Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

The delocalization of electrons in position and momentum space densities: A study of Shannon information entropies

Minhhuy Hô

Published Jan 1, 1998• 1 citation
OpenAlex

Related papers

Shannon information entropy in position space for two-electron atomic systems

Chien-Hao Lin, Y. K. Ho

arXiv:1504.05731•Chemical Physics Letters•May 30, 2015•74 citations

Shannon Information Entropy for Two-Electron Systems in Position Space

Y. K. Ho, Chien-Hao Lin

Bulletin of the American Physical Society•Jun 10, 2015•0 citations

Shannon Information Entropy in Position Space for the Ground and Singly Excited States of Helium with Finite Confinements

Jen‐Hao Ou, Y. K. Ho

We provide benchmark values for Shannon information entropies in position space for the ground state and ls2s 1Se excited state of helium confined with finite confinement potentials by employing the highly correlated Hylleraas-type wave functions. For the excited state, a “tilt” (small oscillation) on the curve of Shannon entropy as a function of width size for the confinement potential is observed. Justified by the behavior of the electron density, the localization or delocalization of the helium wave functions confined with repulsive and attractive finite oscillator (FO) potentials are examined.

Atoms•Mar 24, 2017•29 citations

Shannon and Fisher Entropy for a New Class of Single Hyperbolic Potentials in Fractional Schrödinger Equation

R. Santana Carrillo, David Maya‐Franco, Guo-Hua Sun +1 more

ABSTRACT We investigate the quantum information entropy for a class of single hyperbolic potentials within the context of the fractional Schrödinger equation (FSE). We find that as the derivative variable decreases, the position entropy density function becomes more localized, and its peak heightens. However, there are differences in the degree of localization between the position entropy density functions for each hyperbolic potential, which can be attributed to the varying sizes of the potentials. Conversely, in momentum space, the momentum entropy density function becomes more delocalized, and its peak lowers as the derivative variable decreases for both hyperbolic potentials studied. Our analysis also examines the BBM inequality, demonstrating that it is satisfied for different values of the potential depths. Finally, we explore the Fisher entropy and observe that it increases in position space while decreasing in momentum space as the depth of the wells increases. Our findings provide new insights into the behavior of quantum systems governed by hyperbolic potentials within the fractional Schrödinger framework. The observed localization effects in position space, delocalization in momentum space, and the validation of the BBM inequality highlight the role of fractional derivatives in modifying quantum entropy measures. These results deepen our understanding of quantum information entropy in non‐local quantum systems. They may have implications for fields such as quantum transport in disordered media, semiconductor physics, and the study of anomalous diffusion processes in quantum mechanics.

International Journal of Quantum Chemistry•Mar 21, 2025•5 citations

On the relationship between one-electron potential and densities of Fisher information and Shannon entropy

Mojtaba Alipour, Afshan Mohajeri

Chemical Physics•Oct 31, 2011•10 citations

Information Entropies for H2 and ScF Diatomic Molecules with Deng- Fan-Eckart Potential

P. O. Amadi, A. N. Ikot, U. S. Okorie +3 more

In this study, the Shannon entropy and the Fisher information is investigated with molecular Deng-Fan-Eckart potential for the diatomic molecules and ScF in position and momentum spaces in three dimensions for the ground and the excited states. The results were numerically obtained for diatomic molecules. Localization is observed for Shannon entropy and delocalization for Fisher information for both molecules in the position and momentum spaces. The uncertainty relations for the selected diatomic molecules were satisfied accordingly.

Revista Mexicana de Física•Nov 5, 2020•14 citations
We provide benchmark values for Shannon information entropies in position space for the ground state and ls2s 1Se excited state of helium confined with finite confinement potentials by employing the highly correlated Hylleraas-type wave functions. For the excited state, a “tilt” (small oscillation) on the curve of Shannon entropy as a function of width size for the confinement potential is observed. Justified by the behavior of the electron density, the localization or delocalization of the helium wave functions confined with repulsive and attractive finite oscillator (FO) potentials are examined.
ABSTRACT We investigate the quantum information entropy for a class of single hyperbolic potentials within the context of the fractional Schrödinger equation (FSE). We find that as the derivative variable decreases, the position entropy density function becomes more localized, and its peak heightens. However, there are differences in the degree of localization between the position entropy density functions for each hyperbolic potential, which can be attributed to the varying sizes of the potentials. Conversely, in momentum space, the momentum entropy density function becomes more delocalized, and its peak lowers as the derivative variable decreases for both hyperbolic potentials studied. Our analysis also examines the BBM inequality, demonstrating that it is satisfied for different values of the potential depths. Finally, we explore the Fisher entropy and observe that it increases in position space while decreasing in momentum space as the depth of the wells increases. Our findings provide new insights into the behavior of quantum systems governed by hyperbolic potentials within the fractional Schrödinger framework. The observed localization effects in position space, delocalization in momentum space, and the validation of the BBM inequality highlight the role of fractional derivatives in modifying quantum entropy measures. These results deepen our understanding of quantum information entropy in non‐local quantum systems. They may have implications for fields such as quantum transport in disordered media, semiconductor physics, and the study of anomalous diffusion processes in quantum mechanics.
In this study, the Shannon entropy and the Fisher information is investigated with molecular Deng-Fan-Eckart potential for the diatomic molecules and ScF in position and momentum spaces in three dimensions for the ground and the excited states. The results were numerically obtained for diatomic molecules. Localization is observed for Shannon entropy and delocalization for Fisher information for both molecules in the position and momentum spaces. The uncertainty relations for the selected diatomic molecules were satisfied accordingly.