativity, open quantum systems and complex networks. As each of the aforementioned fields encompasses a huge variety of topics, the thesis contains a selection of particular connections. The first half of the thesis considers an open quantum systems approach to the description of relativistic phenomena. As the aforementioned phenomena often involve dynamically evolving counterparts, some non-Markovian aspects of open quantum systems are initially explored. Conditions for complete positivity are derived for a type of phase-covariant time-local master equation and then applied to a non-Markovian master equation with heuristically-derived decay rates. This is relevant in cases when the physicality of the master equation cannot be postulated. The first relativistic system considered is a superposition of coherent states in a gravitational gradient. It is shown to exhibit decoherence induced by gravitational time dilation through interaction between inner degrees of freedom and the centre of mass of the superposition. The decoherence is quantified using various, widely-used non-classicality measures. The decoherence rates are then compared to decoherence induced by classical noise to roughly evaluate the experimental precision necessary to detect gravitationally induced decoherence. In the second relativistic system, the Unruh effect is modeled as an open system where an Unruh-deWitt detector is interacting with bosonic fields. A master equation with time-dependent decay rates for the open system is derived by assuming a non-conventional spacetime path profile for the detector. A particular parameter governing the physical evolution is identified. The system is shown to exhibit non-Markovianity within the completely positive domain of the master equation, the latter ensured by the conditions derived before. The second half of the thesis starts with a definition of complex networks, which are yet not a commonly used tool in quantum physics. The concept of pairwise tomography networks is then introduced as a way to represent many-body quantum states. As the number of pairwise connections grows quadratically with the number of nodes, an efficiently scaling measurement scheme to recover the pairwise tomography networks is presented. The scheme and the concept of pairwise tomography networks are demonstrated to be useful in various applications and the results of a proof-of-principle experiment are shown. One application explored is a paradigmatic spin chain model known as the XX model. A pairwise entanglement network representation of the XX model is shown to suggest new phenomena such as gradual establishment of quasi-long range order accompanied by a symmetry regarding single-spin concurrence distributions. The existence of structural classes and a cyclic self-similarity in the state are revealed.
Quantum mechanics exhibits a broad collection of theoretical results in complete agreement with experimental evidence. Besides showing unquestionable success in the description of isolated systems, it can be also successfully used to characterize non-isolated quantum system. In such a case, phenomena like dissipation, diffusion or decoherence. The theory of open quantum systems provides the framework where such features can be conveniently explained. \nThis thesis is about decoherence and collapse models. Albeit conceptually they are very far from each other, they both belong the framework of open quantum systems. Indeed, they consider systems interacting with an external entity: an environment for decoherence models, a noise for collapse models. Although the external influence has different origin, they can be described by similar dynamical equations and, to confirm or falsify them, the same experimental tests can be performed. \nThe quantum Brownian motion model can be considered the paradigm of decoherence models. We provide an exact and analytic equation for the time evolution of the operators and we show that the corresponding equation for the states is equivalent to well-known results in the literature. Our derivation allows to compute the time evolution of physically relevant quantities in a much easier way than previous formulations. Moreover, we are not bound to compute the time evolution of the state of the system, which in general is a complicated task. The explicit dependence on the initial state appears only in the initial expectation values and not in the dynamics. This makes possible the derivation of expectation values also for nontrivial states. \nAnother decoherence model we considered is a recently proposed model, based on the mass-energy equivalence. The model describes a decoherence source acting universally on every system whose superposition is extended on positions experiencing different gravitational potentials. We studied the conditions under which this mechanism becomes the dominant decoherence effect in typical interferometric experiments. We show that current experiments are off by several orders of magnitude. New ideas are needed to achieve the necessary requirements. \nThe second part of this thesis concerns collapse models, in particular the Continuous Spontaneous Localization (CSL) model. We focus on experimental tests that can probe it. In this respect, experiments can be grouped in two classes: interferometric tests and non-interferometric ones. The first class includes those experiments, which directly create and detect quantum superpositions of the center of mass of massive systems. The strongest bounds on the CSL parameters come from the second class of non-interferometric experiments, which are sensitive to small position displacements and detect CSL-induced diffusion in position. \nWe investigate how we can benefit from the non-interferometric perspective given by optomechanical setups, which have reached high sensitivities as force and position sensors. Three examples are considered.\nFirst, we compute the upper bounds on the CSL parameters, which can be inferred by the gravitational wave detectors LIGO, LISA Pathfinder and AURIGA.\nSecond, we report new results from an experiment based on a high-quality cantilever cooled to millikelvin temperature. High accuracy measurements of the cantilever thermal fluctuations reveal a nonthermal force noise of unknown origin. This excess noise is compatible with the CSL heating predicted by Adler. Several physical mechanisms able to explain the observed noise have been ruled out.\nThird, we propose an unattempted non-interferometric test aimed to investigate the still unexplored region of the CSL parameter space. Our proposal relies on torsional degrees of freedom rather than the usual vibrational ones. We believe that the test that has been put forward here, will eventually probe the unexplored CSL parameter space.
Quantum mechanics has both deepened our understanding of the physical reality and allowed development of quantum technologies beating their classical counterparts in efficiency, security, and sensitivity. As a major downside, the quantum properties behind these technologies are very sensitive to the effects the system’s interaction with its environment. The theory of open quantum systems describes how such interaction influences the system, and as a consequence, how the quantum features are lost, controlled, and possibly returned by manipulating the environment. This thesis begins with a short description of the most relevant features and results of the open quantum system theory. We continue by presenting some commonly used measures to quantify the information encoded in quantum systems and the correlations between spatially or temporally separated parties. The literature review ends with discussion of non-Markovianity and memory effects which combine the fields of open quantum systems and quantum information in a natural way. The rest of the thesis presents the main results of Publications I – VII. We study the memory effects and physicality conditions of open system dynamics described by the vast family of phase-covariant master equations. We show how the open quantum system picture can be exploited to design probing protocols to extract information without knowing how the probe and system interact. Such protocols are considered also from the point-of view of efficiently obtaining the information required in the probing, both in theory and by experimental implementation. The experiment serves also as evidence for applicability of recently developed geometric tools to design informationally incomplete measurements for solving so-called membership problems. We present and experimentally realize a protocol where control over intial correlations between polarization and frequency gives full freedom to implement any dephasing dynamics in the open system polarization, thus dictating how its information content changes in time. We study the two-qubit memory effects of dephasing dynamics and compare them to the effect of such noise in the transmission efficiency in superdense coding. Optimal noise configurations in different situations are found. Finally, we characterize the families of initial states for which the decay of quantum correlations depends or does not depend on the noise location.
Theoretical investigations of open quantum systems have uncovered a wide variety of unique dynamical phenomena. For instance, current research in quantum information technology aims to control and utilize time-delayed system-reservoir interactions and phonon-induced dynamical dissipative processes for the design of novel chip-integrated quantum optical devices. This thesis develops and advances multiple theoretical approaches for the accurate and efficient description of open quantum systems, where a high degree of information compression is essential to extract crucial information from the open system degrees of freedom which scale exponentially with the system size. The presented methods range from correlation expansions to second-order perturbative master equations, real-time path integral formulations, numerical realizations of high-dimensional tensor networks and, based on the most recent theoretical developments, machine learning implementations in the form of artificial neural networks. We explore all of these techniques with respect to their compression efficiency, performance and representational limits by applying them to a variety of physical setups and scenarios. Firstly, emerging non-Markovian memory effects in open quantum systems are investigated, e.g., resulting from interactions with a structured phonon environment or time-discrete coherent quantum feedback, leading to information exchange and a time-delayed dynamical interplay between system and reservoir. Examined systems range from solid state p-wave topological superconductors coupled to a structured phonon environment, where a memory-induced stabilization and recovery of topological properties is observed, to semiconductor quantum dot nanostructures exhibiting complete population inversion and unidirectional quantum transport as a result of dissipation-induced non-Markovian system-reservoir interactions, and quantum emitters simultaneously subjected to coherent quantum feedback and a decoherence-inducing structured phonon reservoir, leading to the formation of dynamical dissipative structures and population trapping. Secondly, novel machine learning techniques based on artificial neural networks are investigated, enabling simulations of symmetric open quantum spin-1/2 systems with Markovian dynamics. Combining their potential for parallelization and efficient Hilbert space truncation, they facilitate unmatched degrees of information compression and numerical performance for large systems. In this thesis, we expand the representational limits of the restricted Boltzmann machine neural network architecture by developing novel hybrid sampling strategies for a highly customizable compression of configuration space, rendering accurate and efficient simulations of asymmetric systems feasible. Finally, the applicability of the neural network is extended beyond pure spin-1/2 systems by introducing a neural bit encoding scheme for Fock number states, facilitating high performing calculations of large hybrid open quantum systems with bosonic degrees of freedom.
This thesis investigates two thematic lines of research, both underpinned by non-Markovian system-reservoir interactions in quantum optics. The overarching focus is on modelling the open system dynamics in a non-perturbative fashion, broadly on - though not restricted to - instances when the environment is structured. A theory is developed by means of enlarging the open system over environmental degrees of freedom to include memory effects in its dynamics. This is achieved using an established technique that involves mapping a bosonic environment onto a 1D chain of harmonic oscillators. Within this setting, we apply a Heisenberg equation-of-motion approach to derive an exact set coupled differential equations for the open system and a single auxiliary oscillator of the chain. The combined equations are shown to have their interpretation rooted in a quantum Markov stochastic process. Including the auxiliary chain oscillator as part of the original system then enables us to obtain an exact master equation for the enlarged system, avoiding any need for the Born-Markov approximations. Our method is valid for a dissipative two-state system, with cases of multiple excitations and added driving discussed. Separately, we apply the framework of quantum Darwinism to an atom-cavity system, and, subsequently, to a more general multiple-environment model. In both cases, the time-dependent spread of correlations between the open system and fractions of the environment is analysed during the course of the decoherence process. The degree to which information is redundant across different fractions is checked to infer the emergence of classicality. In the second case, we go further and present a decomposition of information in terms of its quantum and classical correlations. A quantitative measure of redundancy is also studied with regard to its ability to witness non-Markovian behaviour. Besides fundamental interest, our results have application to quantum information processing and quantum technologies, keeping in mind the potential beneficial use of non-Markovian effects in reservoir engineering.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
In this thesis we shall apply techniques from quantum information theory to the problem of measuring the structure of spacetime or equivalently measuring the gravitational field. In turn we will also look at how acceleration may effect quantum information techniques for processing and transmitting information. Measuring the structure of spacetime is a slight abuse of terminology as spacetime structure is not directly observable. We will be investigating the estimation of spacetime structure by making measurements on quantum systems which depend on the spacetime background. The structure of spacetime and the gravitational field will be treated in accordance with Einstein's general theory of relativity. This is currently the most accurately tested classical theory for gravity. It is widely believed that fundamentally, gravity should be treated within the framework of quantum mechanics, just like the other forces of nature. This is yet to be seen experimentally and a theory capable of falsifiable predictions is yet to be found. In this thesis we shall focus on the effects of gravity at the classical level, however we shall treat matter and non-gravitational energy using quantum mechanics. When looking at how gravity effects quantum information we will specifically be focusing on the simple case of acceleration, yet we shall treat it in this relativistic spacetime context. Knowing the structure of spacetime in general relativity amounts to knowing an object called the metric tensor. This object contains all the information about a spacetime. This may include local curvature, for instance around a star or black hole, gravitational radiation coming from a binary pulsar and even the large scale structure of the universe such as the rate of expansion. By performing local experiments one may attempt to extract this information. Fundamentally these experiments will be governed by quantum mechanics, hence the accuracy of the estimation will be fundamentally limited by the statistical nature of quantum theory. In this thesis we shall develop an equation which states just what accuracy one can ultimately achieve when attempting to measure the structure of spacetime. This equation will be shown to be a generalisation of known results for the accuracy to which one can ultimately measure position and momentum as well as time and energy. The result will be applied to a range of relativistic phenomena including acceleration in flat spacetime, the local curvature around a black hole, the amplitude of a gravitational wave and the expansion of the universe in a cosmological model. Following the use of quantum information theory to investigate gravity we shall look at how acceleration can effect quantum information. Firstly we shall see how quantum entanglement can be created and stored between two optical cavities when one is uniformly accelerating. This is in contrast to a number of results which predict that entanglement will be lost in the presence of acceleration. This loss of entanglement is predicted due to an as yet unobserved phenomena known as the Unruh effect. The Unruh effect states that an observer uniformly accelerating will see a thermal distribution of particles even if an inertial observer will see no particles at all. We will show how the use of optical cavities can prevent this effect from causing problems both for the storage and creation of entanglement. Finally we shall look at how a particular quantum detection scheme can be employed in the presence of acceleration. Our technique will emphasis the importance of locality, that is the localisation of physics in spacetime. We will also show how some commonly used approximations used to study the Unruh effect, can be avoided with our new formulation.