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Einstein's fluctuation formula. A historical overview

Varro, S

Published Nov 2, 2006• 10 citations
OpenAlex

Abstract

A historical overview is given on the basic results which appeared by the year 1926 concerning Einstein's fluctuation formula of black-body radiation, in the context of light-quanta and wave-particle duality. On the basis of the original publications (from Planck's derivation of the black-body spectrum and Einstein's introduction of the photons up to the results of Born, Heisenberg and Jordan on the quantization of a continuum) a comparative study is presented on the first line of thoughts that led to the concept of quanta. The nature of the particle-like fluctuations and the wave-like fluctuations are analysed by using several approaches. With the help of the classical probability theory, it is shown that the infinite divisibility of the Bose distribution leads to the new concept of classical poissonian photo-multiplets or to the binary photo-multiplets of fermionic character. As an application, Einstein's fluctuation formula is derived as a sum of fermion type fluctuations of the binary photo-multiplets.

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A historical overview is given on the basic results which appeared by the year 1926 concerning Einstein's fluctuation formula of black-body radiation, in the context of light-quanta and wave-particle duality. On the basis of the original publications (from Planck's derivation of the black-body spectrum and Einstein's introduction of the photons up to the results of Born, Heisenberg and Jordan on the quantization of a continuum) a comparative study is presented on the first line of thoughts that led to the concept of quanta. The nature of the particle-like fluctuations and the wave-like fluctuations are analysed by using several approaches. With the help of the classical probability theory, it is shown that the infinite divisibility of the Bose distribution leads to the new concept of classical poissonian photo-multiplets or to the binary photo-multiplets of fermionic character. As an application, Einstein's fluctuation formula is derived as a sum of fermion type fluctuations of the binary photo-multiplets.
A historical overview is given on the basic results which appeared by the year 1926 concerning Einstein's fluctuation formula of black-body radiation, in the context of light-quanta and wave-particle duality. On the basis of the original publications – from Planck's derivation of the black-body spectrum and Einstein's introduction of the photons up to the results of Born, Heisenberg and Jordan on the quantization of a continuum – a comparative study is presented on the first lines of thoughts that led to the concept of quanta. The nature of the particle-like fluctuations and the wave-like fluctuations are analysed by using several approaches. With the help of classical probability theory, it is shown that the infinite divisibility of the Bose distribution leads to the new concept of classical "poissonian photo-multiplets" or to the "binary photo-multiplets" of fermionic character. As an application, Einstein's fluctuation formula is derived as a sum of fermion type fluctuations of the binary photo-multiplets.
Abstract With the failure of classical physics to explain the experimentally observed black body radiation spectrum, the photoelectric effect and the existence of narrow spectral lines in the light emitted by excited atoms, physicists were forced to reach out for new ideas. Following Planck’s initial “drastic hypothesis” of light “quanta”, Einstein led the way in exploring some of the myriad implications of this idea. In particular, the study of fluctuations led to a new understanding of the interaction of electromagnetic radiation with atoms. Einstein invented the photon by showing, through fluctuation studies, that light emitted by atoms must be in the form of plane waves. These ideas led to the first notions regarding the quantization of matter and its dynamics.
Abstract This chapter covers De Broglie’s extension to matter of wave–particle duality, which Einstein had introduced for radiation. It fills in the background in the tradition of extremal principles in classical physics that De Broglie drew on to formulate his theory. It then covers Bose’s introduction of a new statistics for light quanta and Einstein’s application of those statistics to matter in his quantum theory of the ideal gas. Providing support for De Broglie’s ideas, Einstein derived a formula for energy fluctuations in such a gas that has the exact same form as the formula for energy fluctuations in black-body radiations: it is the sum of two terms, one suggesting waves, the other one suggesting particles.
Einstein's papers on quantum theory over the period 1905-1925 are reviewed. These papers played a fundamental role in the development of quantum concepts. This review traces the relationship between these papers, on the one hand, and Wien's and Planck's theoretical work on thermal radiation and Einstein's own work on statistical thermodynamics, on the other. Einstein's 1905 development of the concept of light quanta from Wien's radiation law, the application of this concept to elementary interactions of radiation with matter, Einstein's 1906–1907 analysis of the Planck radiation law, and Einstein's development of the foundations of a quantum theory of specific heat are all discussed. Particular attention is paid to Einstein's 1909 development of the concept of a particle-wave duality for radiation from a study of the energy and momentum fluctuations in a radiation field. Einstein's 1916 papers on the quantum theory of radiation are analyzed, and it is emphasized that Einstein was the first to suggest a probabilistic interpretation of the particle-wave duality, in addition to introducing coefficients to characterize the probabilities for optical transitions and offering his well-known derivation of the Planck radiation law. There is a special discussion of Einstein's expression, in his 1925 paper on the quantum theory of monatomic ideal gases, of high regard for de Broglie's concept of a particle-wave duality for material particles.
Einstein never deviated from his belief in the reality of light quanta. In 1909, he published a remarkable paper in which he showed that fluctuations in the intensity of black-body radiation consisted of the statistical sum of the wave and particle properties of light. Following the 1911 Solvay conference, most of the participants were converted to the existence of light quanta. Bohr first applied the concepts of quanta to the structure of atoms. The experiment which finally convinced everyone of the light quantum hypothesis was Compton's demonstration of the energy change of X-rays in their scattering by electrons. This resulted in the concept of the wave-particle duality of light, one of the major foundation stones of quantum mechanics.
Planck, Einstein and Bose all had to introduce statistics, and thus counting, in order to successfully derive an equation for the energy distribution within the black-body radiation spectrum, and what we now call Bose-Einstein statistics. Some of the details involved in the counting procedure vary while still giving the same result. However, the interpretation of what we count may differ dramatically from one another (as, for example, between Planck and Bose), without impacting the final, mathematical result. We demonstrate here a further alternative, which varies both, in the details of the counting, as well as in the interpretation, while still producing the same well known statistics. This approach puts the "quantumness" back into the radiation emission/absorption process, possibly dispensing with the requirement of quantized light, at least in the context of black-body radiation.