Special relativity is a fascinating and challenging branch of physics. It describes the physics of the high velocity/high energy regime, frequently turning up phenomena that appear paradoxical in view of our everyday experience. In this book we will be quite selective in our presentation of the theory of special relativity: we will concentrate on those features that we consider necessary for the later applications to relativistic quantum chemistry. We do this in good conscience, knowing that there is a vast literature on the subject, catering to a wide range of audiences—from the quite elementary to the very sophisticated. A few examples are listed in the reference list, but a visit to any nearby physics library will provide an ample selection of reading material for those wishing to delve deeper into the matter. In the present chapter we adopt a minimalist approach. We develop some of the basic concepts and formulas of special relativity, building on a rather elementary level of basic physics. The aim is to provide a sufficient foundation for those who want to proceed as quickly as possible to the more quantum chemical parts of the text. In later chapters we will introduce more advanced tools of physics and revisit some of the subjects treated here. The theory of special relativity deals with the description of physical phenomena in frames that move at constant velocity relative to each other. The classroom is one such frame, the car passing at constant speed outside the classroom is another. The trajectory of a ball being thrown up vertically in the car will look quite different whether we describe it relative to the interior of the car or relative to the interior of the classroom. In particular we will be concerned with inertial frames. We define an inertial frame as a frame where spatial relations are Euclidean and where there is a universal time such that free particles move with constant velocities. In classical Newtonian mechanics, relations between the spatial parameters and time in two inertial frames S and S’ are expressed in terms of the Galilean transformations.
Special relativity is a fascinating and challenging branch of physics. It describes the physics of the high velocity/high energy regime, frequently turning up phenomena that appear paradoxical in view of our everyday experience. In this book we will be quite selective in our presentation of the theory of special relativity: we will concentrate on those features that we consider necessary for the later applications to relativistic quantum chemistry. We do this in good conscience, knowing that there is a vast literature on the subject, catering to a wide range of audiences—from the quite elementary to the very sophisticated. A few examples are listed in the reference list, but a visit to any nearby physics library will provide an ample selection of reading material for those wishing to delve deeper into the matter. In the present chapter we adopt a minimalist approach. We develop some of the basic concepts and formulas of special relativity, building on a rather elementary level of basic physics. The aim is to provide a sufficient foundation for those who want to proceed as quickly as possible to the more quantum chemical parts of the text. In later chapters we will introduce more advanced tools of physics and revisit some of the subjects treated here. The theory of special relativity deals with the description of physical phenomena in frames that move at constant velocity relative to each other. The classroom is one such frame, the car passing at constant speed outside the classroom is another. The trajectory of a ball being thrown up vertically in the car will look quite different whether we describe it relative to the interior of the car or relative to the interior of the classroom. In particular we will be concerned with inertial frames. We define an inertial frame as a frame where spatial relations are Euclidean and where there is a universal time such that free particles move with constant velocities. In classical Newtonian mechanics, relations between the spatial parameters and time in two inertial frames S and S’ are expressed in terms of the Galilean transformations.
Abstract In the opening chapter on relativity, C. V. Vishveshwara (Vishu) takes the reader through an excursion on how Einstein laid down the remarkable foundations of special relativity. The chapter begins with an early treatment of relativity, namely Galilean relativity, which while successful with classical mechanics was not tenable with electromagnetism. Working in the seclusion of a patent office, Einstein thought deeply and despairingly of relativity that would encompass electromagnetism. He realized that not only spatial measures but also time varied among inertial observers moving with constant relative velocities. Thus, Einstein’s special theory of relativity came to be, and along with it, his celebrated equation, E = mc2. The chapter then surveys bizarre, observable consequences of this special relativity and how they all beautifully fit into a mathematical framework created by Minkowski in which space and time become united. The chapter concludes by describing physicists’ reactions to this radical new theory and its role in different areas, such as elementary particle physics and astrophysics. In the opening chapter of quantum physics, Smitha describes the circuitous historic path taken by many a physicist explorer that led to the establishment of its mind-boggling fundamentals. This revolutionary branch of physics was seeded by puzzles posed in the late 1800s related to the behavior of light from radiating objects. The chapter begins by exploring the nature of light and the story of blackbody radiation that led to Planck introducing the notion of the quantum. It then surveys the photoelectric effect, which heralds the concept of the photon, and wave-particle duality, which applies both to light and matter. The excursion continues into Schrödinger’s description of matter acting as a wave and its consequences, including energy quantization and quantum tunneling. The chapter then explains Heisenberg’s uncertainty principle from multiple angles. Finally, it presents the quantum picture of the atom and how it resolved some of the deep puzzles, a crowning testament to quantum theory.
Classical mechanics of a free particle is based on Newtonian mechanics and Lagrangian/Hamilton theories. A single frame of reference is chosen (the lab) and particles with the same mass mo (for example) moving at different velocities are considered in the free particle scenario (i.e in the absence of force (potentials)). We argue that the above is identical to considering a single particle with mass mo at time=to and x=0 viewed by various frames moving at different constant velocities -v. From the point of view of each frame, the particle moves at a velocity v. Thus the Newtonian picture of an mo particle moving at different speeds may be considered as a problem of special relativity. We argue (as in (1)) that (x,t)=(0,t) transforms to (x’,t’) such that x’/t’=v. If one uses a metric (1 0) (first row) (0 -1) second row, one may derive special relativistic relationships. In particular, one may obtain the Lorentz invariant -Et + px if (p,E) and (x,t) transform in the same manner. We argue that the relationships obtained from special relativity pertain to classical mechanics and so one may mathematically obtain a function L(v) such that p=dL/dv and E=pv - L for a free particle. In other words, special relativity governs Lagrangian results in the free particle case and is not really needed (in this special case). More importantly, it is special relativity which links E with t and p with x. As noted above, if one considers Netwonian mechanics in a single frame, the notion of special relativity does not arise, but the scaling of time by E and of x by p does i.e. A= -Et+px is the classical action both relativistically and nonrelativistically. It is just not written in this way usually (i.e. A = -mo t sqrt(1-vv) (c=1) relatiivstically and A =t .5mo vv nonrelativistically) We argued in (2) that scaling must manifest itself physically and that it accounts for the physical wavelength in quantum mechanics. We argue that the quantum mechanics of a free particle ultimately follows from special relativity. As a result, ideas of quantum mechanics would not have appeared in Newtonian mechanics nor Lagrangian or Hamiltonian theories. When special relativity was developed it focused on transformations related to different frames, but these are equivalent to describing one frame with many different velocities (same mo). Thus the physics in one frame is governed by special relativity even if it is nonrelativistic. We argue that the notion of the wavelength which appears even in the Schrodinger formalism follows from scaling of x by p which ultimately originates from special relativity. In other words, both the Lagrangian formalism and quantum mechanics follow from special relativity in the free particle case. We argue that free particle quantum mechanics is the starting point of overall quantum mechanics.
In this second chapter we will review the basic mathematical and physical facts about quantum mechanics and establish physical units and notation. Those readers already familiar with the subject can safely jump to the next chapter. An attempt has been made to make the presentation in this chapter as elementary as possible, and yet present the basic facts that will be needed later. There are many beautiful and important topics which will not be touched upon such as self-adjointness of Schrödinger operators, the general mathematical structure of quantum mechanics and the like. These topics are well described in other works, e.g.. Much of the following can be done in a Euclidean space of arbitrary dimension, but in this chapter the dimension of the Euclidean space is taken to be three-which is the physical case-unless otherwise stated. We do this to avoid confusion and, occasionally, complications that arise in the computation of mathematical constants. The interested reader can easily generalize what is done here to the R d , d > 3 case. Likewise, in the next chapters we mostly consider N particles, with spatial coordinates in R 3 , so that the total spatial dimension is 3 N . A Brief Review of the Connection Between Classical and Quantum Mechanics Considering the range of validity of quantum mechanics, it is not surprising that its formulation is more complicated and abstract than classical mechanics. Nevertheless, classical mechanics is a basic ingredient for quantum mechanics. One still talks about position, momentum and energy which are notions from Newtonian mechanics.
Relativistic quantum mechanics is the unification into a consistent theory of Einstein's theory of relativity and the quantum mechanics of physicists such as Bohr, Schrödinger, and Heisenberg. Evidently, to appreciate relativistic quantum theory it is necessary to have a good understanding of these component theories. Apart from this chapter we assume the reader has this understanding. However, here we are going to recall some of the important points of the classical theory of special relativity. There is good reason for doing this. As you will discover all too soon, relativistic quantum mechanics is a very mathematical subject and my experience has been that the complexity of the mathematics often obscures the physics being described. To facilitate the interpretation of the mathematics here, appropriate limits are taken wherever possible, to obtain expressions with which the reader should be familiar. Clearly, when this is done it is useful to have the limiting expressions handy. Presenting them in this chapter means they can be referred to easily. Taking the above argument to its logical conclusion means we should include a chapter on non-relativistic quantum mechanics as well. However, that is too vast a subject to include in a single chapter. Furthermore, there already exists a plethora of good books on the subject.
Up to this point, our study of quantum mechanics has concerned itself with the behaviour of particles that inhabit a Galilean spacetime. For many purposes, in atomic, molecular and condensed matter physics, this theory is quite adequate. We saw in earlier chapters, however, that our actual spacetime has a structure which is much closer to that of the Minkowski spacetime of special relativity and that more general structures must be considered when gravitational phenomena are signicant. From a purely theoretical point of view, it is therefore important to formulate quantum theory in a way which is consistent with these more general spacetimes. The benets of constructing a relativistic quantum theory actually go far beyond the aesthetic satisfaction of making our geometrical and quantum-mechanical reasoning compatible. For one thing, we shall discover that the relativistic theory provides a deeper understanding of spin and the distinction between fermions and bosons, which in the non-relativistic theory appear simply as facts of life that we must strive to accommodate. Also, of course, there are many situations in which relativistic eects become observable, for which non-relativistic theory provides no explanation. The most obvious are high-energy scattering experiments, in which particles acquire kinetic energies comparable with or greater than their rest energies mc2, and the correct 4-momentum (3.33) must be used. There are, however, more subtle eects, such as the spin-orbit coupling that is essential for interpreting atomic spectra, which are also of relativistic origin.
Up to this point, our study of quantum mechanics has concerned itself with the behaviour of particles that inhabit a Galilean spacetime. For many purposes, in atomic, molecular and condensed matter physics, this theory is quite adequate. We saw in earlier chapters, however, that our actual spacetime has a structure which is much closer to that of the Minkowski spacetime of special relativity and that more general structures must be considered when gravitational phenomena are significant. From a purely theoretical point of view, it is therefore important to formulate quantum theory in a way which is consistent with these more general spacetimes. The benefits of constructing a relativistic quantum theory actually go far beyond the aesthetic satisfaction of making our geometrical and quantummechanical reasoning compatible. For one thing, we shall discover that the relativistic theory provides a deeper understanding of spin and the distinction between fermions and bosons, which in the non-relativistic theory appear simply as facts of life that we must strive to accommodate. Also, of course, there are many situations in which relativistic effects become observable, for which nonrelativistic theory provides no explanation. The most obvious are high-energy scattering experiments, in which particles acquire kinetic energies comparable with or greater than their rest energies mc2, and the correct 4-momentum (3.34) must be used. There are, however, more subtle effects, such as the spin-orbit coupling that is essential for interpreting atomic spectra, which are also of relativistic origin.