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Effective descriptions of complex quantum systems: path integrals and operator ordering problems

Ulrich Eckern, Michael J. Gruber, Peter Schwab

Published Jan 1, 2005• 1 citation
OpenAlex

Abstract

We study certain aspects of the effective, occasionally called collective, description of complex quantum systems within the framework of the path integral formalism, in which the environment is integrated out. Generalising the standard Feynman-Vernon Caldeira-Leggett model to include a non-linear coupling between “particle ” and environment, and considering a particular spectral density of the coupling, a coordinatedependent mass (or velocity-dependent potential) is obtained. The related effective quantum theory, which depends on the proper discretisation of the path integral, is derived and discussed. As a result, we find that in general a simple effective low-energy Hamiltonian, in which only the coordinate-dependent mass enters, cannot be formulated. The quantum theory of weakly coupled superconductors and the quantum dynamics of vortices in Josephson junction arrays are physical examples where these considerations, in principle, are of relevance. 1

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We study certain aspects of the effective, occasionally called collective, description of complex quantum systems within the framework of the path integral formalism, in which the environment is integrated out. Generalising the standard Feynman-Vernon Caldeira-Leggett model to include a non-linear coupling between “particle ” and environment, and considering a particular spectral density of the coupling, a coordinatedependent mass (or velocity-dependent potential) is obtained. The related effective quantum theory, which depends on the proper discretisation of the path integral, is derived and discussed. As a result, we find that in general a simple effective low-energy Hamiltonian, in which only the coordinate-dependent mass enters, cannot be formulated. The quantum theory of weakly coupled superconductors and the quantum dynamics of vortices in Josephson junction arrays are physical examples where these considerations, in principle, are of relevance. 1
This chapter constructs path integrals for general Hamiltonians with potentials linear in the velocities, like Hamiltonians of particles in a magnetic field. Two examples are considered: a quantum system coupled to a magnetic field, and diffusion as described by the Fokker-Planck equation. In both examples, the Hamiltonian contains products of the position and momentum operators. A quantization problem then arises since these operators do not commute, and the correspondence principle is no longer sufficient to determine the quantum Hamiltonian. The order between quantum operators is determined by additional conditions, such as hermiticity or conservation of probabilities. The calculation of the corresponding path integral then suffers from ambiguities, directly related to this quantization problem. The continuum limit is no longer unique, but depends on the limiting process. This chapter also considers a situation where space has a nontrivial topology, in this case a circle, and shows how this influences the calculation of the path integral.
We study certain aspects of the effective, occasionally called collective, description of complex quantum systems within the framework of the path integral formalism, in which the environment is integrated out. Generalising the standard Feynman-Vernon Caldeira-Leggett model to include a non-linear coupling between ``particle'' and environment, and considering a particular spectral density of the coupling, a coordinate-dependent mass (or velocity-dependent potential) is obtained. The related effective quantum theory, which depends on the proper discretisation of the path integral, is derived and discussed. As a result, we find that in general a simple effective low-energy Hamiltonian, in which only the coordinate-dependent mass enters, cannot be formulated. The quantum theory of weakly coupled superconductors and the quantum dynamics of vortices in Josephson junction arrays are physical examples where these considerations, in principle, are of relevance.
In many situations, one can approximate the behavior of a quantum system, i.e. a wave function subject to a partial differential equation, by effective classical equations which are ordinary differential equations. A general method and geometrical picture are developed and shown to agree with effective action results, commonly derived through path integration, for perturbations around a harmonic oscillator ground state. The same methods are used to describe dynamical coherent states, which in turn provide means to compute quantum corrections to the symplectic structure of an effective system.
Abstract Dedicated to Bernhard Mühlschlegel on the occasion of his 80th birthday We study certain aspects of the effective, occasionally called collective, description of complex quantum systems within the framework of the path integral formalism, in which the environment is integrated out. Generalising the standard Feynman‐Vernon Caldeira‐Leggett model to include a non‐linear coupling between “particle” and environment, and considering a particular spectral density of the coupling, a coordinate‐dependent mass (or velocity‐dependent potential) is obtained. The related effective quantum theory, which depends on the proper discretisation of the path integral, is derived and discussed. As a result, we find that in general a simple effective low‐energy Hamiltonian, in which only the coordinate‐dependent mass enters, cannot be formulated. The quantum theory of weakly coupled superconductors and the quantum dynamics of vortices in Josephson junction arrays are physical examples where these considerations, in principle, are of relevance.
In many situations, one can approximate the behavior of a quantum system, i.e. a wave function subject to a partial differential equation, by effective classical equations which are ordinary differential equations. A general method and geometrical picture is developed and shown to agree with effective action results, commonly derived through path integration, for perturbations around a harmonic oscillator ground state. The same methods are used to describe dynamical coherent states, which in turn provide means to compute quantum corrections to the symplectic structure of an effective system.
In this thesis the path integral formalism is applied to the calculation of the dynamics of dissipative quantum systems. The time evolution of a system of bilinearly coupled bosonic modes is treated using the real-time path integral technique in coherent-state representation. This method is applied to a damped harmonic oscillator within the Caldeira-Leggett model. In order to get the stationary trajectories the corresponding Lagrangian function is diagonalized and then the path integrals are evaluated by means of the stationary-phase method. The time evolution of the reduced density matrix in the basis of coherent states is given in simple analytic form for weak system-bath coupling, i.e. the so-called rotating-wave terms can be evaluated exactly but the non-rotating-wave terms only in a perturbative manner. The validity range of the rotating-wave approximation is discussed from the viewpoint of spectral equations. In addition, it is shown that systems without initial system-bath correlations can exhibit initial jumps in the population dynamics even for rather weak dissipation. Only with initial correlations the classical trajectories for the system coordinate can be recovered. The path integral formalism in a combined phase-space and coherent-state representation is applied to the problem of curve-crossing dynamics. The system of interest is described by two coupled one-dimensional harmonic potential energy surfaces interacting with a heat bath. The mapping approach is used to rewrite the Lagrangian function of the electronic part of the system. Using the Feynman-Vernon influence-functional method the bath is eliminated whereas the non-Gaussian part of the path integral is treated using the perturbation theory in the small coordinate shift between potential energy surfaces. The vibrational and the population dynamics is considered in a lowest order of the perturbation. The dynamics of a Gaussian wave packet is analyzed along a one-dimensional reaction coordinate. Also the damping rate of coherence in the electronic part of the relevant system is evaluated within the ordinary and variational perturbation theory. The analytic expressions for the rate functions are obtained in the low and high temperature regimes.