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Quantum Work Statistics with Initial Coherence

María García Díaz, Giacomo Guarnieri, Mauro Paternostro

Published Jan 1, 2020• 20 citations
Publisher

Abstract

The two-point measurement scheme for computing the thermodynamic work performed on a system requires it to be initially in equilibrium. The Margenau-Hill scheme, among others, extends the previous approach to allow for a non-equilibrium initial state. We establish a quantitative comparison between both schemes in terms of the amount of coherence present in the initial state of the system, as quantified by the l1-coherence measure. We show that the difference between the two first moments of work, the variances of work, and the average entropy production obtained in both schemes can be cast in terms of such initial coherence. Moreover, we prove that the average entropy production can take negative values in the Margenau-Hill framework.

DOI
10.3390/e22111223

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The two-point measurement scheme for computing the thermodynamic work performed on a system requires it to be initially in equilibrium. The Margenau-Hill scheme, among others, extends the previous approach to allow for a non-equilibrium initial state. We establish a quantitative comparison between both schemes in terms of the amount of coherence present in the initial state of the system, as quantified by the l1-coherence measure. We show that the difference between the two first moments of work, the variances of work, and the average entropy production obtained in both schemes can be cast in terms of such initial coherence. Moreover, we prove that the average entropy production can take negative values in the Margenau-Hill framework.
The two-point measurement scheme for computing the thermodynamic work performed on a system requires it to be initially in equilibrium. The Margenau-Hill scheme, among others, extends the previous approach to allow for a non-equilibrium initial state. We establish a quantitative comparison between both schemes in terms of the amount of coherence present in the initial state of the system, as quantified by the l1-coherence measure. We show that the difference between the two first moments of work, the variances of work, and the average entropy production obtained in both schemes can be cast in terms of such initial coherence. Moreover, we prove that the average entropy production can take negative values in the Margenau-Hill framework.
In quantum thermodynamics, the two-projective-measurement (TPM) scheme provides a successful description of stochastic work only in the absence of initial quantum coherence. Extending the quantum work distribution to quasiprobability is a general way to characterize work fluctuation in the presence of initial coherence. However, among a large number of different definitions, there is no consensus on the most appropriate work quasiprobability. In this article, we list several physically reasonable requirements including the first law of thermodynamics, time-reversal symmetry, positivity of second-order moment, and a support condition for the work distribution. We prove that the only definition that satisfies all these requirements is the Margenau-Hill (MH) quasiprobability of work. In this sense, the MH quasiprobability of work shows its advantages over other definitions. As an illustration, we calculate the MH work distribution of a breathing harmonic oscillator with initial squeezed states and show the convergence to classical work distribution in the classical limit.
Abstract Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance—such as work, heat and entropy production—on the amount of quantum coherences that is made available to a system. However, whether coherences hinder or enhance the value taken by such quantifiers of thermodynamic performance is yet to be ascertained. We show that, when considering entropy production generated in a process taking a finite-size bipartite quantum system out of equilibrium through local non-unitary channels, no general monotonicity relationship exists between the entropy production and degree of quantum coherence in the state of the system. A direct correspondence between such quantities can be retrieved when considering specific forms of open-system dynamics applied to suitably chosen initial states. Our results call for a systematic study of the role of genuine quantum features in the non-equilibrium thermodynamics of quantum processes.
Abstract We consider Margenau-Hill quasiprobability that measures a statistical weight assigned to an observation of an energy eigenvalue pair and its utilization in assessing work done by isolated quantum ensembles that generally contain coherence. We point out some physically reasonable and intuitive features of the statistical properties of work determined by Margenau-Hill quasiprobability. To be specific, we show that in sharp contrast to other proposals, the moment-generating function given by Margenau-Hill quasiprobability fulfills the composition and shift properties, and thus guarantees the additivity of works performed by joined work protocols. Work fluctuations accessed by Margenau-Hill distribution also give expected values for initially pure energy ensembles, providing a rationale as to why it serves as a unique measure in characterizing quantum work and its fluctuations.
The standard definition of quantum fluctuating work is based on the two-projective energy measurement, which however does not apply to systems with initial quantum coherence because the first projective energy measurement destroys the initial coherence, and affects the subsequent evolution of the system. To address this issue, several alternative definitions, such as those based on the full counting statistics and the Margenau-Hill distribution, have been proposed recently. These definitions seem ad hoc because justifications for them are still lacking. In the current study, by utilizing the quantum Feynman-Kac formula and the phase space formulation of quantum mechanics, we prove that the leading order of work distributions is equal to the classical work distribution. Thus we prove the validity of the quantum-classical correspondence of work distributions for initial states with quantum coherence, and provide some justification for those definitions of work. We use an exactly solvable model of the linearly dragged harmonic oscillator to demonstrate our main results.
A central challenge in quantum thermodynamics is to access work fluctuations in coherent processes without distorting the energetics of the unmeasured evolution. In standard two-point schemes, the initial energy measurement dephases coherent inputs, causing the measured average work to differ from that of the unmeasured evolution. Here, we develop an operational scheme for accessing work statistics for closed quantum systems based on the abstract notion of variation in the Heisenberg picture Hamiltonian. This scheme preserves energetically relevant coherences, thereby faithfully reproducing unmeasured work, while still producing positive probabilities. We derive modified Jarzynski and Crooks relations, as well as a thermodynamic uncertainty relation, identifying coherence-induced correction terms. Furthermore, we show that this scheme can reliably quantify the performance of a coherent engine in situations where the two-point energy measurement would suppress work output. In addition, the scheme requires only a single measurement and can predict the work associated with a subsequent unitary transformation. We exploit this feature to construct a Maxwell-demon protocol that can outperform energy-based feedback engines for coherent work extraction. Our results establish this scheme as a framework for accessing coherent work fluctuations without erasing the coherence that drives quantum thermodynamic performance.