In classical thermodynamic processes the unavoidable presence of irreversibility, quantified by the entropy production, carries two energetic footprints: the reduction of extractable work from the optimal, reversible case, and the generation of a surplus of heat that is irreversibly dissipated to the environment. Recently it has been shown that in the quantum regime an additional quantum irreversibility occurs that is linked to decoherence into the energy basis. Here we employ quantum trajectories to construct distributions for classical heat and quantum heat exchanges, and show that the heat footprint of quantum irreversibility differs markedly from the classical case. We also quantify how quantum irreversibility reduces the amount of work that can be extracted from a state with coherences. Our results show that decoherence leads to both entropic and energetic footprints which both play an important role in the optimization of controlled quantum operations at low temperature. In classical thermodynamics irreversibility occurs whenever a non-thermal system is brought into contact with a thermal environment. Using quantum trajectories the authors here establish two energetic footprints of quantum irreversible processes, and find that while quantum irreversibility leads to the occurrence of a quantum heat and a reduction of work production, the two are not linked in the same manner as the classical laws of thermodynamics would dictate.
In classical thermodynamic processes the unavoidable presence of irreversibility, quantified by the entropy production, carries two energetic footprints: the reduction of extractable work from the optimal, reversible case, and the generation of a surplus of heat that is irreversibly dissipated to the environment. Recently it has been shown that in the quantum regime an additional quantum irreversibility occurs that is linked to decoherence into the energy basis. Here we employ quantum trajectories to construct distributions for classical heat and quantum heat exchanges, and show that the heat footprint of quantum irreversibility differs markedly from the classical case. We also quantify how quantum irreversibility reduces the amount of work that can be extracted from a state with coherences. Our results show that decoherence leads to both entropic and energetic footprints which both play an important role in the optimization of controlled quantum operations at low temperature. In classical thermodynamics irreversibility occurs whenever a non-thermal system is brought into contact with a thermal environment. Using quantum trajectories the authors here establish two energetic footprints of quantum irreversible processes, and find that while quantum irreversibility leads to the occurrence of a quantum heat and a reduction of work production, the two are not linked in the same manner as the classical laws of thermodynamics would dictate.
Abstract In classical thermodynamic processes the unavoidable presence of irreversibility, quantified by the entropy production, carries two energetic footprints: the reduction of extractable work from the optimal, reversible case, and the generation of a surplus of heat that is irreversibly dissipated to the environment. Recently it has been shown that in the quantum regime an additional quantum irreversibility occurs that is linked to decoherence into the energy basis. Here we employ quantum trajectories to construct distributions for classical heat and quantum heat exchanges, and show that the heat footprint of quantum irreversibility differs markedly from the classical case. We also quantify how quantum irreversibility reduces the amount of work that can be extracted from a state with coherences. Our results show that decoherence leads to both entropic and energetic footprints which both play an important role in the optimization of controlled quantum operations at low temperature.
It is a central question in quantum thermodynamics to determine how irreversible is a process that transforms an initial state $\ensuremath{\rho}$ to a final state $\ensuremath{\sigma}$ and whether such irreversibility can be thought of as a useful resource. For example, we might ask how much work can be obtained by thermalizing $\ensuremath{\rho}$ to a thermal state $\ensuremath{\sigma}$ at temperature T of an ambient heat bath. Here, we show that, for different sets of resource-theoretic thermodynamic operations, the amount of entropy produced along a transition is characterized by how reversible the process is. More specifically, this entropy production depends on how well we can return the state $\ensuremath{\sigma}$ to its original form $\ensuremath{\rho}$ without investing any work. At the same time, the entropy production can be linked to the work that can be extracted along a given transition and we explore the consequences that this fact has for our results. We also exhibit an explicit reversal operation in terms of the Petz recovery channel coming from quantum information theory. Our result establishes a quantitative link between the reversibility of thermodynamical processes and the corresponding work gain.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
Abstract Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. This allows us to identify a genuine quantum contribution to the entropy production in non-equilibrium quantum processes. We discuss how these features emerge both in Lindblad-Davies differential maps and finite maps subject to the constraints of thermal operations. We also show how this separation naturally leads to two independent entropic conservation laws for the global system-environment dynamics, one referring to the redistribution of populations between system and environment and the other describing how the coherence initially present in the system is distributed into local coherences in the environment and non-local coherences in the system-environment state. Finally, we discuss how the processing of quantum coherences and the incompatibility of non-commuting measurements leads to fundamental limitations in the description of quantum trajectories and fluctuation theorems.
The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two contributions: a classical one and a quantum one. Here we show that for degenerate (or near-degenerate) quantum systems there are additional quantum contributions which, remarkably, can become negative. Furthermore, such negative contributions are related to significant changes in the ongoing thermodynamics. This includes phenomena such as generation of coherences between degenerate energy levels (called horizontal coherences), alteration of energy exchanges, and, last but not least, reversal of the natural convergence of the populations toward the thermal equilibrium state. Going further, we establish a complementarity relation between horizontal coherences and population convergence, which is particularly enlightening for understanding heat flow reversals. Conservation laws of the different types of coherences are derived. Some consequences for thermal machines and resource theory of coherence are suggested.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.