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The British Journal for the Philosophy of Science

Classical Particle Indistinguishability, Precisely

James Wills

Published Apr 15, 2021• 2 citations
Publisher

Abstract

I present a new perspective on the meaning of indistinguishability of classical particles. This leads to a solution to the problem in statistical mechanics of justifying the inclusion of a factor N! in a probability distribution over the phase space of N indistinguishable classical particles.
DOI
10.1086/714817

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According to classical physics particles are basic building blocks of the world. Classical particles are distinguishable objects, individuated by physical characteristics. By contrast, in quantum mechanics the standard view is that particles of the same kind ("identical particles") are in all circumstances indistinguishable from each other. This indistinguishability doctrine is motivated by the (anti)symmetrization postulates together with the assumption (``factorism'') that each single particle is represented in exactly one factor space in the tensor product Hilbert space of a many-particles system. Although the factorist assumption is standard in the literature, it is conceptually problematic. Particle indistinguishability is incompatible with the everyday meaning of ``particle'', and also with how this term is used both in classical physics and in the experimental practice of physics. The standard view requires quantum particles of the same kind to remain indistinguishable even in the classical limit, so that a transition to the classical picture of the world seems impossible. Earlier we have proposed an alternative conception of quantum particles that does not rely on factorism and that avoids these and other problems. We further explain and develop this proposal here. In our view, particles in quantum theory are not fundamental but \emph{emergent}. However, in those situations where the particle concept is applicable, quantum particles---identical or not---are distinguishable in the same way as classical particles.
The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical statistical mechanics. In particular, the Gibbs paradox has sometimes been interpreted as a sign of the untenability of the classical concept of a particle and as a premonition that quantum theory is needed. This idea of a ‘quantum connection’ stubbornly persists in the literature, even though it has also been criticized frequently. Here we shall argue that although this criticism is justified, the proposed alternative solutions have often been wrong and have not put the paradox in its right perspective. In fact, the Gibbs paradox is unrelated to fundamental issues of particle identity; only distinguishability in a pragmatic sense plays a role (in this we develop ideas of van Kampen [10]), and in principle the paradox always is there as long as the concept of a particle applies at all. In line with this we show that the paradox survives even in quantum mechanics, in spite of the quantum mechanical (anti-)symmetrization postulates.
Abstract According to classical physics particles are basic building blocks of the world. These classical particles are distinguishable objects, individuated by unique combinations of physical properties. By contrast, in quantum mechanics the received view is that particles of the same kind (“identical particles”) are physically indistinguishable from each other and lack identity. This doctrine rests on the quantum mechanical (anti)symmetrization postulates together with the “factorist” assumption that each single particle is represented in exactly one factor space of the tensor product Hilbert space of a many-particle system. Even though standard in theoretical physics and the philosophy of physics, the assumption of factorism and the ensuing indistinguishability of particles are problematic. Particle indistinguishability is irreconcilable with the everyday meaning of “particle”, and also with how this term is used in the practice of physics. Moreover, it is a consequence of the standard view that identical quantum particles remain indistinguishable even in the classical limit, which makes a smooth transition to the classical particle concept impossible. Lubberdink (1998; 2009) and Dieks and Lubberdink (2011) have proposed an alternative conception of quantum particles that does not rely on factorism and avoids these difficulties. We further explain and discuss this alternative framework here. One of its key consequences is that particles in quantum theory are not fundamental but emergent; another that once they have emerged, quantum particles are always physically distinguishable and thus possess a physically grounded identity.