Quantum Electrodynamical Treatments of Atoms Interacting with Radiation Fields .

Abraham Nitzan

Many dynamical processes of interest are either initiated or probed by light, and their understanding requires some knowledge of this subject. This chapter is included in order to make this text self contained by providing an overview of subjects that are used in various applications later in the text. In particular, it aims to supplement the elementary view of radiation–matter interaction as a time-dependent perturbation in the Hamiltonian, by describing some aspects of the quantum nature of the radiation field. This is done on two levels: The main body of this chapter is an essentially qualitative overview that ends with a treatment of spontaneous emission as an example. The Appendix gives some more details on the mathematical structure of the theory. In elementary treatments of the interaction of atoms and molecules with light, the radiation field is taken as a classical phenomenon.

Vladilen S Letokhov

Vladilen S Letokhov

M. Guccione, Maria Anastasia Jivulescu, ANTONINO MESSINA

We consider a two-photon quantum model of radiation-matter interaction between a single two-level atom and a degenerate bimodal high-Q cavity field. Within this tripartite system the explicit construction of two collective radiation modes, one of which freely evolving and the other one quadratically coupled to the matter subsystem, is reported. Meaning and advantages of such a decoupling treatment are carefully discussed.

Yu. M. Golubev

A. O. Barut, Jonathan P. Dowling

We use a self-field approach to quantum electrodynamics (QED) to show how one may obtain spontaneous emission and the Lamb shift in a two-level atom without second quantization of the radiation field. In addition, we compare the self-field formalism to that of the neoclassical theory of electrodynamics advanced by Crisp and Jaynes [Phys. Rev. 179, 1253 (1969)]. We show that the neoclassical model can be obtained from the self-field approach used here, but that the two are not equivalent. In particular, the self-field approach appears to give a more complete description of radiative processes. Finally, we show that the neoclassical theory's prediction of a nonexponential ``chirruped'' decay is most likely a mathematical artifact of the improper application of the superposition principle in a nonlinear model where such a principle does not hold. A correct treatment with self-field QED yields the usual exponential decay dynamics.