Quantum probes are atomic-sized devices mapping information of their environment to quantum mechanical states. By improving measurements and at the same time minimizing perturbation of the environment, they form a central asset for quantum technologies. We realize spin-based quantum probes by immersing individual Cs atoms into an ultracold Rb bath. Controlling inelastic spin-exchange processes between probe and bath allows mapping motional and thermal information onto quantum-spin states. We show that the steady-state spin-population is well suited for absolute thermometry, reducing temperature measurements to detection of quantum spin distributions. Moreover, we find that the information gain per inelastic collision can be maximized by accessing the nonequilibrium spin dynamic. The sensitivity of nonequilibrium quantum probing effectively beats the steady-state Cramér Rao limit of quantum probing by almost an order of magnitude, while reducing the perturbation of the bath to only three quanta of angular momentum. Our work paves the way for local probing of quantum systems at the Heisenberg limit, and moreover for optimizing measurement strategies via control of nonequilibrium dynamics.
We study the sensitivity of a collisional single-atom probe for ultracold gases. Inelastic spin-exchange collisions map information about the gas temperature T or external magnetic field B onto the quantum spin-population of single-atom probes, and previous work showed enhanced sensitivity for short-time nonequilibrium spin dynamics [Phys. Rev. X 10, 011018 (2020)]. Here, we numerically investigate the steady-state sensitivity of such single-atom probes to various observables. We find that the probe shows distinct sensitivity maxima in the (B,T) parameter diagram, although the underlying spin-exchange rates scale monotonically with temperature and magnetic field. In parameter space, the probe generally has the largest sensitivity when sensing the energy ratio between thermal energy and Zeeman energy in an externally applied magnetic field, while the sensitivity to the absolute energy, i.e., the sum of kinetic and Zeeman energy, is low. We identify the parameters yielding sensitivity maxima for a given absolute energy, which we can relate to a direct comparison of the thermal Maxwell-Boltzmann distribution with the Zeeman-energy splitting. We compare our equilibrium results to nonequilibrium experimental results from a single-atom quantum probe, showing that the sensitivity maxima in parameter space qualitatively prevail also in the nonequilibrium dynamics, while a quantitative difference remains. Our work thereby offers a microscopic explanation for the properties and performance of this single-atom quantum probe, connecting thermodynamic properties to microscopic interaction mechanisms. Our results pave the way for optimization of quantum-probe applications in (B,T) parameter space beyond the previously shown boost by nonequilibrium dynamics.
We employ collisions of individual atomic cesium (Cs) impurities with an ultracold rubidium (Rb) gas to probe atomic interaction with hyperfine- and Zeeman-state sensitivity. Controlling the Rb bath's internal state yields access to novel phenomena observed in interatomic spin exchange. These can be tailored at ultralow energies, owing to the excellent experimental control over all relevant energy scales. First, detecting spin-exchange dynamics in the Cs hyperfine-state manifold, we resolve a series of previously unreported Feshbach resonances at magnetic fields below 300 mG, separated by energies as low as h×15 kHz. The series originates from a coupling to molecular states with binding energies below h×1 kHz and wave function extensions in the micrometer range. Second, at magnetic fields below ≈100 mG, we observe the emergence of a new reaction path for alkali atoms, where in a single, direct collision between two atoms two quanta of angular momentum can be transferred. This path originates from the hyperfine analog of dipolar spin-spin relaxation. Our work yields control of subtle ultralow-energy features of atomic collision dynamics, opening new routes for advanced state-to-state chemistry, for controlling spin exchange in quantum many-body systems for solid-state simulations, or for determination of high-precision molecular potentials.
Measuring the temperature of a quantum system is an essential task in almost all aspects of quantum technologies. Theoretically, an optimal strategy for thermometry often requires measuring energy, which demands full accessibility over the entire system as well as a complex entangled measurement basis. In this paper, we take a different approach and show that single-qubit sequential measurements in the computational basis not only allow for precise thermometry of a many-body system, but may also achieve precision beyond the thermometry capacity of the probe at equilibrium, given by the Cram\'er-Rao bound. Thus, using consecutive single-qubit measurements of the probe out of equilibrium is, in most cases, very beneficial, as it achieves lower-temperature uncertainties and avoids demanding energy measurements when compared with probes at thermal equilibrium. To obtain such precision, the time between the two subsequent measurements should be smaller than the thermalization time so that the probe never thermalizes. Therefore, the nonequilibrium dynamics of the system continuously imprint information about temperature in the state of the probe. To demonstrate the generality of our findings, we consider thermometry in both spin chains and the Jaynes-Cummings model.
Accurate temperature estimation in the quantum and cryogenic regimes remains a fundamental challenge. Here, we investigate nonequilibrium quantum thermometry using a single-qubit probe coupled to a bosonic bath through noncommuting interaction operators, which unify pure dephasing and dissipative dynamics within a spin-boson model. We show that the interference between these two coupling channels induces strong non-Markovian feedback between populations and coherences, leading to coherence trapping and enhanced thermal sensitivity. Remarkably, by tuning the coupling structure, the probe's temperature sensitivity exhibits a quadratic low-temperature scaling, even under weak coupling. Moreover, while coherence-based measurements are formally suboptimal, they become the most informative in the early nonequilibrium regime, where memory effects dominate. Our findings identify noncommutative system-bath couplings as a practical and tunable resource for achieving high-precision quantum thermometry in realistic open-system architectures.
We report on spin dynamics of individual, localized neutral impurities immersed in a Bose-Einstein condensate. Single cesium atoms are transported into a cloud of rubidium atoms and thermalize with the bath, and the ensuing spin exchange between localized impurities with quasispin F_{i}=3 and bath atoms with F_{b}=1 is resolved. Comparing our data to numerical simulations of spin dynamics, we find that, for gas densities in the Bose-Einstein condensate regime, the dynamics is dominated by the condensed fraction of the cloud. We spatially resolve the density overlap of impurities and gas by the spin population of impurities. Finally, we trace the coherence of impurities prepared in a coherent superposition of internal states when coupled to a gas of different densities. For our choice of states, we show that, despite high bath densities and, thus, fast thermalization rates, the impurity coherence is not affected by the bath, realizing a regime of sympathetic cooling while maintaining internal state coherence. Our work paves the way toward the nondestructive probing of quantum many-body systems via localized impurities.